**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 67-64-1 |Acetone | 43-69 | 200-662-2 |
|----------------|--------------------------------------|----------|-----------|
| 84-74-2 |Dibutyl phthalate | 3-5 | 201-557-4 |
|----------------|--------------------------------------|----------|-----------|
| 1330-20-7 |Xylenes (o-, m-, p- isomers) | 12-24 | 215-535-7 |
|----------------|--------------------------------------|----------|-----------|
| 9003-63-8 |2-propenoic acid, 2-methyl-, butyl est| 16-28 | unlisted |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: XN F
Risk Phrases: 11 20/21 36/38 66 67
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Highly flammable. Harmful by inhalation and in contact with skin.
Irritating to eyes and skin. Repeated exposure may cause skin
dryness or cracking. Vapours may cause drowsiness and dizziness.
Potential Health Effects
Eye:
Produces irritation, characterized by a burning sensation, redness,
tearing, inflammation, and possible corneal injury.
Skin:
Causes skin irritation. Skin absorption is slight. Prolonged
exposure may cause the formation of vesicles (blisters). Contact with
the skin causes erythema (redness), dryness, and defatting.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract. May
cause central nervous system depression, characterized by
excitement, followed by headache, dizziness, drowsiness, and nausea.
Advanced stages may cause collapse, unconsciousness, coma and
possible death due to respiratory failure. May cause effects similar
to those of acute inhalation.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. Prolonged exposure may result in dizziness and general
weakness. Irritation may lead to chemical pneumonitis and pulmonary
edema. May cause liver and kidney damage. May cause motor
incoordination and speech abnormalities. Exposure may cause blood
abnormalities. May cause irritation of the mucous membranes. May
cause hyperplasia (the abnormal multiplication or increase in the
number of normal cells in normal arrangement) of the bone and spleen.
Chronic:
Chronic exposure to organic solvents has been associated with
various neurotoxic effects including permanent brain and nervous
system damage. Prolonged or repeated skin contact may cause
dermatitis.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further
exposure.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Possible aspiration hazard. Get medical aid
immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Use water spray to keep fire-exposed containers cool. Flammable
liquid and vapor. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. May be
ignited by heat, sparks, and flame. Vapors may form an explosive
mixture with air. Containers may explode when heated.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water. For large fires, use dry chemical, carbon dioxide,
alcohol-resistant foam, or water spray.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation. A vapor suppressing foam may be used to reduce
vapors. Water spray may reduce vapor but may not prevent ignition in
closed spaces.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Avoid contact with eyes, skin,
and clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Keep from contact with oxidizing
materials. Store in a cool, dry, well-ventilated area away from
incompatible substances.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 67-64-1:
United Kingdom, WEL - TWA: 500 ppm TWA; 1210 mg/m3 TWA
United Kingdom, WEL - STEL: 1500 ppm STEL; 3620 mg/m3 STEL
United States OSHA: 1000 ppm TWA; 2400 mg/m3 TWA
Belgium - TWA: 500 ppm VLE; 1210 mg/m3 VLE
Belgium - STEL: 1000 ppm VLE; 2420 mg/m3 VLE
France - VME: 750 ppm VME; 1800 mg/m3 VME
Germany: 500 ppm TWA; 1200 mg/m3 TWA
Japan: 200 ppm OEL; 470 mg/m3 OEL
Malaysia: 500 ppm TWA; 1187 mg/m3 TWA
Netherlands: 750 ppm MAC; 1780 mg/m3 MAC
Russia: 200 mg/m3 TWA
Spain: 500 ppm VLA-ED; 1210 mg/m3 VLA-ED
CAS# 84-74-2:
United Kingdom, WEL - TWA: 5 mg/m3 TWA
United Kingdom, WEL - STEL: 10 mg/m3 STEL
United States OSHA: 5 mg/m3 TWA
Belgium - TWA: 5 mg/m3 VLE
France - VME: 5 mg/m3 VME
Japan: 5 mg/m3 OEL
Malaysia: 1 ppm TWA; 8.6 mg/m3 TWA
Russia: 0.5 mg/m3 TWA
Spain: 5 mg/m3 VLA-ED
CAS# 1330-20-7:
United Kingdom, WEL - TWA: 50 ppm TWA; 220 mg/m3 TWA
United Kingdom, WEL - STEL: 100 ppm STEL; 441 mg/m3 STEL
United States OSHA: 100 ppm TWA; 435 mg/m3 TWA
Belgium - TWA: 50 ppm VLE; 221 mg/m3 VLE
Belgium - STEL: 150 ppm VLE; 442 mg/m3 VLE
France - VME: 100 ppm VME; 435 mg/m3 VME
France - VLE: 150 ppm VLE; 650 mg/m3 VLE
Germany: 100 ppm TWA; 440 mg/m3 TWA
Germany: Skin absorber
Japan: 50 ppm OEL; 217 mg/m3 OEL
Malaysia: 199 ppm TWA; 434 mg/m3 TWA
Netherlands: 50 ppm MAC; 210 mg/m3 MAC
Russia: 50 mg/m3 TWA
Spain: 50 ppm VLA-ED; 221 mg/m3 VLA-ED
Spain: 100 ppm VLA-EC; 442 mg/m3 VLA-EC
CAS# 9003-63-8:
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless
Odor: acetone-like
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water:
Specific Gravity/Density:
Molecular Formula: Solution
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
High temperatures, incompatible materials, ignition sources.
Incompatibilities with Other Materials:
Perchlorates, aliphatic amines, chromyl chloride, hexachloromelamine,
chromic anhydride, chloroform + alkali, potassium-tert-butoxide,
strong acids, 1,3-Dichloro-5,5-dimethyl-2,4-imidazolidindione
(dichlorohydrantoin), Attacks some forms of plastics, rubber, and
coatings..
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 67-64-1: AL3150000
CAS# 84-74-2: TI0875000
CAS# 1330-20-7: ZE2100000
CAS# 9003-63-8: UD3399000
LD50/LC50:
CAS# 67-64-1: Dermal, guinea pig: LD50 = >9400 uL/kg; Draize test,
rabbit, eye: 20 mg Severe; Draize test, rabbit, eye: 20 mg/24H
Moderate; Draize test, rabbit, eye: 10 uL Mild; Draize test, rabbit,
skin: 500 mg/24H Mild; Inhalation, mouse: LC50 = 44 gm/m3/4H;
Inhalation, rat: LC50 = 50100 mg/m3/8H; Oral, mouse: LD50 = 3 gm/kg;
Oral, rabbit: LD50 = 5340 mg/kg; Oral, rat: LD50 = 5800 mg/kg.
CAS# 84-74-2: Inhalation, mouse: LC50 = 25 gm/m3/2H; Inhalation,
rat: LC50 = 4250 mg/m3; Oral, mouse: LD50 = 3474 mg/kg; Oral, rat:
LD50 = 7499 mg/kg; Skin, rabbit: LD50 = >20 mL/kg.
CAS# 1330-20-7: Draize test, rabbit, eye: 87 mg Mild; Draize test,
rabbit, eye: 5 mg/24H Severe; Draize test, rabbit, skin: 100%
Moderate; Draize test, rabbit, skin: 500 mg/24H Moderate; Inhalation,
rat: LC50 = 5000 ppm/4H; Oral, mouse: LD50 = 2119 mg/kg; Oral, rat:
LD50 = 4300 mg/kg; Skin, rabbit: LD50 = >1700 mg/kg.
CAS# 9003-63-8.
Carcinogenicity:
Acetone -
Not listed by ACGIH, IARC, or NTP.
Dibutyl phthalate -
Not listed by ACGIH, IARC, or NTP.
Xylenes (o-, m-, p- isomers) -
Not listed by ACGIH, IARC, or NTP.
2-propenoic acid, 2-methyl-, butyl ester, homopolymer -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Ecotoxicity:
Fish: Rainbow trout: LC50 = 13.5 mg/L; 96 Hr; UnspecifiedFish:
Goldfish: LD50 = 13 mg/L; 24 Hr; UnspecifiedFish: Fathead Minnow:
LC50 = 46 mg/L; 1 Hr; Static bioassayAcute and long-term toxicity to
fish and invertebrates: LD50 for goldfish is 13 mg/L/24
Hr.
Cas#1330-20-7:
LC50(96Hr.) rainbow trout = 8.05 mg/L, Static
condition;
LC50(96Hr.) fathead minnow = 16.1 mg/L, flow-through
conditions; LC50(96Hr.) bluegill = 16.1 mg/L, flow-through;
EC50 (48
Hr.) water flea = 3.82 mg/L, flow-through conditions;
EC50(24 Hr.)
photobacterium phosphoreum = 0.0084 mg/L, Microtox test.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: FLAMMABLE SOLID, N.O.S. (CONTAINS ACETONE AND XYLE
NES)
Hazard Class: 3
UN Number: 1993
Packing Group: II
IMO
Shipping Name: FLAMMABLE SOLID, N.O.S. (CONTAINS ACETONE AND XYLE
NES)
Hazard Class: 3
UN Number: 1993
Packing Group: II
RID/ADR
Shipping Name: FLAMMABLE SOLID, N.O.S. (CONTAINS ACETONE AND XYLE
NES)
Hazard Class: 3,3b
UN Number: 1993
Packing group: II
USA RQ: CAS# 67-64-1: 5000 lb final RQ; 2270 kg final RQ
USA RQ: CAS# 84-74-2: 10 lb final RQ; 4.54 kg final RQ
USA RQ: CAS# 1330-20-7: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XN F
Risk Phrases:
R 11 Highly flammable.
R 20/21 Harmful by inhalation and in contact with
skin.
R 36/38 Irritating to eyes and skin.
R 66 Repeated exposure may cause skin dryness or
cracking.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 9 Keep container in a well-ventilated place.
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
WGK (Water Danger/Protection)
CAS# 67-64-1: 0
CAS# 84-74-2: 2
CAS# 1330-20-7: 2
CAS# 9003-63-8: No information available.
Canada
CAS# 67-64-1 is listed on Canada's DSL List.
CAS# 84-74-2 is listed on Canada's DSL List.
CAS# 1330-20-7 is listed on Canada's DSL List.
CAS# 9003-63-8 is listed on Canada's DSL List.
CAS# 67-64-1 is listed on Canada's Ingredient Disclosure List.
CAS# 84-74-2 is listed on Canada's Ingredient Disclosure List.
CAS# 1330-20-7 is not listed on Canada's Ingredient Disclosure List.
CAS# 9003-63-8 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 67-64-1 is listed on the TSCA inventory.
CAS# 84-74-2 is listed on the TSCA inventory.
CAS# 1330-20-7 is listed on the TSCA inventory.
CAS# 9003-63-8 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 11 Highly flammable.
R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or cracking.
R 67 Vapours may cause drowsiness and dizziness.
MSDS Creation Date: 4/20/2001 Revision #3 Date: 10/05/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
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