**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 7664-39-3 |Hydrogen fluoride | <0.1 | 231-634-8 |
|----------------|--------------------------------------|----------|-----------|
| 7732-18-5 |Water | >99 | 231-791-2 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: None Listed.
Risk Phrases: None Listed.
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Not available.
Potential Health Effects
Eye:
Non-irritating to the eyes.
Skin:
Non-irritating to the skin.
Ingestion:
Low hazard for usual industrial handling.
Inhalation:
Low hazard for usual industrial handling.
Chronic:
None
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation
develops, get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Wash mouth out with water. Get medical aid if irritation or symptoms
occur.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Material will not burn. During a fire, irritating
and highly toxic gases may be generated by thermal decomposition or
combustion.
Extinguishing Media:
Not available.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash hands before eating. Use with adequate ventilation. No special
handling procedures are required.
Storage:
No special precautions indicated. No special storage requirements.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
There are no special ventilation requirements. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7664-39-3:
United Kingdom, WEL - TWA: 1.8 ppm TWA (as F); 1.5 mg/m3 TWA (as
United Kingdom, WEL - STEL: 3 ppm STEL (as F); 2.5 mg/m3 STEL (as
United States OSHA: 3 ppm TWA
Belgium - TWA: 1.8 ppm VLE; 1.5 mg/m3 VLE
Belgium - STEL: 3 ppm VLE; 2.5 mg/m3 VLE
France - VLE: 3 ppm VLE; 2.5 mg/m3 VLE
Germany: 3 ppm TWA; 2.5 mg/m3 TWA
Germany: Skin absorber
Japan: 3 ppm Ceiling; 2.5 mg/m3 Ceiling
Malaysia: 3 ppm Ceiling (as F); 2.3 mg/m3 Ceiling (as F)
Netherlands: 3.3 ppm STEL; 2.5 mg/m3 STEL (as F)
Russia: 0.5 mg/m3 TWA
Russia: 0.1 mg/m3 STEL
Spain: 1.8 ppm VLA-ED; 1.5 mg/m3 VLA-ED
Spain: 3 ppm VLA-EC; 2.5 mg/m3 VLA-EC
CAS# 7732-18-5:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: colorless - Clear - water-white
Odor: odorless
pH: Not available.
Vapor Pressure: 17.5 mm Hg @ 20 deg C.
Viscosity: 1 cP @ 20C
Boiling Point: 100 deg C
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature: Not available.
Solubility in water: Not available.
Specific Gravity/Density: 1.000
Molecular Formula: H2O
Molecular Weight: 18.0134
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable.
Conditions to Avoid:
None reported.
Incompatibilities with Other Materials:
None.
Hazardous Decomposition Products:
None.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7664-39-3: MW7875000
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 7664-39-3: Inhalation, mouse: LC50 = 342 ppm/1H; Inhalation,
mouse: LC50 = 5000 mg/m3/5M; Inhalation, mouse: LC50 = 270
mg/m3/60M; Inhalation, rat: LC50 = 1276 ppm/1H; Inhalation, rat: LC50
= 1100 mg/m3/60M.
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg.
Carcinogenicity:
Hydrogen fluoride -
Not listed by ACGIH, IARC, or NTP.
Water -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.
USA RQ: CAS# 7664-39-3: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7664-39-3: 1
CAS# 7732-18-5: No information available.
Canada
CAS# 7664-39-3 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7664-39-3 is listed on Canada's Ingredient Disclosure List.
CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7664-39-3 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
MSDS Creation Date: 4/27/2001 Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Antimony Silicate (Tungsten Doped)
| 1314-35-8 |
|
Beryllium atomic absorption standard solution, 1mg/ml Be in 2% HNO3
| 7440-41-7 |
|
Ammonium Standard, 1000ppm (as N)
| 7732-18-5 |
|
1-Bromopropane, 99%
| 106-94-5 |
|
Thallium Atomic Absorption Standard Solution, 1mg.ml Tl in 2% HNO3
| 7440-28-0 |
|
1,4-Dioxane, Reagent ACS
| 123-91-1 |
|
GASAB
| 0-01-1 |
|
Nicotine Solution, Cigarette
| 0-01-1 |
|
1,6-Heptadien-4-ol, 97%
| 2883-45-6 |
|
Carbol Fuchsin
| 108-95-2 |
|
(S)-2-Amino-3-Methoxypropanoic Acid, 98%
| 32620-11-4 |
|
(R)-(-)-5-Hydroxymethyl-2-Pyrroldinone
| 66673-40-3 |
|
(S)-(+)-5-Triloxymethyl-2-Pyrrolidinone
| 105526-85-0 |
|
N,N-Didecyl-1-Decanamine (Pract) (Isomeric Mixture)
| 1070-01-5 |
|
R-(+)-3-Pyrrolidinol
| 2799-21-5 |
|
Ruthenium atomic absorption standard solution, 1 mg/ml ru in 10% hcl
| |
|
Isophthalaldehyde, 99%
| 626-19-7 |
|
3-(Methylthio)propionaldehyde, 95% (GC)
| 3268-49-3 |
|
3-Nitropropionic acid, 99%
| 504-88-1 |
|
Chromium standard metal solution in 2% nitric acid
| 7440-47-3 |
|
Cobalt Chloride
| 7646-79-9 |
|
Arsenic standard metal solution, 1000 ppm in 2% HNO3
| 1327-53-3 |
|
n-(3-Bromopropyl)-phthalimide
| 5460-29-7 |
|
2-Hydroxymethyl-1,4-Benzodioxan, 98%(GC)
| 3663-82-9 |
|
Cyclohexanebutyric acid, 99%
| 4441-63-8 |
|
ICP Standard Metal Solution in Hydrochloric Acid
| 0-00-0 |
|
Arsenic standard metal solution, 10000 ppm in 5% HNO3
| 1327-53-3 |
|
2-Methyl-3-Methoxypyrazine, 70-90%, Balance 10-30%
| 63450-30-6 |
|
CRANCO
| 67-64-1 |
|
2,4'-Dibromoacetophenone, 98%
| 99-73-0 |
|
2,3-Diaminopropionic Acid Hydrobromide 98 %
| 18635-45-5 |
|
Matrix 1
| 7732-18-5 |
|
Matrix 2
| 7664-39-3 |
|
Matrix 3
| 7664-39-3 |
|
Beryllium acetate
| 19049-40-2 |
|
Hafnium oxychloride octahydrate
| 13759-17-6 |
|
Ammonium Hexafluorotantalate
| 33380-11-9 |
|
Ammonium Tetraborate
| 0-01-1 |
|
3-Amino-2,4-dimethylpentane, 98+%
| 4083-57-2 |
|
3-Bromo-4-Fluorobenzonitrile, 98%
| 79630-23-2 |
|
Sodium dichromate
| 10588-01-9 |
|
2,4-Dinitrofluorobenzene
| 70-34-8 |
|
Phenylmalonic acid, 99%
| 2613-89-0 |
|
Carbonylbis-(triphenylphosphine)-rhodium (I) chloride
| 13938-94-8 |
|
2,2'-Methylenebisbenzothiazole, 97%
| 1945-78-4 |
|
Chromosulfuric acid
| 7664-93-9 |
|
Lead (II) Hydroxyacetate
| 0-01-1 |
|
Ethyl 3,4,5-Trimethoxybenzoylacetate
| |
|
Hydrofluoric Acid (Hydrogen Fluoride, liquefied)
| 7664-39-3 |
|
Lactic acid, reagent ACS
| 50-21-5 |
|
|