**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 1476-11-5 |cis-1,4-Dichloro-2-butene | 95.0 | 216-021-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ N
Risk Phrases: 26 34 45 24/25 50/53
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Very toxic by inhalation. Causes burns. May cause cancer. Toxic in
contact with skin and if swallowed. Very toxic to aquatic organisms,
may cause long-term adverse effects in the aquatic
environment.Corrosive.The toxicological properties of this material
have not been fully investigated.Air sensitive.Moisture
sensitive.Light sensitive.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears). Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. May cause abdominal
pain, nausea, vomiting, and inflammation of the gums and mouth.
Chronic:
Possible cancer hazard based on tests with laboratory animals.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. SPEED IS ESSENTIAL. A DOCTOR MUST BE
NOTIFIED AT ONCE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Will burn if involved in a fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Wash hands before eating. Remove
contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Use spark-proof tools and explosion proof
equipment. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a dry area. Keep refrigerated. (Store below
4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits.
Exposure Limits
CAS# 1476-11-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear yellow
Odor: Unpleasant odor.
pH: Not available.
Vapor Pressure: 3.5 mbar
Viscosity: Not available.
Boiling Point: 152 deg C @ 758.00mm Hg
Freezing/Melting Point: -48 deg C
Autoignition Temperature: Not available.
Flash Point: 56 deg C ( 132.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density: 1.1880g/cm3
Molecular Formula: C4H6Cl2
Molecular Weight: 125.00
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, light,
ignition sources, exposure to air, excess heat, temperatures above
65C, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents and strong bases.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 1476-11-5 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
cis-1,4-Dichloro-2-butene -
Not listed by ACGIH, IARC, or NTP.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.*
Hazard Class: 6.1 (8)
UN Number: 2927
Packing Group: II
IMO
Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 6.1 (8)
UN Number: 2927
Packing Group: II
RID/ADR
Shipping Name: TOXIC LIQUID, CORROSIVE, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2927
Packing group: II
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ N
Risk Phrases:
R 45 May cause cancer.
R 24/25 Toxic in contact with skin and if swallowed.
R 26 Very toxic by inhalation.
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic environment.
Safety Phrases:
S 53 Avoid exposure - obtain special instructions
before use.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 60 This material and its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1476-11-5: No information available.
Canada
CAS# 1476-11-5 is listed on Canada's DSL List.
CAS# 1476-11-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 1476-11-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
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Chlorzoxazone, 98%
| 95-25-0 |
|
4-Amino-6-Hydroxy-2-Mercaptopyrimidine Monohydrate, 98%
| 65802-56-4 |
|
Methyl trifluoroacetate, 99%
| 431-47-0 |
|
Rescinnamine, 98.0 - 101.0%
| 24815-24-5 |
|
3-Hydroxypropionitrile, P.A.
| 109-78-4 |
|
Dl-m-tyrosine, 98.5%
| 775-06-4 |
|
Benzyl Isocyanate, 98%
| 3173-56-6 |
|
d-(-)-Erythrose, 85%
| 583-50-6 |
|
6,7-Dimethoxy-1,2,3,4-tetrahydroisoquinoli ne hydrochloride, 98%
| 2328-12-3 |
|
2,3,4,5,6-Pentafluorobenzyl alcohol, 96-98%
| 440-60-8 |
|
2-Ethylhexanoic acid, p.a.
| 149-57-5 |
|
L-2-Pyrrolidone-5-carboxylic acid, 98%
| 98-79-3 |
|
Tetramethylammonium perchlorate
| 2537-36-2 |
|
5-Iodovanillin, 97%
| 5438-36-8 |
|
(-)-Myrtenol, 97+%
| 515-00-4 |
|
p-Toluamide
| 619-55-6 |
|
7-??(Chlorocarbonyl)methoxy??-4-Methylcoumarin
| 91454-65-8 |
|
Methyl 3,5-dihydroxybenzoate, 97%
| 2150-44-9 |
|
Aluminum fluoride trihydrate, 97%
| 15098-87-0 |
|
Boc-L-Arginine, 99+%
| 13726-76-6 |
|
2-Mesitylenesulfonic acid dihydrate, 97%
| 3453-83-6 |
|
2-Bromo-2',4'-Dimethoxyacetophenone, 98%
| 60965-26-6 |
|
Pentamethylbenzyl Chloride, 97% (Titr.)
| 484-65-1 |
|
cis-1,4-Dichloro-2-butene, 95%
| 1476-11-5 |
|
Aniline hydrochloride, 99%
| 142-04-1 |
|
Ammonium Perchlorate, 99.8%
| 7790-98-9 |
|
Poly(N,N-dimethyl-3,5-dimethylene-piperidinium chloride) 20 wt.%
| 7732-18-5 |
|
Samarium atomic absorption standard solution, 1 mg/ml Sm in 2% HNO3
| 7440-19-9 |
|
3-Chloro-5-Methoxyphenol, 99%
| 65262-96-6 |
|
Ethyl 2-furoate, 99%
| 614-99-3 |
|
Cresol Red, Water Soluble, Indicator Grade
| 62625-29-0 |
|
L-Buthionine-S,R-Sulfoximine, 99%
| 83730-53-4 |
|
gamma-Butyrolactone, 99+%
| 96-48-0 |
|
Ethoxyamine Hydrochloride, 99+% (Titr.)
| 3332-29-4 |
|
2-Tert-Butylcyclohexanol, Mixture of Isomers, 99%
| 13491-79-7 |
|
L-(+)-Glutamic Acid Hydrochloride, 99%
| 138-15-8 |
|
Bis(trimethylsilyl)sulfate, 98%
| 18306-29-1 |
|
Alpha-Methyl-Alpha-Propylsuccinimide 99+%
| 1497-19-4 |
|
3-Bromopyridine, 99%
| 626-55-1 |
|
3-Nitrosalicylaldehyde, 98%
| 5274-70-4 |
|
5-Hydroxydopamine Hydrochloride, 99%
| 5720-26-3 |
|
n,n-bis(Trimethylsilyl)acetamide
| 10416-58-7 |
|
1,4-Diphenyl-1,3-butadiene, scintillation grade
| 886-65-7 |
|
Benzyl Chloride
| 100-44-7 |
|
2-Methyl-5-Nitroindole, 95+%
| 7570-47-0 |
|
2,5-Dimethyl-1H-benzimidazole, 99%
| 1792-41-2 |
|
2,4-Dimethoxybenzylamine Hydrochloride, 97%
| 20781-21-9 |
|
3',4'-(Didecyloxy)Acetophenone, 98%
| 118468-33-0 |
|
(R)-Styrene Oxide, 99%
| 20780-53-4 |
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Metrizamide p.a.
| 31112-62-6 |
|
|