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MSDS 
:
 Carbol Fuchsin
CAS 
:
 108-95-2
SYNONYMS 
:
 4-[(4-amino-m-tolyl)(4-iminocyclohexa-2,5-dien-1-ylidene)met.
**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****

+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 108-95-2 |Phenol | 8.0 | 203-632-7 |
|----------------|--------------------------------------|----------|-----------|
| 4197-24-4 |Carbol Fuchsin | Balance | 224-086-6 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T
Risk Phrases: 34 24/25

**** SECTION 3 - HAZARDS IDENTIFICATION ****

EMERGENCY OVERVIEW
Causes burns. Toxic in contact with skin and if
swallowed.Corrosive.Light sensitive.

Potential Health Effects
Eye:
Causes severe eye irritation and possible burns. May cause
chemical conjunctivitis and corneal damage.
Skin:
Toxic in contact with skin. Causes severe skin irritation and
possible burns. May cause skin rash (in milder cases), and cold and
clammy skin with cyanosis or pale color.
Ingestion:
May cause severe and permanent damage to the digestive tract. Poison
by ingestion. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract. May cause systemic effects.
Inhalation:
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma. Aspiration may lead
to pulmonary edema. May cause systemic effects.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
liver and kidney damage. May cause cancer according to animal
studies. Effects may be delayed.

**** SECTION 4 - FIRST AID MEASURES ****

Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:

**** SECTION 5 - FIRE FIGHTING MEASURES ****

General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide, or regular foam.

**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****

General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.

**** SECTION 7 - HANDLING and STORAGE ****

Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Store protected from light. Discard contaminated
shoes.
Storage:
Keep container closed when not in use. Store protected from light.
Store in a cool, dry area away from incompatible substances.

**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****

Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 108-95-2:
United Kingdom, WEL - TWA: 2 ppm TWA
United Kingdom, WEL - STEL: 6 ppm STEL
United States OSHA: 5 ppm TWA; 19 mg/m3 TWA
Belgium - TWA: 2 ppm VLE; 7.8 mg/m3 VLE
France - VME: 5 ppm VME; 19 mg/m3 VME
Germany: 5 ppm TWA; 19 mg/m3 TWA
Germany: Skin absorber
Japan: 5 ppm OEL; 19 mg/m3 OEL
Malaysia: 5 ppm TWA; 15 mg/m3 TWA
Netherlands: 2 ppm MAC; 8 mg/m3 MAC
Russia: 0.3 mg/m3 TWA
Spain: 2 ppm VLA-ED; 8 mg/m3 VLA-ED
CAS# 4197-24-4:


Personal Protective Equipment

Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.

**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****

Physical State: Crystalline powder
Color: dark green
Odor: phenol-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula:
Molecular Weight:

**** SECTION 10 - STABILITY AND REACTIVITY ****

Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Light, dust generation, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, strong bases, strong acids.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported

**** SECTION 11 - TOXICOLOGICAL INFORMATION ****

RTECS#:
CAS# 108-95-2: SJ3325000
CAS# 4197-24-4 unlisted.
LD50/LC50:
CAS# 108-95-2: Draize test, rabbit, eye: 5 mg Severe; Draize test,
rabbit, skin: 500 mg/24H Severe; Draize test, rabbit, skin: 100 mg
Mild; Inhalation, mouse: LC50 = 177 mg/m3; Inhalation, mouse: LC50 =
177 mg/m3/4H; Inhalation, rat: LC50 = 316 mg/m3; Inhalation, rat:
LC50 = 316 mg/m3/4H; Oral, mouse: LD50 = 270 mg/kg; Oral, rat: LD50 =
317 mg/kg; Oral, rat: LD50 = 512 mg/kg; Skin, rabbit: LD50 = 630
mg/kg; Skin, rat: LD50 = 669 mg/kg; Skin, rat: LD50 = 1500 mg/kg.
CAS# 4197-24-4.
Carcinogenicity:
Phenol -
Not listed by ACGIH, IARC, or NTP.
Carbol Fuchsin -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.

**** SECTION 12 - ECOLOGICAL INFORMATION ****

Ecotoxicity:
Fish: Pseudomonas putida:

**** SECTION 13 - DISPOSAL CONSIDERATIONS ****

Dispose of in a manner consistent with federal, state, and local regulations.

**** SECTION 14 - TRANSPORT INFORMATION ****

IATA
Shipping Name: Toxic solid, organic, n.o.s.*
Hazard Class: 6.1
UN Number: 2811
Packing Group: 2
IMO
Shipping Name: Toxic solid, organic, n.o.s.
Hazard Class: 6.1
UN Number: 2811
Packing Group: 2
RID/ADR
Shipping Name: PHENOL SOLUTION
Hazard Class: 6.1
UN Number: 2821
Packing group: III
USA RQ: CAS# 108-95-2: 1000 lb final RQ; 454 kg final RQ

**** SECTION 15 - REGULATORY INFORMATION ****

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 24/25 Toxic in contact with skin and if swallowed.
R 34 Causes burns.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 108-95-2: 2
CAS# 4197-24-4: No information available.
Canada
CAS# 108-95-2 is listed on Canada's DSL List.
CAS# 108-95-2 is listed on Canada's Ingredient Disclosure List.
CAS# 4197-24-4 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 108-95-2 is listed on the TSCA inventory.
CAS# 4197-24-4 is not listed on the TSCA inventory.
It is for research and development use only.

**** SECTION 16 - ADDITIONAL INFORMATION ****

Text for R-phrases from Section 2
R 34 Causes burns.
R 24/25 Toxic in contact with skin and if swallowed.
MSDS Creation Date: 3/13/2001 Revision #3 Date: 3/18/2003

The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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