**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 532-28-5 |Mandelonitrile, tech. | ca. 100 | 208-532-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 23/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic by inhalation, in contact with skin and if swallowed.Moisture
sensitive.The toxicological properties of this material have not
been fully investigated.
Potential Health Effects
Eye:
Causes severe eye irritation.
Skin:
Causes skin irritation.
Ingestion:
Metabolism may release cyanide, which may result in headache,
dizziness, weakness, collapse, unconsciousness and possible death.
Causes gastrointestinal tract irritation. May form methemoglobin
which in sufficient concentration causes cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Inhalation:
May cause effects similar to those described for ingestion. Causes
irritation of the mucous membrane and upper respiratory tract.
Chronic:
Absorption into the body leads to the formation of methemoglobin
which in sufficient concentrations causes cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Wash area with soap and water. Absorb spill using an absorbent,
non-combustible material such as earth, sand, or vermiculite. Do not
use combustible materials such as sawdust. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get in eyes, on skin, or on clothing. Keep container tightly
closed. Do not ingest or inhale. Keep from contact with moist air and
steam. Do not breathe vapor.
Storage:
Keep containers tightly closed. Store protected from moisture. Store
in a cool, dry area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 532-28-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 170 deg C @ 760.00mmHg
Freezing/Melting Point: -10 deg C
Autoignition Temperature: Not applicable.
Flash Point: 97 deg C ( 206.60 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: 170 deg C
Solubility in water: May decompose.
Specific Gravity/Density: 1.1170g/cm3
Molecular Formula: C8H7NO
Molecular Weight: 133.15
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable. However, may decompose if exposed to moist air or water.
Conditions to Avoid:
Incompatible materials, moisture.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, strong
bases, moisture.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 532-28-5: OO8400000
LD50/LC50:
CAS# 532-28-5: Draize test, rabbit, eye: 250 ug/24H Severe.
Carcinogenicity:
Mandelonitrile, tech. -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.*
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
IMO
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing Group: III
RID/ADR
Shipping Name: TOXIC LIQUID, ORGANIC, N.O.S.
Hazard Class: 6.1
UN Number: 2810
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin
and if swallowed.
Safety Phrases:
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 532-28-5: No information available.
Canada
CAS# 532-28-5 is listed on Canada's NDSL List.
CAS# 532-28-5 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 532-28-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 7/08/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
2',4'-Dimethylacetoacetanilide
| 97-36-9 |
|
2,5-Dihydroxybenzoic Acid, 99%
| 490-79-9 |
|
Mandelonitrile, tech.
| 532-28-5 |
|
N-Acetylsulfanilyl Chloride, 99%(Titr.)
| 121-60-8 |
|
DL-Amethopterin hydrate
| 60388-53-6 |
|
D-Ethionine, 98%
| 535-32-0 |
|
Boron trichloride, 1M solution in methylene chloride
| 75-09-2 |
|
2,4,4-Trimethyl-2-Oxazoline, 99%
| 1772-43-6 |
|
4-Nitrophenyl Isothiocyanate
| 2131-61-5 |
|
Norephedrine Hydrochloride, 98% (Titr.)
| 3195-78-6 |
|
Diethyl phenylphosphonite, 99%
| 1638-86-4 |
|
2,3-Dichlorobutane, 98%
| 7581-97-7 |
|
1,1-Diphenylethylene, 99% (GC)
| 530-48-3 |
|
2-(N-Ethylperfluorooctanesulfonamido)ethyl methacrylate, stab. w/
| 92-84-2 |
|
1-Hydroxybenzotriazole, 98%
| 2592-95-2 |
|
3',4'-Dimethylacetophenone, 97%
| 3637-01-2 |
|
4-Chloro-alpha-methylbenzylamine, 97%
| 6299-02-1 |
|
4-Phenylazophenol, 97% (UV-Vis)
| 1689-82-3 |
|
Diethyl oxalate, 99%
| 95-92-1 |
|
l-Lysine dihydrochloride, 99%
| 657-26-1 |
|
2-Iodobenzoyl Chloride, 98+%
| 609-67-6 |
|
2-Chloronicotinamide, 98%
| 10366-35-5 |
|
2-Thenylmercaptan, 98%
| 6258-63-5 |
|
2-??4-(4-dimethylaminophenyl)-1,3- butadienyl??-3-ethylbenzothiazolium
| 114720-33-1 |
|
3-Chloro-2-methylpropionitrile, tech., 85+%
| 7659-45-2 |
|
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| 7732-18-5 |
|
Succinyl chloride, ca 95 %
| 543-20-4 |
|
2-Chloro-4-fluorobenzyl chloride, 98%
| 93286-22-7 |
|
1-(2,4-Dichlorophenyl)-1-Propanone 95%
| 37885-41-9 |
|
3-Ethoxyphenol, 98% (gc)
| 621-34-1 |
|
Rhodium on alumina powder (5% rh)
| |
|
Dibutyltin bis(2-ethylhexanoate)
| 2781-10-4 |
|
2,4-Diamino-6-phenyl-s-triazine, 99+% (titr.)
| 91-76-9 |
|
Ethyl Methylcarbamate, 99% (GC)
| 105-40-8 |
|
(4-Aminophenyl)trimethylammonium iodide hydrochloride, 94%
| 62654-12-0 |
|
2,2,5,5-Tetramethyl-3-Pyrrolidine- Carboxamide
| 702-96-5 |
|
Celestine blue
| 1562-90-9 |
|
1-(2-Furyl)-1,3-butanedione
| 25790-35-6 |
|
N-alpha-Benzoyl-dl-arginine-p-nitroanilide hydrochloride, 99+%
| 911-77-3 |
|
Hydroxy Naphthol Blue, Disodium Salt, P.A.
| 29114-66-7 |
|
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| 60-33-3 |
|
Octafluorotoluene, 98%
| 434-64-0 |
|
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| 124-65-2 |
|
2-Methoxyethyl Acetoacetate, 97%
| 22502-03-0 |
|
2-(2-Thienyl)pyridine, 97+%
| 3319-99-1 |
|
Naphthol green b
| 19381-50-1 |
|
2,4,5-Trimethyloxazole, 95%
| 20662-84-4 |
|
P-Arsanilic Acid, 99% (UV-Vis)
| 98-50-0 |
|
(S)-(+)-10-Methyl-1(9)-Octal-2-One,98.5%
| 4087-39-2 |
|
Indole-3-pyruvic acid , 97%
| 392-12-1 |
|
|