**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 142-04-1 |Aniline hydrochloride | 99% | 205-519-8 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T N
Risk Phrases: 20/21/22 40 50 48/23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Limited evidence of a carcinogenic effect. Very toxic to aquatic
organisms. Toxic : danger of serious damage to health by prolonged
exposure through inhalation, contact with skin and if
swallowed.Harmful.Hygroscopic (absorbs moisture from the air).Light
sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin. Causes
symptoms similar to those of inhalation.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
May cause effects similar to those for inhalation exposure.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. May cause
anoxia, characterized by weakness, headache, dizziness, confusion,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), weak and irregular heart beat, collapse,
unconsciousness, convulsions, coma and death.
Chronic:
May cause methemoglobinemia, which is characterized by
chocolate-brown colored blood, headache, weakness, dizziness, breath
shortness, cyanosis (bluish skin due to deficient oxygenation of
blood), rapid heart rate, unconsciousness and possible death. May
cause cancer according to animal studies.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wash area with soap and water.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation. Use only in a chemical fume
hood.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store
in a tightly closed container.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
CAS# 142-04-1:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: Not available.
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 245 deg C @ 760.00mm Hg
Freezing/Melting Point: 196 - 198 deg C
Autoignition Temperature: Not available.
Flash Point: 193 deg C ( 379.40 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: insoluble in ethyl ether and chloroform
Specific Gravity/Density:
Molecular Formula: C6H7N.HCl
Molecular Weight: 129.59
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 142-04-1: CY0875000
LD50/LC50:
CAS# 142-04-1: Draize test, rabbit, eye: 20 mg/24H Moderate; Draize
test, rabbit, skin: 500 mg/24H Moderate; Oral, mouse: LD50 = 841
mg/kg; Oral, rat: LD50 = 840 mg/kg.
Carcinogenicity:
Aniline hydrochloride -
California: carcinogen, initial date 5/15/98
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Water danger/protection: WGK 2
LC50 (48H) goldfish 5.5 mg/l
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: ANILINE HYDROCHLORIDE
Hazard Class: 6.1
UN Number: 1548
Packing Group: III
IMO
Shipping Name: ANILINE HYDROCHLORIDE
Hazard Class: 6.1
UN Number: 1548
Packing Group: III
RID/ADR
Shipping Name: ANILINE HYDROCHLORIDE
Hazard Class: 6.1
UN Number: 1548
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 40 Limited evidence of a carcinogenic effect.
R 48/23/24/25 Toxic : danger of serious damage to
health by prolonged exposure through inhalation,
contact with skin and if swallowed.
R 50 Very toxic to aquatic organisms.
Safety Phrases:
S 28 After contact with skin, wash immediately
with...
S 36/37 Wear suitable protective clothing and
gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 142-04-1: 2
Canada
CAS# 142-04-1 is listed on Canada's DSL List.
CAS# 142-04-1 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 142-04-1 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 11/13/1997 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Chlorzoxazone, 98%
| 95-25-0 |
|
4-Amino-6-Hydroxy-2-Mercaptopyrimidine Monohydrate, 98%
| 65802-56-4 |
|
Methyl trifluoroacetate, 99%
| 431-47-0 |
|
Rescinnamine, 98.0 - 101.0%
| 24815-24-5 |
|
3-Hydroxypropionitrile, P.A.
| 109-78-4 |
|
Dl-m-tyrosine, 98.5%
| 775-06-4 |
|
Benzyl Isocyanate, 98%
| 3173-56-6 |
|
d-(-)-Erythrose, 85%
| 583-50-6 |
|
6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoli ne hydrochloride, 98%
| 2328-12-3 |
|
2,3,4,5,6-Pentafluorobenzyl alcohol, 96-98%
| 440-60-8 |
|
2-Ethylhexanoic acid, p.a.
| 149-57-5 |
|
L-2-Pyrrolidone-5-carboxylic acid, 98%
| 98-79-3 |
|
Tetramethylammonium perchlorate
| 2537-36-2 |
|
5-Iodovanillin, 97%
| 5438-36-8 |
|
(-)-Myrtenol, 97+%
| 515-00-4 |
|
p-Toluamide
| 619-55-6 |
|
7-??(Chlorocarbonyl)methoxy??-4-Methylcoumarin
| 91454-65-8 |
|
Methyl 3,5-dihydroxybenzoate, 97%
| 2150-44-9 |
|
Aluminum fluoride trihydrate, 97%
| 15098-87-0 |
|
Boc-L-Arginine, 99+%
| 13726-76-6 |
|
2-Mesitylenesulfonic acid dihydrate, 97%
| 3453-83-6 |
|
2-Bromo-2',4'-Dimethoxyacetophenone, 98%
| 60965-26-6 |
|
Pentamethylbenzyl Chloride, 97% (Titr.)
| 484-65-1 |
|
cis-1,4-Dichloro-2-butene, 95%
| 1476-11-5 |
|
Aniline hydrochloride, 99%
| 142-04-1 |
|
Ammonium Perchlorate, 99.8%
| 7790-98-9 |
|
Poly(N,N-dimethyl-3,5-dimethylene-piperidinium chloride) 20 wt.%
| 7732-18-5 |
|
Samarium atomic absorption standard solution, 1 mg/ml Sm in 2% HNO3
| 7440-19-9 |
|
3-Chloro-5-Methoxyphenol, 99%
| 65262-96-6 |
|
Ethyl 2-furoate, 99%
| 614-99-3 |
|
Cresol Red, Water Soluble, Indicator Grade
| 62625-29-0 |
|
L-Buthionine-S,R-Sulfoximine, 99%
| 83730-53-4 |
|
gamma-Butyrolactone, 99+%
| 96-48-0 |
|
Ethoxyamine Hydrochloride, 99+% (Titr.)
| 3332-29-4 |
|
2-Tert-Butylcyclohexanol, Mixture of Isomers, 99%
| 13491-79-7 |
|
L-(+)-Glutamic Acid Hydrochloride, 99%
| 138-15-8 |
|
Bis(trimethylsilyl)sulfate, 98%
| 18306-29-1 |
|
Alpha-Methyl-Alpha-Propylsuccinimide 99+%
| 1497-19-4 |
|
3-Bromopyridine, 99%
| 626-55-1 |
|
3-Nitrosalicylaldehyde, 98%
| 5274-70-4 |
|
5-Hydroxydopamine Hydrochloride, 99%
| 5720-26-3 |
|
n,n-bis(Trimethylsilyl)acetamide
| 10416-58-7 |
|
1,4-Diphenyl-1,3-butadiene, scintillation grade
| 886-65-7 |
|
Benzyl Chloride
| 100-44-7 |
|
2-Methyl-5-Nitroindole, 95+%
| 7570-47-0 |
|
2,5-Dimethyl-1H-benzimidazole, 99%
| 1792-41-2 |
|
2,4-Dimethoxybenzylamine Hydrochloride, 97%
| 20781-21-9 |
|
3',4'-(Didecyloxy)Acetophenone, 98%
| 118468-33-0 |
|
(R)-Styrene Oxide, 99%
| 20780-53-4 |
|
Metrizamide p.a.
| 31112-62-6 |
|
|