**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 149-57-5 |2-Ethylhexanoic acid | 100 | 205-743-6 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 63
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Possible risk of harm to the unborn child.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. A single prolonged skin exposure is not
likely to result in the material being absorbed in harmful amounts.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis. Possible risk of harm to the unborn child.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
In case of contact, immediately flush eyes with plenty of water for
at least 15 minutes. Get medical aid immediately.
Skin:
In case of contact, immediately flush skin with plenty of water.
Remove contaminated clothing and shoes. Get medical aid. Wash
clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Avoid contact with eyes, skin, and clothing. Use
only with adequate ventilation. Avoid breathing vapor or mist.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
CAS# 149-57-5:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear, colorless
Odor: mild odor
pH: acidic
Vapor Pressure: 0.03 mm Hg @ 20 deg C
Viscosity: 7.73 cps
Boiling Point: 228 deg C @ 760 mm Hg
Freezing/Melting Point: -59 deg C
Autoignition Temperature: 371 deg C ( 699.80 deg F)
Flash Point: 118 deg C ( 244.40 deg F)
Explosion Limits, lower: .80 vol %
Explosion Limits, upper: 6.00 vol %
Decomposition Temperature:
Solubility in water: Slightly soluble.
Specific Gravity/Density: 0.903 g/ml @ 25C
Molecular Formula: C8H16O2
Molecular Weight: 144.21
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, reducing agents, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 149-57-5: MO7700000
LD50/LC50:
CAS# 149-57-5: Dermal, guinea pig: LD50 = 6300 uL/kg; Draize test,
rabbit, eye: 20 mg Severe; Oral, rat: LD50 = 3 gm/kg; Skin, rabbit:
LD50 = 1260 uL/kg.
Rabbit LD50 Skin; 1260 uL/kg = 1138 mg/kg.
6300 uL/kg = 5689 mg/kg.
Reaction: Mild.
(slight to moderate) was observed in 5 of 6 New Zealand white rabbits
4 hours after application of undiluted 2-ethylhexanoic acid.
Carcinogenicity:
2-Ethylhexanoic acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 63 Possible risk of harm to the unborn child.
Safety Phrases:
S 36/37 Wear suitable protective clothing and
gloves.
WGK (Water Danger/Protection)
CAS# 149-57-5: 1
Canada
CAS# 149-57-5 is listed on Canada's DSL List.
CAS# 149-57-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 149-57-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/24/1999 Revision #4 Date: 11/07/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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ALL MSDS PAGES IN THIS GROUP
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| 440-60-8 |
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| 149-57-5 |
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| 98-79-3 |
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| 15098-87-0 |
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| 13726-76-6 |
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| 60965-26-6 |
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| 1476-11-5 |
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| 7732-18-5 |
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| 65262-96-6 |
Ethyl 2-furoate, 99%
| 614-99-3 |
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| 83730-53-4 |
gamma-Butyrolactone, 99+%
| 96-48-0 |
Ethoxyamine Hydrochloride, 99+% (Titr.)
| 3332-29-4 |
2-Tert-Butylcyclohexanol, Mixture of Isomers, 99%
| 13491-79-7 |
L-(+)-Glutamic Acid Hydrochloride, 99%
| 138-15-8 |
Bis(trimethylsilyl)sulfate, 98%
| 18306-29-1 |
Alpha-Methyl-Alpha-Propylsuccinimide 99+%
| 1497-19-4 |
3-Bromopyridine, 99%
| 626-55-1 |
3-Nitrosalicylaldehyde, 98%
| 5274-70-4 |
5-Hydroxydopamine Hydrochloride, 99%
| 5720-26-3 |
n,n-bis(Trimethylsilyl)acetamide
| 10416-58-7 |
1,4-Diphenyl-1,3-butadiene, scintillation grade
| 886-65-7 |
Benzyl Chloride
| 100-44-7 |
2-Methyl-5-Nitroindole, 95+%
| 7570-47-0 |
2,5-Dimethyl-1H-benzimidazole, 99%
| 1792-41-2 |
2,4-Dimethoxybenzylamine Hydrochloride, 97%
| 20781-21-9 |
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| 118468-33-0 |
(R)-Styrene Oxide, 99%
| 20780-53-4 |
Metrizamide p.a.
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