**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 106-94-5 |1-Bromopropane | 99 | 203-445-0 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 10 20
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Flammable. Harmful by inhalation.
Potential Health Effects
Eye:
Causes eye irritation and possible burns.
Skin:
Causes skin irritation and possible burns.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. May cause liver and kidney damage. Vapors may cause
dizziness or suffocation. Exposure may cause bone marrow changes.
Exposure may cause blood abnormalities. Causes respiratory tract
irritation with possible burns.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion. There are not enough human data
on 1-bromopropane to determine whether the chemical has harmed human
reproduction and development. However, research on lab rats shows
1-bromopropane can damage reproduction and development in that
animal. Effects, such as a lengthened estrous (reproductive) cycle,
occurred when female rats inhaled 1-bromopropane at concentrations of
250 ppm.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Remove
contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. May polymerize explosively when
involved in a fire. Vapors are heavier than air and may travel to a
source of ignition and flash back. Vapors can spread along the
ground and collect in low or confined areas.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Water may be ineffective. Do NOT get water
inside containers. Do NOT use straight streams of water.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Use spark-proof tools and explosion proof
equipment. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames. Use only with adequate ventilation. Keep
away from heat, sparks and flame. Avoid breathing vapor or mist.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 106-94-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 146 mmHg @ 20 C
Viscosity: Not available.
Boiling Point: 71 deg C @ 760 mm Hg
Freezing/Melting Point: -110 deg C
Autoignition Temperature: 490 deg C ( 914.00 deg F)
Flash Point: 25 deg C ( 77.00 deg F)
Explosion Limits, lower: 4.60 vol %
Explosion Limits, upper: 7.8 vol %
Decomposition Temperature:
Solubility in water: 2.5 g/l (20C)
Specific Gravity/Density: 1.35 g/cm3
Molecular Formula: C3H7Br
Molecular Weight: 122.99
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 106-94-5: TX4110000
LD50/LC50:
CAS# 106-94-5: Inhalation, mouse: LC50 = 7100 mg/m3; Inhalation,
rat: LC50 = 253 gm/m3/30M; Inhalation, rat: LC50 = 19700 mg/m3; Oral,
mouse: LD50 = 4700 mg/kg; Oral, rat: LD50 = 3600 mg/kg.
Carcinogenicity:
1-Bromopropane -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing Group: III
IMO
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing Group: III
RID/ADR
Shipping Name: BROMOPROPANES
Hazard Class: 3
UN Number: 2344
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 10 Flammable.
R 20 Harmful by inhalation.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 24 Avoid contact with skin.
WGK (Water Danger/Protection)
CAS# 106-94-5: No information available.
Canada
CAS# 106-94-5 is listed on Canada's DSL List.
CAS# 106-94-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 106-94-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/12/1998 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|