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MSDS  : Formic acid, methyl ester
CAS  : 107-31-3
SYNONYMS  : * Formiate de methyle * Methylester kyseliny mravenci * Methyle (formiate de) * Methyl formate * Methylformiaat * Methylformiat * Methyl methanoate * Metil (formiato di) * Mravencan methylnaty
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : LQ8925000
CHEMICAL NAME : Formic acid, methyl ester
CAS REGISTRY NUMBER : 107-31-3
LAST UPDATED : 199712
DATA ITEMS CITED : 28
MOLECULAR FORMULA : C2-H4-O2
MOLECULAR WEIGHT : 60.06
WISWESSER LINE NOTATION : VHO1
COMPOUND DESCRIPTOR : Agricultural Chemical
SYNONYMS/TRADE NAMES :
* Formiate de methyle
* Methylester kyseliny mravenci
* Methyle (formiate de)
* Methyl formate
* Methylformiaat
* Methylformiat
* Methyl methanoate
* Metil (formiato di)
* Mravencan methylnaty

*** HEALTH HAZARD DATA ***

** ACUTE TOXICITY DATA **

TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 1622 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73.
For publisher information, see IOHSA5. Volume(issue)/page/year: 41,31,1972

*** REVIEWS ***

ACGIH TLV-STEL 368 mg/m3 (150 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

ACGIH TLV-TWA 246 mg/m3 (100 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

TOXICOLOGY REVIEW
AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60.
For publisher information, see AEHLAU. Volume(issue)/page/year: 20,517,1959

*** U.S. STANDARDS AND REGULATIONS ***

MSHA STANDARD-air:TWA 100 ppm (250 mg/m3)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
3,165,1971

OSHA PEL (Gen Indu):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1910.1000,1994

OSHA PEL (Construc):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1926.55,1994

OSHA PEL (Shipyard):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1915.1000,1993

OSHA PEL (Fed Cont):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
41,50-204.50,1994

*** OCCUPATIONAL EXPOSURE LIMITS ***

OEL-AUSTRALIA:TWA 100 ppm (250 mg/m3);STEL 150 ppm (375 mg/m3) JAN 1993

OEL-AUSTRIA:TWA 100 ppm (250 mg/m3) JAN 1993

OEL-BELGIUM:TWA 100 ppm (246 mg/m3);STEL 150 ppm (369 mg/m3) JAN 1993

OEL-DENMARK:TWA 100 ppm (250 mg/m3) JAN 1993

OEL-FINLAND:TWA 100 ppm (250 mg/m3);STEL 150 ppm (375 mg/m3) JAN 1993

OEL-FRANCE:TWA 100 ppm (250 mg/m3) JAN 1993

OEL-GERMANY:TWA 100 ppm (250 mg/m3) JAN 1993

OEL-THE NETHERLANDS:TWA 100 ppm (250 mg/m3);STEL 200 ppm JAN 1993

OEL-THE PHILIPPINES:TWA 100 ppm (250 mg/m3) JAN 1993

OEL-SWITZERLAND:TWA 100 ppm (250 mg/m3);STEL 200 ppm (500 mg/m3) JAN 1993

OEL-TURKEY:TWA 100 ppm (250 mg/m3) JAN 1993

OEL-UNITED KINGDOM:TWA 100 ppm (250 mg/m3);STEL 150 ppm JAN 1993

OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV

OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO METHYL FORMATE-air:10H TWA 100 ppm;STEL 150 ppm
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 33850
No. of Facilities: 80 (estimated)
No. of Industries: 6
No. of Occupations: 22
No. of Employees: 7738 (estimated)
No. of Female Employees: 1402 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

EPA TSCA Section 8(d) unpublished health/safety studies

EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998


*** END OF RECORD ***
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Formic acid, hexyl ester 629-33-4
Formic acid, hexylidenemethylhydrazide 57590-22-4
Formic acid, hydrazide 624-84-0
Formaldehyde, polymer with benzenamine 25214-70-4
Formic acid, hydrazodi- 628-36-4
Formic acid, indium(3+) salt 40521-21-9
Formic acid, isobutyl ester 542-55-2
Formic acid, isopropyl ester 625-55-8
Formic acid, methyl ester 107-31-3
Formic acid, methylhydrazide 758-17-8

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