**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 623-00-7 |4-Bromobenzonitrile | 98 | 210-764-9 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XN
Risk Phrases: 20/21/22 36/37/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Harmful by inhalation, in contact with skin and if swallowed.
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. Can produce
delayed pulmonary edema.
Chronic:
Effects may be delayed.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. This
material in sufficient quantity and reduced particle size is capable
of creating a dust explosion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Remove contaminated clothing and wash before reuse. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Use with adequate ventilation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 623-00-7:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Crystalline powder
Color: slightly beige
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: 235-237 deg C @ 760 mmHg
Freezing/Melting Point: 111 - 114 deg C
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: C7H4BrN
Molecular Weight: 182.02
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong bases.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 623-00-7: DI2460000
LD50/LC50:
CAS# 623-00-7: Oral, mouse: LD50 = 237 mg/kg.
Carcinogenicity:
4-Bromobenzonitrile -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 8.13-8.71 mg/L; 5,15,30
min; Microtox test at 15C
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Nitriles, TOXIC, N.O.S.*
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
IMO
Shipping Name: NITRILES, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing Group: III
RID/ADR
Shipping Name: Nitriles, TOXIC, N.O.S.
Hazard Class: 6.1
UN Number: 3276
Packing group: III
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with
skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 623-00-7: 2
Canada
None of the chemicals in this product are listed on the DSL/NDSL list.
CAS# 623-00-7 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 623-00-7 is not listed on the TSCA inventory.
It is for research and development use only.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 6/08/1999 Revision #4 Date: 3/11/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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ALL MSDS PAGES IN THIS GROUP
| NAME | CAS |
Methyl 2-isocyano-3-methylpentanoate, 96%
| 0-01-1 |
4-Bromobenzonitrile, 98%
| 623-00-7 |
Methyl 3,4,5-Trihydroxybenzoate, 99 %
| 99-24-1 |
3-Hydroxy-2-nitropyridine, 97%
| 15128-82-2 |
Methyl 2-isocyano-3-methylbutyrate, 96%
| 40846-66-0 |
Methyl 3-isocyanopropionate, 96%
| 0-01-1 |
Methyl 2-isocyanopropionate, 96%
| 33115-74-1 |
1-Isocyano-3-isopropoxypropane, 96%
| 602262-07-7 |
1,1,3,3-Tetramethylbutyl isocyanide
| 14542-93-9 |
2,3-Dihydro-6-isocyano-1,4-benzodioxine, 95%
| 174092-82-1 |
Butyl Lactate, 99% (GC)
| 138-22-7 |
Dimethyl-d6 sulfate, 99+ atom % d
| 15199-43-6 |
Cyclopentyl isocyanide, 96%
| 68498-54-4 |
2-Cyclohexen-1-ylethyl isocyanide, 96%
| 172223-58-4 |
Diphenylmethyl isocyanide, 96%
| 3128-85-6 |
Methyl 2-isocyano-3-phenylpropionate, 96%
| 63157-14-2 |
alpha-Methylbenzyl isocyanide, 96%
| 17329-20-3 |
4-Fluorophenyl isocyanide, 95%
| 24075-34-1 |
3-Phenylpropyl isocyanide, 96%
| 111944-21-9 |
Phenylethyl isocyanide, 96%
| 59795-89-0 |
Benzo[a]pyrene, 96.5%
| 50-32-8 |
1-(Trifluoroacetyl)imidazole, 95%
| 1546-79-8 |
Ethylurea, 97%
| 625-52-5 |
1-Naphthalenemethanol, 98%
| 4780-79-4 |
Trimethylaluminum, 1,0M solution in heptane
| 75-24-1 |
Triisobutylaluminium, 1.1M solution in toluene
| 100-99-2 |
Ethylmagnesium chloride, 2.0M solution in THF
| 109-99-9 |
Triethylaluminium, 1,3M solution in heptane
| 97-93-8 |
Diethylzinc, 1,5M solution in toluene
| 108-88-3 |
Sodium thiophosphate hydrate
| 10489-48-2 |
cis-2,6-Dimethylmorpholine, 97%
| 6485-55-8 |
N-(2-Chloroethyl)pyrrolidine hydrochloride, 98%
| 7250-67-1 |
MP Alumina R, ICN material
| 1344-28-1 |
Tributylborane, 98%
| 122-56-5 |
L(-)-10-Camphorsulfonyl chloride
| 39262-22-1 |
Sodium cyanoborohydride, solution in THF
| 109-99-9 |
1-Phenyl-2-propanol, 99%
| 14898-87-4 |
N-(4-Dimethylamino-3,5-dinitrophenyl)maleimide
| 3475-74-9 |
8-Chloro-1-octanol, 98%
| 23144-52-7 |
1,10-Diamino-4,7-dioxadecane
| 2997-01-5 |
(4-Methoxybenzylidene)malonitrile, 98%
| 2826-26-8 |
1-(2-Hydroxyphenyl)piperazine, 98%
| 1011-17-2 |
5-Bromo-2-methylaniline, 98%
| 39478-78-9 |
1-Iodo-3-methylbutane, stabilized, 98%
| 541-28-6 |
2,4,6-Trivinylcyclotriboroxane-pyridine complex
| 92988-08-4 |
2-Methyl-5-nitroanisole, 99%
| 13120-77-9 |
Methyl 3-benzoylpropionate, 97%
| 25333-24-8 |
Ethyl 3-methylbenzoate, 98%
| 120-33-2 |
3,4-Dichlorostyrene, stabilized, 95%
| 2039-83-0 |
Dihydroquinine hydrobromide hydrate
| 0-01-1 |
|
|