**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
| 7681-52-9 |Sodium Hypochlorite, 5% Active Chlorin| ca. 95.0 | 231-668-3 |
+----------------+--------------------------------------+----------+-----------+
Hazard Symbols: XI
Risk Phrases: 31 36/38
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Contact with acids liberates toxic gas. Irritating to eyes and
skin.Corrosive.Light sensitive.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract.
Chronic:
No information found.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately. Do NOT allow victim to rub eyes or keep eyes closed.
Extensive irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Do not induce vomiting. Never give anything by mouth to an
unconscious person. Get medical aid immediately. Wash mouth out with
water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Antidote:
None reported.
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Substance
is noncombustible. Oxidizer. Greatly increases the burning rate of
combustible materials.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin
and eyes. Do not get in eyes, on skin, or on clothing. Keep container
tightly closed. Do not ingest or inhale. Use with adequate
ventilation. Use only in a chemical fume hood. Discard contaminated
shoes.
Storage:
Keep container closed when not in use. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances. Keep refrigerated. (Store below 4C/39F.)
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 7681-52-9:
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: clear colorless to pale yellow
Odor: Disagreeable, sweetish odor
pH: Not available.
Vapor Pressure: 17.5 mm Hg @ 20C
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: N/A
Explosion Limits, upper: N/A
Decomposition Temperature:
Solubility in water: soluble in water
Specific Gravity/Density: 1.097
Molecular Formula: ClNaO
Molecular Weight: 74.44
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures. Anhydrous salt is
highly explosive and sensitive to heat or friction. Decomposed by
hot water.
Conditions to Avoid:
Incompatible materials, light, combustible materials, strong acids.
Incompatibilities with Other Materials:
Strong oxidizing agents, ammonium nitrate, methanol,
phenylacetonitrile, ammonium oxalate, ethyleneimine, azardine,
Reaction with formic acid at 55C becomes explosive.
Hazardous Decomposition Products:
Hydrogen chloride, chlorine, sodium oxide.
Hazardous Polymerization: Will not occur.
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 7681-52-9: NH3486300
LD50/LC50:
CAS# 7681-52-9: Draize test, rabbit, eye: 10 mg Moderate; Draize
test, rabbit, eye: 1.31 mg Mild; Oral, mouse: LD50 = 5800 mg/kg.
Carcinogenicity:
Sodium Hypochlorite, 5% Active Chlorine, Reagent -
Not listed by ACGIH, IARC, or NTP.
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
Other
No information available.
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Dispose of in a manner consistent with federal, state, and local regulations.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
IMO
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing Group:
RID/ADR
Shipping Name: Not regulated.
Hazard Class:
UN Number:
Packing group:
USA RQ: CAS# 7681-52-9: 100 lb final RQ; 45.4 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 31 Contact with acids liberates toxic gas.
R 36/38 Irritating to eyes and skin.
Safety Phrases:
S 28A After contact with skin, wash immediately with
plenty of water.
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 50 Do not mix with ... (to be specified by the
manufacturer).
S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7681-52-9: 2
Canada
CAS# 7681-52-9 is listed on Canada's DSL List.
CAS# 7681-52-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 7681-52-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
MSDS Creation Date: 2/03/1999 Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|
| ALL MSDS PAGES IN THIS GROUP
| | NAME | CAS |
|
Chloroacetic Acid, P.A.
| 79-11-8 |
|
N-Formyl-3-Methoxy-Morpholine, 95%
| 61020-09-5 |
|
Chloroacetic Acid, Flakes, 99%
| 79-11-8 |
|
Methanesulfonic Acid, Tech., 70%
| 75-75-2 |
|
Formic Acid, Reagent ACS, 96+% (Titr.)
| 64-18-6 |
|
Formic Acid, Reagent ACS, 88+% (Titr.)
| 64-18-6 |
|
Formic Acid, P.A.
| 64-18-6 |
|
Formic Acid, 99%
| 64-18-6 |
|
Hydrochloric Acid 1 N or 1 M Solution
| 7647-01-0 |
|
Hydrochloric Acid, C.P.
| 7647-01-0 |
|
2,3,4,6-Tetra-o-acetyl-alpha-d-glucopyrano syl bromide, 98.5%,
| 572-09-6 |
|
Hydrochloric Acid, Reagent ACS
| 7647-01-0 |
|
Hydrochloric Acid, P.A., Min. 37%
| 7647-01-0 |
|
Inosine 5'-Monophosphate, Disodium Salt Hydrate, 99+%
| 4691-65-0 |
|
Hydrochloric Acid, 0.1N Standard Solution
| 7647-01-0 |
|
Hydrochloric Acid, 1N Standard Solution
| 7647-01-0 |
|
Methyl 3-Trifluoromethylbenzoylacetate
| |
|
Deuterium Chloride, 20 wt% Solution in D2O 99+ Atom % D
| 7698-05-7 |
|
]1,3-Benzodioxole, 99%
| 274-09-9 |
|
Deuterium Oxide, 100.0 Atom % D
| 7789-20-0 |
|
Deuterium Oxide, 100.0 Atom % D Low in Paramagnetic Impurities
| 7789-20-0 |
|
Octamethyltrisiloxane, 98%
| 107-51-7 |
|
Water, Deuterium-Depleted
| 7732-18-5 |
|
Water for HPLC
| 7732-18-5 |
|
Ammonium Iron (II) Sulfate Hexahydrate, P.A.
| 7783-85-9 |
|
Ammonium Iron (II) Sulfate Hexahydrate, Reagent ACS (Crystals)
| 7783-85-9 |
|
Ammonium iron(iii) sulfate dodecahydrate, p.a.
| 7783-83-7 |
|
Ammonium iron(iii) sulfate dodecahydrate, reagent acs (crystals)
| 7783-83-7 |
|
Methyl Butyrate, 99% (GC)
| 623-42-7 |
|
Diphenylamine, 99%
| 122-39-4 |
|
Hydrochloric Acid 5 to 6N Solution in 2-Propanol
| 67-63-0 |
|
2,3-Benzofluorene, Tech.,90%
| 243-17-4 |
|
Diphenylamine, p.a.; redox-indicator
| 122-39-4 |
|
Silicon (IV) Chloride, 99.8+%
| 10026-04-7 |
|
Diphenylamine, reagent acs
| 122-39-4 |
|
Sodium Hypochlorite (5% Chlorine), Reagent
| 7681-52-9 |
|
Hydrochloric acid, 0.5N solution
| 7647-01-0 |
|
Hydrochloric acid, 2N solution
| 7647-01-0 |
|
Hydrochloric Acid, 1:1 Aqueous Solution
| 7647-01-0 |
|
Ferric Ammonium Sulfate Indicator Solution
| 7664-93-9 |
|
Hexamine Solution
| 100-97-0 |
|
Perchloric Acid, 0.100 N Solution
| 64-19-7 |
|
Phenolphthalein, 0.5% IPA Solution
| 67-63-0 |
|
Test MSDS
| 67-63-0 |
|
This is new.
| |
|
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| |
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fgfghjfgkh
| 4252-78-2 |
|
Sodium hydroxide, purum, pellets
| 1310-73-2 |
|
Sodium hydroxide, pellets, p.a.
| 1310-73-2 |
|
Sodium hydroxide, reagent ACS, pellets, 97+%
| 1310-73-2 |
|
|