**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 120-78-5 |2,2'-Dithio(bis)benzothiazole | >/= 94 | 204-424-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI N
Risk Phrases: 31 43 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. May cause sensitization by
skin contact. Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.The toxicological
properties of this material have not been fully investigated.
Potential Health Effects
Eye:
May cause eye irritation. Dust may cause mechanical irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated. May
cause allergic reaction.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up or absorb material, then place into a
suitable clean, dry, closed container for disposal. Avoid generating
dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Use with
adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 120-78-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Powder
Color: yellow
Odor: aromatic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 177.00 - 183.00 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble
Specific Gravity/Density:
Molecular Formula: C14H8N2S4
Molecular Weight: 332.49
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Contact with acids
liberates toxic gas, Sulfur oxides.
Conditions to Avoid:
Dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 120-78-5: DL4550000
LD50/LC50:
CAS# 120-78-5: Oral, mouse: LD50 = 7 gm/kg; Oral, rat: LD50 = >12
gm/kg; Skin, rabbit: LD50 = >7940 mg/kg.
Carcinogenicity:
2,2'-Dithio(bis)benzothiazole -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Daphnia: Daphnia: 82mg/L; 48 Hr; EC50Fish: Bluegill/Sunfish: 82mg/L;
48 Hr; LC50Fish: Rainbow trout: 66mg/L; 96 Hr; LC50Fish: Fathead
Minnow: >1000 mg/L; 96 Hr; LC50Algae: 0.7 mg/L; 96 Hr; EC50
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S
.
Hazard Class: 9
UN Number: 3077
Packing Group: III
IMO
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S
.
Hazard Class: 9
UN Number: 3077
Packing Group: III
RID/ADR
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S
.
Hazard Class: 9
UN Number: 3077
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI N
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 43 May cause sensitization by skin contact.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 120-78-5: 2
Canada
CAS# 120-78-5 is listed on Canada's DSL List.
CAS# 120-78-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 120-78-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/10/1998 Revision #4 Date: 10/20/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Cumene-d12, 99 atom % D
| 0-00-1 |
|
Methyl Methacrylate-D8, 99.5 Atom % D, Stabilized with 100 ppm
| 0-00-1 |
|
Methylcyclohexane-d14, 99.5 atom % D
| 108-87-2 |
|
Ethylene Glycol-D6, 99 Atom % D
| 15054-86-1 |
|
Ethyl alcohol-d6, anhydrous, 99 Atom % D
| 64-17-5 |
|
Methyl-d3 alcohol, 99.5 atom % D
| 67-56-1 |
|
(S,S)-(+)-2,2-Dimethyl-5-Methylamino-4-Phenyl-1,3-Dioxane
| 0-00-1 |
|
2,2-Dimethyl-1,3-Dioxan-5-One
| 74181-34-3 |
|
1,2,2,6,6-Pentamethyl-4-Piperidinol
| 2403-89-6 |
|
2,2'-Dithio(bis)benzothiazole
| 120-78-5 |
|
Acridine Orange, ca. 55%
| 10127-02-3 |
|
Cyclopentadienylmolybdenum Tricarbonyl Sodium
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|
1,2-Bis(dicyclohexylphosphino)ethane nickel(II) chloride
| 96555-88-3 |
|
1-Octene, 99+%
| 111-66-0 |
|
Lauric Acid, 99.8+% (GC)
| 143-07-7 |
|
Ethylenediaminetetraacetic Acid, Tripotassium Salt Dihydrate (Pract),
| 7732-18-5 |
|
alpha-Terpineol, 99%
| 98-55-5 |
|
Calcium bromide hydrate
| 7789-41-5 |
|
3-Hydroxy-N-Methylpiperidine, 97%
| 3554-74-3 |
|
2-Hydroxymethyl-12-Crown-4, Tech., 93% (gGC)
| 75507-26-5 |
|
Methyl(2E,4S)-(-)-4-(phenylmethoxy)pent-2-enoate
| 112489-57-3 |
|
Ethyl Isocyanoacetate, 97% (GC)
| 2999-46-4 |
|
N-Iodosuccinimide
| 516-12-1 |
|
3,5-Dichlorobenzotrifluoride
| 0-00-1 |
|
DL-Methionine, Feed Grade
| 59-51-8 |
|
2-Vinyl-1,3-dioxolane
| 3984-22-3 |
|
N-Glycine, E.P. Pyrogene Free
| 56-40-6 |
|
D(-)-glutamine
| 5959-95-5 |
|
4,5-Dihydroxynaphthalene-2,7-Disulfonic Acid, Disodium Salt
| 5808-22-0 |
|
Albumine Bovine, Fraction V (pH:7.0)
| 94349-60-7 |
|
n-Methyl-2,2,6,6-tetramethyl-4-piperidinol 99%
| 50-01-4 |
|
Ethyl cis-2-amino-1-cyclopentane carboxylate hydrochloride, 99%
| 142547-15-7 |
|
cis-2-(Benzyloxycarbonylamino)-1- cyclopentanecarboxylic acid
| |
|
3',4'-(Didodecyloxy)benzaldehyde, 99% (GC)
| 117241-25-5 |
|
2-Amino-1,2,3,4-Tetrahydronaphthalene-2- Carboxylic Acid
| 0-00-0 |
|
2,2',4'-Trichloroacetophenone, 99% (gc)
| 4252-78-2 |
|
3-Aminophenol, 99%
| 591-27-5 |
|
Alpha-Naphtholbenzein
| 6948-88-5 |
|
cis-2-Aminomethylcycloheptanol hydrochloride
| 0-00-0 |
|
n-(Tributyl)tinpyrrole
| 50486-65-2 |
|
2-Benzoyl-1-cyano-6,7-dimethoxy-1,2,3,4- tetrahydroisoquinoline
| |
|
Aluminum, Powder, -120 Mesh, 99,99%
| 7429-90-5 |
|
3-Amino-4-methylpentanoic acid
| 2458-12-0 |
|
3-Hydroxy-2,2-dimethyl-3-phenylpropionic- acid
| 0-00-0 |
|
(4S,2RS)-2,5,5-Trimethylthiazolidine-4- Carboxylic Acid
| 0-00-0 |
|
Bromobenzene-d5
| 108-86-1 |
|
3-Amino-1-phenoxy-2-propanol hydrochloride, 98%
| 4287-20-1 |
|
Tetrathiafulvalene, 99+%
| 31366-25-3 |
|
|