**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 67-63-0 |Test MSDS | 23 | 200-661-7 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: T+ T F+
Risk Phrases: 11 45 8 9
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. May cause cancer. Contact with combustible
material may cause fire. Explosive when mixed with combustible
material.
Potential Health Effects
Eye:
Dust may cause mechanical irritation. Causes moderate eye
irritation.
ut ygtuyg hjgjk
Skin:
Not available.
Ingestion:
Not available.
Inhalation:
Not available.
Chronic:
Not available.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Not available.
Skin:
Not available.
Ingestion:
Not available.
Inhalation:
Not available.
Notes to Physician:
Treat symptomatically and supportively.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
Not available.
Extinguishing Media:
Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
NFPA Rating: health-1; flammability-3; reactivity-0
Explosion Limits, Lower: Not available.
Upper: Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Not available.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Not available.
Storage:
Not available.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Personal Protective Equipment
Eyes:
Not available.
Skin:
Not available.
Clothing:
Not available.
Respirators:
Not available.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Solid
Appearance: white
Odor: aliphatic hydrocarbon odor
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 90 deg C
Decomposition Temperature: 67 deg F
Solubility: Not available.
Specific Gravity/Density: Not available.
Molecular Formula: HCl
Molecular Weight: 36.46
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Not available.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (mineral, oxidizing,
e.g. chromic acid, hypochlorous acid, nitric acid, sulfuric acid),
acids (organic, e.g. acetic acid, benzoic acid, formic acid,
methanoic acid, oxalic acid), azo, diazo, and hydrazines (e.g.
dimethyl hydrazine, hydrazine, methyl hydrazine), isocyanates (e.g.
methyl isocyanate), metals (alkali and alkaline, e.g. cesium,
potassium, sodium), nitrides (e.g. potassium nitride, sodium
nitride), peroxides and hydroperoxides (organic, e.g. acetyl
peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone
peroxide), epoxides (e.g. butyl glycidyl ether), oxidizing agents
(strong, e.g. bromine, hydrogen peroxide, nitrogen dioxide,
potassium nitrate), reducing agents (strong, e.g. aluminum carbide,
chlorosilane, hydrogen phosphide, lithium hydride), water reactive
substances (e.g. acetic anyhdride, alkyl aluminum chloride, calcium
carbide, ethyl dichlorosilane).
Hazardous Decomposition Products:
Not available.
Hazardous Polymerization: Has not been reported.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-63-0: NT8050000
LD50/LC50:
CAS# 67-63-0: Oral, mouse: LD50 = 3600 mg/kg; Oral, rabbit: LD50 =
6410 mg/kg; Oral, rat: LD50 = 5045 mg/kg; Skin, rabbit: LD50 = 12800
mg/kg.
Carcinogenicity:
Test MSDS -
IARC: Group 3 carcinogen
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
For further information, contact Fisher Scientific.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
CDG/CPL
IMO
Shipping Name: NITROBENZENE
Hazard Class: 6.1
UN Number: 1662
Packing Group: II
IATA
Shipping Name: NITROBENZENE
Hazard Class: 6.1
UN Number: 1662
Packing Group: II
RID/ADR
Shipping Name: NITROBENZENE
Dangerous Goods Code: 6.1(12B)
UN Number: 1662
Canadian TDG
No information available.
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: T+ T F+
Risk Phrases:
R 11 Highly flammable.
R 45 May cause cancer.
R 8 Contact with combustible material may cause
fire.
R 9 Explosive when mixed with combustible material.
Safety Phrases:
S 14 Keep away from ... (incompatible materials to
be indicated by the manufacturer).
S 17 Keep away from combustible material.
WGK (Water Danger/Protection)
CAS# 67-63-0: 1
Canada
CAS# 67-63-0 is listed on Canada's DSL/NDSL List.
WHMIS: Not available.
CAS# 67-63-0 is listed on Canada's Ingredient Disclosure List.
Exposure Limits
CAS# 67-63-0:. OEL-AUSTRALIA:TWA 400 ppm (980 mg/m3);STEL 500 ppm (12
25 mg/m3). OEL-BELGIUM:TWA 400 ppm (985 mg/m3);STEL 500 ppm (1230 mg/m
3). OEL-DENMARK:TWA 200 ppm (490 mg/m3);Skin. OEL-FRANCE:STEL 400 ppm
(980 mg/m3). OEL-GERMANY:TWA 400 ppm (980 mg/m3). OEL-JAPAN:STEL 400 p
pm (980 mg/m3). OEL-THE NETHERLANDS:TWA 400 ppm (980 mg/m3);Skin. OEL-
THE PHILIPPINES:TWA 400 ppm (980 mg/m3). OEL-RUSSIA:STEL 400 ppm (10 m
g/m3). OEL-SWEDEN:TWA 150 ppm (350 mg/m3);STEL 250 ppm (600 mg/m3). OE
L-SWITZERLAND:TWA 400 ppm (980 mg/m3);STEL 800 ppm. OEL-TURKEY:TWA 200
ppm (500 mg/m3). OEL-UNITED KINGDOM:TWA 400 ppm (980 mg/m3);STEL 500
ppm;Skin. OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV. OE
L IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV
US FEDERAL
TSCA
CAS# 67-63-0 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/29/1996 Revision #2 Date: 9/03/1997
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
|
|
|