**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Isopropyl alcohol | 78-82 | 200-661-7 |
|----------------|--------------------------------------|----------|-----------|
| 7647-01-0 |Hydrochloric acid | 18-22 | 231-595-7 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: T F C
Risk Phrases: 11 23 35 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Toxic by inhalation. Causes severe burns. Vapours
may cause drowsiness and dizziness.Hygroscopic (absorbs moisture
from the air).
Potential Health Effects
Eye:
May cause irreversible eye injury. Vapor or mist may cause
irritation and severe burns. Contact with liquid is corrosive to the
eyes and causes severe burns. May cause painful sensitization to
light.
Skin:
May be absorbed through the skin in harmful amounts. Contact with
liquid is corrosive and causes severe burns and ulceration.
Isopropanol has a low potential to cause allergic skin reactions;
however, rare cases of allergic contact dermatitis have been
reported.
Ingestion:
May cause kidney damage. May cause circulatory system failure. May
cause central nervous system depression, characterized by excitement,
followed by headache, dizziness, drowsiness, and nausea. Advanced
stages may cause collapse, unconsciousness, coma and possible death
due to respiratory failure. Aspiration of material into the lungs
may cause chemical pneumonitis, which may be fatal. May cause
corrosion and permanent tissue destruction of the esophagus and
digestive tract.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. May
cause narcotic effects in high concentration. Vapors may cause
dizziness or suffocation. Exposure to the mist and vapor may erode
exposed teeth. Causes corrosive action on the mucous membranes.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Repeated
exposure may cause erosion of teeth. Adverse reproductive effects
have been reported in animals. Repeated contact may cause corneal
damage. Prolonged exposure may cause conjunctivitis,
photosensitization, and possible blindness.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes). SPEEDY ACTION IS CRITICAL!
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Give milk of
magnesia.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Do NOT use sodium bicarbonate in an attempt to neutralize the acid.
Antidote:
Do NOT use oils or ointments in eye.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water runoff can cause environmental damage. Dike
and collect water used to fight fire. Vapors may form an explosive
mixture with air. Vapors can travel to a source of ignition and
flash back. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Will burn if
involved in a fire. Use water spray to keep fire-exposed containers
cool. Containers may explode in the heat of a fire. Flammable liquid
and vapor. May form explosive peroxides. Vapors may be heavier than
air. They can spread along the ground and collect in low or
confined areas. Reaction with water may generate much heat which will
increase the concentration of fumes in the air. Contact with metals
may evolve flammable hydrogen gas.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Water may be
ineffective. Use dry chemical, carbon dioxide, or alcohol-resistant
foam. Do NOT get water inside containers. Do NOT use straight
streams of water. Most foams will react with the material and
release corrosive/toxic gases. Cool containers with flooding
quantities of water until well after fire is out. For small fires,
use carbon dioxide (except for cyanides), dry chemical, dry sand,
and alcohol-resistant foam.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Large spills may be neutralized with dilute alkaline solutions of
soda ash (sodium carbonate, Na2CO3), or lime (calcium oxide, CaO).
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Remove all sources of ignition. Use a spark-proof
tool. Provide ventilation. Do not get water inside containers. A
vapor suppressing foam may be used to reduce vapors. Cover with dry
earth, dry sand, or other non-combustible material followed with
plastic sheet to minimize spreading and contact with water.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Use spark-proof tools and explosion proof equipment.
Contents may develop pressure upon prolonged storage. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Take precautionary measures against
static discharges. Keep container tightly closed. Do not ingest or
inhale. Use only in a chemical fume hood. Discard contaminated
shoes. Use caution when opening. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames. Keep from contact with moist air and steam.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Do not store in metal containers. Store protected
from moisture. Containers should be dated when opened and tested
periodically for the presence of peroxides. Should crystals form in
a peroxidizable liquid, peroxidation may have occurred and the
product should be considered extremely dangerous. In this instance,
the container should only be opened remotely by professionals.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use only under a chemical fume hood.
Exposure Limits
CAS# 67-63-0:
United Kingdom, WEL - TWA: 400 ppm TWA; 999 mg/m3 TWA
United Kingdom, WEL - STEL: 500 ppm STEL; 1250 mg/m3 STEL
United States OSHA: 400 ppm TWA; 980 mg/m3 TWA
Belgium - TWA: 400 ppm VLE; 997 mg/m3 VLE
Belgium - STEL: 500 ppm VLE; 1248 mg/m3 VLE
France - VLE: 400 ppm VLE; 980 mg/m3 VLE
Germany: 200 ppm TWA; 500 mg/m3 TWA
Japan: 400 ppm Ceiling; 980 mg/m3 Ceiling
Malaysia: 400 ppm TWA; 983 mg/m3 TWA
Netherlands: 250 ppm MAC; 650 mg/m3 MAC
Russia: 10 mg/m3 TWA
Spain: 400 ppm VLA-ED; 998 mg/m3 VLA-ED
Spain: 500 ppm VLA-EC; 1250 mg/m3 VLA-EC
CAS# 7647-01-0:
United Kingdom, WEL - TWA: 1 ppm TWA (aerosol mist and gas); 2 mg
TWA (aerosol mist and gas)
United Kingdom, WEL - STEL: 5 ppm STEL (aerosol mist and gas); 8
mg/m3 STEL (aerosol mist and gas)
United States OSHA: ; 5 ppm Ceiling; 7 mg/m3 Ceiling
Belgium - TWA: 5 ppm VLE; 8 mg/m3 VLE
Belgium - STEL: 10 ppm VLE; 15 mg/m3 VLE
France - VLE: 5 ppm VLE; 7.5 mg/m3 VLE
Germany: 8 mg/m3 TWA
Japan: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Malaysia: 5 ppm Ceiling; 7.5 mg/m3 Ceiling
Netherlands: 10 ppm STEL; 15 mg/m3 STEL
Netherlands: 5 ppm MAC; 8 mg/m3 MAC
Russia: 5 mg/m3 TWA
Spain: 5 ppm VLA-ED; 7.6 mg/m3 VLA-ED
Spain: 10 ppm VLA-EC; 15 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: 399 deg C ( 750.20 deg F)
Flash Point: 11 deg C ( 51.80 deg F)
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Miscible.
Specific Gravity/Density: .9090g/cm3
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form
and accumulate peroxides which may explode when subjected to heat or
shock. This material is most hazardous when peroxide levels are
concentrated by distillation or evaporation. Isopropanol is
susceptible to autoxidation and therefore should be classified as
peroxidizable.
Conditions to Avoid:
Light, ignition sources, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, acetic anhydride, alkali metals,
aluminum, amines, copper, copper alloys, fluorine, halogens, iron,
sodium hydroxide, steel, sulfuric acid, vinyl acetate, zinc, hydrogen
peroxide, potassium permanganate, cesium acetylene carbide, rubidium
acetylene carbide, rubidium carbide, sodium, acid anhydrides,
chlorosulfonic acid, oleum, chromium trioxide, phosgene, carbonates,
perchloric acid, calcium phosphide, potassium tert-butoxide, metal
oxides, acetates, cesium carbide, moisture, beta-propiolactone,
ethyleneimine, propylene oxide, Attacks some forms of plastics,
rubbers, and coatings., lithium silicides, alcohols + hydrogen
cyanide, 2-aminoethanol, ammonium hydroxide, calcium carbide,
1,1-difluoroethylene, ethylene diamine, magnesium boride, mercuric
sulfate, silver perchlorate + carbon tetrachloride, uranium
phosphide, 2-butanone, aluminum isopropoxide + crotonaldehyde +
heat, trinitiromethane, barium perchlorate, dioxygenyl
tetrafluoroborate, sodium dichrom.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, carbon monoxide, carbon dioxide,
hydrogen gas.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
CAS# 7647-01-0: MW4025000 MW4031000
LD50/LC50:
CAS# 67-63-0: Draize test, rabbit, eye: 100 mg Severe; Draize test,
rabbit, eye: 10 mg Moderate; Draize test, rabbit, eye: 100 mg/24H
Moderate; Draize test, rabbit, skin: 500 mg Mild; Inhalation, mouse:
LC50 = 53000 mg/m3; Inhalation, rat: LC50 = 16000 ppm/8H; Inhalation,
rat: LC50 = 72600 mg/m3; Oral, mouse: LD50 = 3600 mg/kg; Oral, mouse:
LD50 = 3600 mg/kg; Oral, rabbit: LD50 = 6410 mg/kg; Oral, rat: LD50 =
5045 mg/kg; Oral, rat: LD50 = 5000 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
CAS# 7647-01-0: Inhalation, mouse: LC50 = 1108 ppm/1H; Inhalation,
mouse: LC50 = 20487 mg/m3/5M; Inhalation, mouse: LC50 = 3940
mg/m3/30M; Inhalation, mouse: LC50 = 8300 mg/m3/30M; Inhalation,
rat: LC50 = 3124 ppm/1H; Inhalation, rat: LC50 = 60938 mg/m3/5M;
Inhalation, rat: LC50 = 7004 mg/m3/30M; Inhalation, rat: LC50 =
45000 mg/m3/5M; Inhalation, rat: LC50 = 8300 mg/m3/30M; Oral,
rabbit: LD50 = 900 mg/kg.
Carcinogenicity:
Isopropyl alcohol -
Not listed by ACGIH, IARC, or NTP.
Hydrochloric acid -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Goldfish: > 5000 mg/L; 24 Hr; CAS# 67-63-0 (modified ASTM D
1345 bioassay)Fish: Fathead Minnow: 11,830 mg/L; 1 Hr; CAS# 67-63-0
(static bioassay)Fish: Bluegill/Sunfish: 3.6 mg/L; 48Hr; CAS#
7647-01-0: Lethal (unspecified)Fish: Bluegill/Sunfish: LC50; 96 Hr;
CAS# 7647-01-0: pH 3.0-3.5CAS# 67-63-0: 2-Propanol is suggested to
volatilize and leach into ground water due partly to low soil
adsorption. In water, it will volatilize (estimated half-life = 5.4
days) and may biodegrade. 2-Propanol is not expected to adsorb to
aquatic sediment or bioconcentrate in fish. In the atmosphere it is
expected to photodegrade with a half-life of 1 to several days.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.*
Hazard Class: 3 (8)
UN Number: 2924
Packing Group: II
IMO
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3.2 (8)
UN Number: 2924
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class: 3 (8)
UN Number: 2924
Packing group: II
USA RQ: CAS# 7647-01-0: 5000 lb final RQ; 2270 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T F C
Risk Phrases:
R 11 Highly flammable.
R 23 Toxic by inhalation.
R 35 Causes severe burns.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 7 Keep container tightly closed.
S 16 Keep away from sources of ignition - No
smoking.
S 24/25 Avoid contact with skin and eyes.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
CAS# 7647-01-0: 1
Canada
CAS# 67-63-0 is listed on Canada's DSL List.
CAS# 7647-01-0 is listed on Canada's DSL List.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
CAS# 7647-01-0 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
CAS# 7647-01-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 36 Irritating to eyes.
R 36/37/38 Irritating to eyes, respiratory system and
skin.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 7/23/1999 Revision #5 Date: 9/30/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|