**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 109-99-9 |Tetrahydrofuran | 93% | 203-726-8 |
|----------------|--------------------------------------|----------|-----------|
| 25895-60-7 |Sodium cyanoborohydride | 7% | 247-317-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T F N
Risk Phrases: 11 19 23/24/25 36/37/38 51/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May form explosive peroxides. Toxic by inhalation,
in contact with skin and if swallowed. Irritating to eyes,
respiratory system and skin. Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.Moisture
sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Toxic in contact with skin.
Ingestion:
May cause irritation of the digestive tract. May cause cyanosis
(bluish discoloration of skin due to deficient oxygenation of the
blood). Toxic if swallowed.
Inhalation:
Causes respiratory tract irritation. Toxic if inhaled.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Containers may explode in the
heat of a fire. Flammable liquid and vapor. May form explosive
peroxides.
Extinguishing Media:
DO NOT USE WATER! Use dry chemical. Contact with water or steam may
produce toxic and flammable vapors.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area. Store under
nitrogen.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
CAS# 109-99-9:
United Kingdom, WEL - TWA: 50 ppm TWA; 150 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 300 mg/m3 STEL
United States OSHA: 200 ppm TWA; 590 mg/m3 TWA
Belgium - TWA: 200 ppm VLE; 599 mg/m3 VLE
Belgium - STEL: 100 ppm VLE; 300 mg/m3 VLE
France - VME: 200 ppm VME; 590 mg/m3 VME
Germany: 50 ppm TWA; 150 mg/m3 TWA
Germany: Skin absorber
Japan: 200 ppm OEL; 590 mg/m3 OEL
Malaysia: 200 ppm TWA; 590 mg/m3 TWA
Netherlands: 100 ppm MAC; 300 mg/m3 MAC
Russia: 100 mg/m3 TWA
Spain: 50 ppm VLA-ED; 150 mg/m3 VLA-ED
Spain: 100 ppm VLA-EC; 300 mg/m3 VLA-EC
CAS# 25895-60-7:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: -18 deg C ( -0.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 0.915
Molecular Formula: CH3BNNa
Molecular Weight: 62.84
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen cyanide, carbon monoxide, oxides of nitrogen, carbon
dioxide, oxides of boron.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 109-99-9: LU5950000
CAS# 25895-60-7 unlisted.
LD50/LC50:
CAS# 109-99-9: Inhalation, rat: LC50 = 21000 ppm/3H; Oral, rat: LD50
= 1650 mg/kg.
CAS# 25895-60-7.
Carcinogenicity:
Tetrahydrofuran -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to
Sodium cyanoborohydride -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.*
Hazard Class: 3 (6.1)
UN Number: 1992
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3 (6.1)
UN Number: 1992
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, TOXIC, N.O.S.
Hazard Class: 3 (6.1)
UN Number: 1992
Packing group: II
USA RQ: CAS# 109-99-9: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F N
Risk Phrases:
R 11 Highly flammable.
R 19 May form explosive peroxides.
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 28A After contact with skin, wash immediately with
plenty of water.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static
discharges.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 109-99-9: 1
CAS# 25895-60-7: 2
Canada
CAS# 109-99-9 is listed on Canada's DSL List.
CAS# 25895-60-7 is listed on Canada's NDSL List.
CAS# 109-99-9 is listed on Canada's Ingredient Disclosure List.
CAS# 25895-60-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 109-99-9 is listed on the TSCA inventory.
CAS# 25895-60-7 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 19 May form explosive peroxides.
R 36/37 Irritating to eyes and respiratory system.
MSDS Creation Date: 9/20/2004 Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Methyl 2-isocyano-3-methylpentanoate, 96%
| 0-01-1 |
|
4-Bromobenzonitrile, 98%
| 623-00-7 |
|
Methyl 3,4,5-Trihydroxybenzoate, 99 %
| 99-24-1 |
|
3-Hydroxy-2-nitropyridine, 97%
| 15128-82-2 |
|
Methyl 2-isocyano-3-methylbutyrate, 96%
| 40846-66-0 |
|
Methyl 3-isocyanopropionate, 96%
| 0-01-1 |
|
Methyl 2-isocyanopropionate, 96%
| 33115-74-1 |
|
1-Isocyano-3-isopropoxypropane, 96%
| 602262-07-7 |
|
1,1,3,3-Tetramethylbutyl isocyanide
| 14542-93-9 |
|
2,3-Dihydro-6-isocyano-1,4-benzodioxine, 95%
| 174092-82-1 |
|
Butyl Lactate, 99% (GC)
| 138-22-7 |
|
Dimethyl-d6 sulfate, 99+ atom % d
| 15199-43-6 |
|
Cyclopentyl isocyanide, 96%
| 68498-54-4 |
|
2-Cyclohexen-1-ylethyl isocyanide, 96%
| 172223-58-4 |
|
Diphenylmethyl isocyanide, 96%
| 3128-85-6 |
|
Methyl 2-isocyano-3-phenylpropionate, 96%
| 63157-14-2 |
|
alpha-Methylbenzyl isocyanide, 96%
| 17329-20-3 |
|
4-Fluorophenyl isocyanide, 95%
| 24075-34-1 |
|
3-Phenylpropyl isocyanide, 96%
| 111944-21-9 |
|
Phenylethyl isocyanide, 96%
| 59795-89-0 |
|
Benzo[a]pyrene, 96.5%
| 50-32-8 |
|
1-(Trifluoroacetyl)imidazole, 95%
| 1546-79-8 |
|
Ethylurea, 97%
| 625-52-5 |
|
1-Naphthalenemethanol, 98%
| 4780-79-4 |
|
Trimethylaluminum, 1,0M solution in heptane
| 75-24-1 |
|
Triisobutylaluminium, 1.1M solution in toluene
| 100-99-2 |
|
Ethylmagnesium chloride, 2.0M solution in THF
| 109-99-9 |
|
Triethylaluminium, 1,3M solution in heptane
| 97-93-8 |
|
Diethylzinc, 1,5M solution in toluene
| 108-88-3 |
|
Sodium thiophosphate hydrate
| 10489-48-2 |
|
cis-2,6-Dimethylmorpholine, 97%
| 6485-55-8 |
|
N-(2-Chloroethyl)pyrrolidine hydrochloride, 98%
| 7250-67-1 |
|
MP Alumina R, ICN material
| 1344-28-1 |
|
Tributylborane, 98%
| 122-56-5 |
|
L(-)-10-Camphorsulfonyl chloride
| 39262-22-1 |
|
Sodium cyanoborohydride, solution in THF
| 109-99-9 |
|
1-Phenyl-2-propanol, 99%
| 14898-87-4 |
|
N-(4-Dimethylamino-3,5-dinitrophenyl)maleimide
| 3475-74-9 |
|
8-Chloro-1-octanol, 98%
| 23144-52-7 |
|
1,10-Diamino-4,7-dioxadecane
| 2997-01-5 |
|
(4-Methoxybenzylidene)malonitrile, 98%
| 2826-26-8 |
|
1-(2-Hydroxyphenyl)piperazine, 98%
| 1011-17-2 |
|
5-Bromo-2-methylaniline, 98%
| 39478-78-9 |
|
1-Iodo-3-methylbutane, stabilized, 98%
| 541-28-6 |
|
2,4,6-Trivinylcyclotriboroxane-pyridine complex
| 92988-08-4 |
|
2-Methyl-5-nitroanisole, 99%
| 13120-77-9 |
|
Methyl 3-benzoylpropionate, 97%
| 25333-24-8 |
|
Ethyl 3-methylbenzoate, 98%
| 120-33-2 |
|
3,4-Dichlorostyrene, stabilized, 95%
| 2039-83-0 |
|
Dihydroquinine hydrobromide hydrate
| 0-01-1 |
|
|