**** SECTION 2 - COMPOSITION, INFORMATION ON INGREDIENTS ****
+----------------+--------------------------------------+----------+-----------+
| CAS# | Chemical Name | % | EINECS# |
|----------------|--------------------------------------|----------|-----------|
|----------------|--------------------------------------|----------|-----------|
| 96-77-5 |Phenol disulfonic acid solution | 25% | 202-533-6 |
|----------------|--------------------------------------|----------|-----------|
| 7664-93-9 |Sulfuric acid | 75% | 231-639-5 |
+----------------+--------------------------------------+----------+-----------+
Text for R-phrases: see Section 16
Hazard Symbols: C
Risk Phrases: 35
**** SECTION 3 - HAZARDS IDENTIFICATION ****
EMERGENCY OVERVIEW
Causes severe burns.Corrosive.Water-reactive.
Potential Health Effects
Eye:
Contact with liquid is corrosive to the eyes and causes severe
burns. May cause eye injury.
Skin:
Contact with liquid is corrosive and causes severe burns and
ulceration.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May cause corrosion and permanent
tissue destruction of the esophagus and digestive tract.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema.
Chronic:
Repeated inhalation may cause chronic bronchitis. Repeated exposure
may cause erosion of teeth.
**** SECTION 4 - FIRST AID MEASURES ****
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
**** SECTION 5 - FIRE FIGHTING MEASURES ****
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Reacts
violently with water.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use extinguishing
media most appropriate for the surrounding fire. If water is the only
media available, use in flooding amounts.
**** SECTION 6 - ACCIDENTAL RELEASE MEASURES ****
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Cover with sand, dry lime or soda ash and place in
a closed container for disposal. Isolate area and deny entry. Provide
ventilation.
**** SECTION 7 - HANDLING and STORAGE ****
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with clothing and other combustible materials. Do not
get on skin or in eyes. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Corrosives area.
**** SECTION 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION ****
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
CAS# 96-77-5:
CAS# 7664-93-9:
United States OSHA: 1 mg/m3 TWA
Belgium - TWA: 1 mg/m3 VLE
Belgium - STEL: 3 mg/m3 VLE
France - VME: 1 mg/m3 VME
France - VLE: 3 mg/m3 VLE
Germany: 0.5 mg/m3 TWA (inhalable fraction, battery manufacture,
metal working in a close
Japan: 1 mg/m3 Ceiling
Malaysia: 1 mg/m3 TWA
Netherlands: 1 mg/m3 MAC
Russia: 1 mg/m3 TWA
Spain: 1 mg/m3 VLA-ED
Spain: 3 mg/m3 VLA-EC
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
**** SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES ****
Physical State: Liquid
Color: light pink
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: Not available.
Autoignition Temperature: Not applicable.
Flash Point: Not applicable.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Reacts with water.
Specific Gravity/Density: 1.40
Molecular Formula: Mixture
Molecular Weight: 0
**** SECTION 10 - STABILITY AND REACTIVITY ****
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, combustible materials.
Incompatibilities with Other Materials:
Bases; halides; metals; carbides; chlorates; fulminates; nitrates;
picrates; cyanides; alkali halides; nitrites; zinc iodide;
permanganates; hydrogen peroxide; azides; perchlorates; nitromethane;
phosphorus. Sulfuric acid reacts violently with water;
cyclopentadiene; cyclopentanone oxime; nitroaryl amines; hexalithium
disilicide; phosphorous (III) oxide.
Hazardous Decomposition Products:
Carbon monoxide, oxides of sulfur, carbon dioxide.
Hazardous Polymerization: Has not been reported
**** SECTION 11 - TOXICOLOGICAL INFORMATION ****
RTECS#:
CAS# 96-77-5 unlisted.
CAS# 7664-93-9: WS5600000
LD50/LC50:
Not available.
CAS# 7664-93-9: Draize test, rabbit, eye: 250 ug Severe; Inhalation,
mouse: LC50 = 320 mg/m3/2H; Inhalation, mouse: LC50 = 320 mg/m3;
Inhalation, rat: LC50 = 510 mg/m3/2H; Inhalation, rat: LC50 = 510
mg/m3; Oral, rat: LD50 = 2140 mg/kg.
Carcinogenicity:
Phenol disulfonic acid solution -
Not listed by ACGIH, IARC, or NTP.
Sulfuric acid -
ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorg
California: carcinogen, initial date 3/14/03 (listed as Strong inorgan
NTP: Known carcinogen (listed as Strong inorganic acid mists co
IARC: Group 1 carcinogen
Other:
See actual entry in RTECS for complete information.
**** SECTION 12 - ECOLOGICAL INFORMATION ****
**** SECTION 13 - DISPOSAL CONSIDERATIONS ****
Products which are considered hazardous for supply are classified as Special
Waste and the disposal of such chemicals is covered by regulations which may
vary according to location. Contact a specialist disposal company or the local
waste regulator for advice. Empty containers must be decontaminated before
returning for recycling.
**** SECTION 14 - TRANSPORT INFORMATION ****
IATA
Shipping Name: PHENOLSULPHONIC ACID, LIQUID
Hazard Class: 8
UN Number: 1803
Packing Group: II
IMO
Shipping Name: PHENOLSULPHONIC ACID, LIQUID
Hazard Class: 8
UN Number: 1803
Packing Group: II
RID/ADR
Shipping Name: PHENOLSULPHONIC ACID, LIQUID
Hazard Class: 8
UN Number: 1803
Packing group: II
USA RQ: CAS# 7664-93-9: 1000 lb final RQ; 454 kg final RQ
**** SECTION 15 - REGULATORY INFORMATION ****
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 35 Causes severe burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 30 Never add water to this product.
S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
WGK (Water Danger/Protection)
CAS# 96-77-5: No information available.
CAS# 7664-93-9: 2
Canada
CAS# 96-77-5 is listed on Canada's NDSL List.
CAS# 7664-93-9 is listed on Canada's DSL List.
CAS# 96-77-5 is not listed on Canada's Ingredient Disclosure List.
CAS# 7664-93-9 is listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 96-77-5 is listed on the TSCA inventory.
CAS# 7664-93-9 is listed on the TSCA inventory.
**** SECTION 16 - ADDITIONAL INFORMATION ****
Text for R-phrases from Section 2
R 35 Causes severe burns.
MSDS Creation Date: 12/12/1997 Revision #2 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no way shall the company be
liable for any claims, losses, or damages of any third party or for lost
profits or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if the company has been advised of
the possibility of such damages.
--------------------------------------------------------------------------------
--------------------------------------------------------------------------------
|
|
|