**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 62-38-4 |Phenylmercuric Acetate | >98 | 200-532-5 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T
Risk Phrases: 25 34 48/24/25
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Toxic if swallowed. Causes burns. Toxic : danger of serious damage
to health by prolonged exposure in contact with skin and if
swallowed.Light sensitive.Corrosive.Toxic.
Potential Health Effects
Eye:
Causes eye burns. May cause chemical conjunctivitis and corneal
damage.
Skin:
Causes skin burns. May cause skin rash (in milder cases), and cold
and clammy skin with cyanosis or pale color.
Ingestion:
May be fatal if swallowed. May cause severe and permanent damage to
the digestive tract. Causes gastrointestinal tract burns. May cause
perforation of the digestive tract. Inorganic mercury compounds may
cause central and peripheral nervous system effects. May cause
systemic effects.
Inhalation:
Causes chemical burns to the respiratory tract. Aspiration may lead
to pulmonary edema. May cause systemic effects. Acute exposure to
high concentrations of mercury vapors may cause severe respiratory
tract irritation.
Chronic:
Effects may be delayed. Chronic exposure to mercury may cause
permanent central nervous system damage, fatigue, weight loss,
tremors, personality changes. Chronic ingestion may cause
accumulation of mercury in body tissues. Chronic exposure to mercury
vapors may produce weakness, fatigue, anorexia, loss of weight and
gastrointestinal disturbances which is collectively referred to as
asthenic-vegetative syndrome or micromercurialism. Chronic exposure
to mercury compounds may produce immunologic glomerular disease.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Use only in a well-ventilated area. Minimize dust generation and
accumulation. Do not breathe dust, vapor, mist, or gas. Do not get in
eyes, on skin, or on clothing. Keep container tightly closed. Do not
ingest or inhale. Store protected from light. Discard contaminated
shoes.
Storage:
Keep container closed when not in use. Store in a cool, dry,
well-ventilated area away from incompatible substances. Corrosives
area. Store protected from light.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 62-38-4:
United States OSHA: 0.1 mg/m3 Ceiling (listed under Mercury, ary
and inorganic compounds).
Belgium - TWA: (listed as mercury, aryl and inorganic compounds):
mg/m3 VLE (as Hg)
France - VME: (listed as mercury, aryl and inorganic compounds):
mg/m3 VME (as Hg)
Germany: (listed as mercury, aryl and inorganic compounds): 0.1 m
VME (as Hg)
Malaysia: (listed as mercury, aryl and inorganic compounds): 0.1
mg/m3 TWA (as Hg)
Spain: (listed as mercury, aryl and inorganic compounds): 0.1 mg/
VLA-ED (as Hg)
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Color: white to cream
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 149 - 153 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: 2 G/L IN WATER (20C)
Specific Gravity/Density:
Molecular Formula: C8H8HgO2
Molecular Weight: 336.73
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Light, dust generation, excess heat, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 62-38-4: OV6475000
LD50/LC50:
CAS# 62-38-4: Draize test, rabbit, eye: 50 ug/24H Severe; Oral,
mouse: LD50 = 13250 ug/kg; Oral, rat: LD50 = 41 mg/kg.
Carcinogenicity:
Phenylmercuric Acetate -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENYLMERCURIC ACETATE
Hazard Class: 6.1
UN Number: 1674
Packing Group: II
IMO
Shipping Name: PHENYLMERCURIC ACETATE
Hazard Class: 6.1
UN Number: 1674
Packing Group: II
RID/ADR
Shipping Name: PHENYLMERCURIC ACETATE
Hazard Class: 6.1
UN Number: 1674
Packing group: II
USA RQ: CAS# 62-38-4: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T
Risk Phrases:
R 25 Toxic if swallowed.
R 34 Causes burns.
R 48/24/25 Toxic : danger of serious damage to
health by prolonged exposure in contact with skin and
if swallowed.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 62-38-4: 3
Canada
CAS# 62-38-4 is listed on Canada's DSL List.
CAS# 62-38-4 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 62-38-4 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 9/02/1997 Revision #4 Date: 12/03/2002
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
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|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Zincon, monosodium salt
| 62625-22-3 |
|
Propylamine, 98%
| 107-10-8 |
|
Phenylmercuric Acetate, 98.0-100.5%
| 62-38-4 |
|
Kaolin
| 1332-58-7 |
|
Triethyl orthoformate, 98%
| 122-51-0 |
|
n-Methylbenzylamine, 97%
| 103-67-3 |
|
Triphenylmethyl chloride
| 76-83-5 |
|
8-Hydroxy-1,3,6-Pyrenetrisulfonic Acid Trisodium Salt, 98% (UV-Vis)
| 6358-69-6 |
|
Trans-2-Aminocyclohexanol Hydrochloride, 99%
| 5456-63-3 |
|
Benzoin methyl ether, 96% (tlc)
| 3524-62-7 |
|
Heptanoic Acid, 98%
| 111-14-8 |
|
Diisobutylaluminum hydride(DIBAL-H), 1.0M solution in hexane
| 110-54-3 |
|
Diisobutylaluminum hydride (1.0M solution in toluene)
| 108-88-3 |
|
1-Phenyltridecane
| 123-02-4 |
|
Glycolic Acid, 99%
| 79-14-1 |
|
Phenylacetyl chloride, 98%
| 103-80-0 |
|
Rubidium Hydroxide, 99%, 50 wt% Solution In Water
| 1310-82-3 |
|
Adenosine 5'-Triphosphate, Disodium Salt Hydrate, 98%(HPLC)
| 987-65-5 |
|
TRICHLOROACETYL CHLORIDE, 99%
| 76-02-8 |
|
Silver Carbonate, 99%
| 534-16-7 |
|
Tetrabutylammonium Hydrogen Sulfate, 98%
| 32503-27-8 |
|
Adipoyl Chloride, 99+% (Titr.)
| 111-50-2 |
|
Benzylamine, 99%
| 100-46-9 |
|
1,3-Cyclopentanedione, 97%
| 3859-41-4 |
|
Poly(n-vinylcarbazole), secondary standard
| 25067-59-8 |
|
Nonanoic Acid, Tech., 90%
| 112-05-0 |
|
(D,L)-4-Fluoro-alpha-methylbenzylamine, 97%
| 403-40-7 |
|
Selenium(iv) oxide, p.a.
| 7446-08-4 |
|
Selenium(IV) oxide
| 7446-08-4 |
|
4'-Nitroacetanilide
| 104-04-1 |
|
Manganese(II) chloride, anhydrous
| 7773-01-5 |
|
Pinacolone, 96% (gc)
| 75-97-8 |
|
Cis-Dicyclohexano-18-Crown-6, Mixture of Syn-Cis and Anti-Cis
| 16069-36-6 |
|
cis-Dicyclohexano-18-crown-6, cis-anti-cis isomer, 98+%
| 15128-66-2 |
|
1-Nitroso-2-naphthol-3,6-disulfonic acid, disodium salt hydrate, 98%
| 525-05-3 |
|
2-Naphthol, 98%
| 135-19-3 |
|
2-Naphthol (techn)
| 135-19-3 |
|
3-Bromopropionic Acid, 97%
| 590-92-1 |
|
4'-Chloroacetophenone, 97%
| 99-91-2 |
|
Ethyl chloroformate, 99%
| 541-41-3 |
|
6-Chloro-1-Hexanol, 95%
| 2009-83-8 |
|
1,3-Cyclohexadiene, 96%, stabilized with 50 ppm BHT
| 592-57-4 |
|
N-(4-Chlorophenyl)-p-toluenesulfonamide, pract.
| 2903-34-6 |
|
Camphene, 80%
| 79-92-5 |
|
N,N'-Methylenebisacrylamide, 96%
| 110-26-9 |
|
3-Chlorobenzoic Acid, 99+%
| 535-80-8 |
|
3,5-Dimethylphenol, 98%
| 108-68-9 |
|
4-Chlorostyrene, stabilized with 0.1% tert-butylcatechol
| 98-29-3 |
|
Cyanogen Bromide, 97%
| 506-68-3 |
|
Tin, Powder, 99.9999%
| 7440-31-5 |
|
|