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MSDS  : Silicon
CAS  : 7440-21-3
SYNONYMS  : * Defoamer S-10 * Polyeristalline silicon powder * Silicon
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : VW0400000
CHEMICAL NAME : Silicon
CAS REGISTRY NUMBER : 7440-21-3
LAST UPDATED : 199712
DATA ITEMS CITED : 31
MOLECULAR FORMULA : Si
MOLECULAR WEIGHT : 28.09
COMPOUND DESCRIPTOR : Primary Irritant
SYNONYMS/TRADE NAMES :
* Defoamer S-10
* Polyeristalline silicon powder
* Silicon

*** HEALTH HAZARD DATA ***

** SKIN/EYE IRRITATION DATA **

TYPE OF TEST : Standard Draize test
ROUTE OF EXPOSURE : Administration into the eye
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 3 mg
REACTION SEVERITY : Mild
REFERENCE :
FAONAU FAO Nutrition Meetings Report Series. (Rome, Italy) No.?-57,
1948-77. Discontinued. Volume(issue)/page/year: 53A,21,1974

** ACUTE TOXICITY DATA **

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 3160 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
FAONAU FAO Nutrition Meetings Report Series. (Rome, Italy) No.?-57,
1948-77. Discontinued. Volume(issue)/page/year: 53A,21,1974

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Intraperitoneal
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 500 mg/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Olfaction) - effect, not otherwise
specified
Sense Organs and Special Senses (Eye) - effect, not otherwise specified
Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161)
Formerly U.S. Clearinghouse for Scientific & Technical Information.
Volume(issue)/page/year: OTS0536164

*** REVIEWS ***

ACGIH TLV-TWA 10 mg/m3
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

*** U.S. STANDARDS AND REGULATIONS ***

MSHA STANDARD-air:TWA 10 mg/m3
DTLWS* "Documentation of the Threshold Limit Values for Substances in
Workroom Air," Supplements. For publisher information, see 85INA8.
Volume(issue)/page/year: 3,27,1973

OSHA PEL (Gen Indu):8H TWA 15 mg/m3, total dust
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1910.1000,1994

OSHA PEL (Gen Indu):8H TWA 5 mg/m3, respirable fraction
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1910.1000,1994

OSHA PEL (Construc):8H TWA 15 mg/m3, total dust
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1926.55,1994

OSHA PEL (Construc):8H TWA 5 mg/m3, respirable fraction
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1926.55,1994

OSHA PEL (Shipyard):8H TWA 15 mg/m3, total dust
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1915.1000,1993

OSHA PEL (Shipyard):8H TWA 5 mg/m3, respirable fraction
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1915.1000,1993

*** OCCUPATIONAL EXPOSURE LIMITS ***

OEL-AUSTRALIA:TWA 10 mg/m3 JAN 1993

OEL-BELGIUM:TWA 10 mg/m3 JAN 1993

OEL-DENMARK:TWA 10 mg/m3 JAN 1993

OEL-FRANCE:TWA 10 mg/m3 JAN 1993

OEL-THE NETHERLANDS:TWA 10 mg/m3 JAN 1993

OEL-SWITZERLAND:TWA 4 mg/m3 JAN 1993

OEL-UNITED KINGDOM:TWA 10 mg/m3 (total dust) JAN 1993

OEL-UNITED KINGDOM:TWA 5 mg/m3 (resp. dust) JAN 1993

OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV

OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO SILICON, respirable fraction-air:10H TWA 5 mg/m3
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO SILICON, total dust-air:10H TWA 10 mg/m3
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - 68695
No. of Facilities: 3856 (estimated)
No. of Industries: 48
No. of Occupations: 66
No. of Employees: 99138 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - X4229
No. of Facilities: 12 (estimated)
No. of Industries: 1
No. of Occupations: 5
No. of Employees: 1740 (estimated)
No. of Female Employees: 503 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - X4230
No. of Facilities: 118 (estimated)
No. of Industries: 6
No. of Occupations: 6
No. of Employees: 1962 (estimated)
No. of Female Employees: 112 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - X6495
No. of Facilities: 19 (estimated)
No. of Industries: 1
No. of Occupations: 2
No. of Employees: 2379 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 68695
No. of Facilities: 59062 (estimated)
No. of Industries: 296
No. of Occupations: 129
No. of Employees: 693583 (estimated)
No. of Female Employees: 28164 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

EPA TSCA Section 8(d) unpublished health/safety studies

EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998


*** END OF RECORD ***
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ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
NAMECAS
Silicate, soapstoneSUBSTANCE DEFINITION :Containing less than 1% crystalline silicaREFERENCE :FEREAC Federal Register. (U.S. Government Printing Office, Supt. ofDocuments, Washington, DC 20402) V.1- 1936- 65997-15-1
Silicic acid 7699-41-4
Silicic acid (ortho) 10193-36-9
Silicic acid (polyortho) 1343-98-2
Silicic acid, aluminum magnesium salt 1327-43-1
Silicic acid, beryllium salt 15191-85-2
Silicic acid, beryllium zinc salt 39413-47-3
SF-1508 56378-68-8
Silicic acid, calcium salt 1344-95-2
Silicic acid (H2SiO3), calcium salt (11) 10101-39-0
Silicic acid, 2-chloroethyl ester 10101-39-0
Silicic acid (H2SiO3), disodium salt 6834-92-0
Silicic acid, 2-ethylbutyl ester 68037-57-0
Silicic acid, methyl ester 12002-26-5
Silicic acid, tetra(2-ethylbutyl) ester 78-13-7
Silicic acid, tetraethyl ester 78-10-4
Silicic acid, tetra(2-fluoroethyl) ester 650-00-0
Silicic acid, tetrakis(2-chloroethyl) ester 18290-84-1
SF-1739 61991-01-3
Silicic acid (H2SiO4), tetrakis(1-methylpropyl) ester 5089-76-9
Silicic acid, tetramethyl ester 681-84-5
Silicon 7440-21-3
Silicon(1+),(1-(bis(2-hydroxyethyl)amino)-2-propanolato(3-)-N,O,O',O") (ethylmethylsulfonium eta-methylide)-, iodide,(TB-5-34)- 67349-10-4
Silicon carbide 409-21-2
Silicon chloride 10026-04-7
Silicon chrome 11133-78-1
Silicon(1+), (diethylsulfoniumeta-methylide)((1,1',1"-nitrilotris(2-propanolato))(3-)- N,O,O',O")-, bromide, (TB-5-23) 67366-36-3
Silicon(1+), ((1,1-dimethylethyl)methylsulfoniumeta-methylide)((2,2',2"-nitrilotris(ethanolato))(3-)-N,O,O',O")-, iodide, (TB-5-23)- 67349-11-5
Silicon dioxide, hydrate 67349-11-5
SF 3024-B20-KOSUBSTANCE DEFINITION :Phenol resin which is mixture of oligomersREFERENCE :GTPZAB Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene andOccupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)V.1-36, 1957-1992. For publisher information, see MTPEEIVolume(issue)/page/year: 28(7),53,1984 67349-11-5
Silicon,(3,3,4,4,5,5,6,6,7,7,8,8-dodecafluoro-1-iodooctyl)((2,2'2,''-nitrilotris(e thanolato))(3-)-N,O,O',O'')-,(TB-5-23)- 135798-16-2
Silicon,(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluoro-1-iododecyl)((2,2',2 ''-nitrilotris(ethanolato(3-)-N,O,O',O'')-, (TB-5-23)- 135798-18-4
Silicon,(3,3,4,4,5,5,5-heptafluoro-1-iodopentyl)((2,2',2''-nitrilotris(ethanolato) )(3-)- N,O,O',O'')-, (TB-5-23)- 112341-58-9
Silicon,(3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-hexadecafluoro-1-iododecyl)((2,2',2''-n itrilotris(ethanolato))(3-)-N,O,O',O'')-, (TB-5-23)- 135798-17-3
Silicon,((2,2',2''-nitrilotris(ethanolato))(3-)-N,O,O',O'')(3,3,4,4,5,5,6,6,6-nona fluoro-1- iodohexyl)-,(TB-5-23)- 135798-15-1
Silicon,((2,2',2''-nitrilotris(ethanolato))(3-)-N,O,O',O'')(3,3,4,4,5,5,6,6-octafl uoro-1- iodohexyl)-, (TB-5-23)- 135798-14-0
Silicon,((2,2',2''-nitrilotris(ethanolato))(3-)-N,O,O',O'')(3,3,4,4,5,5,6,6,7,7,8, 8,8-tridecafluoro-1-iodooctyl)-, (TB-5-23)- 135829-02-6
Silicon,((2,2',2''-nitrilotris(ethanolato))(3-)-N,O,O',O'')(3,3,3-trifluoro-1-iodo propyl)-, (TB-5-23)- 112341-57-8
Silicone 7158 112341-57-8
Silicone antifoam sag-47 112341-57-8
SF-1540 A 71329-58-3
Silicone antifoam sag-100 71329-58-3
Silicone C-25 71329-58-3
Silicone fluid L-43 71329-58-3
Silicone L-31 71329-58-3
Silicone L-42 (oil) 71329-58-3
Silicone L-45 63148-62-9
Silicone L-75 63148-53-8
Silicone L-76 63148-53-8
Silicone L-77 63148-53-8

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