*** CHEMICAL IDENTIFICATION ***
RTECS NUMBER : LQ8925000
CHEMICAL NAME : Formic acid, methyl ester
CAS REGISTRY NUMBER : 107-31-3
LAST UPDATED : 199712
DATA ITEMS CITED : 28
MOLECULAR FORMULA : C2-H4-O2
MOLECULAR WEIGHT : 60.06
WISWESSER LINE NOTATION : VHO1
COMPOUND DESCRIPTOR : Agricultural Chemical
SYNONYMS/TRADE NAMES :
* Formiate de methyle
* Methylester kyseliny mravenci
* Methyle (formiate de)
* Methyl formate
* Methylformiaat
* Methylformiat
* Methyl methanoate
* Metil (formiato di)
* Mravencan methylnaty
*** HEALTH HAZARD DATA ***
** ACUTE TOXICITY DATA **
TYPE OF TEST : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE : Oral
SPECIES OBSERVED : Rodent - rabbit
DOSE/DURATION : 1622 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
IMSUAI Industrial Medicine and Surgery. (Northbrook, IL) V.18-42, 1949-73.
For publisher information, see IOHSA5. Volume(issue)/page/year: 41,31,1972
*** REVIEWS ***
ACGIH TLV-STEL 368 mg/m3 (150 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997
ACGIH TLV-TWA 246 mg/m3 (100 ppm)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997
TOXICOLOGY REVIEW
AMIHAB AMA Archives of Industrial Health. (Chicago, IL) V.11-21, 1955-60.
For publisher information, see AEHLAU. Volume(issue)/page/year: 20,517,1959
*** U.S. STANDARDS AND REGULATIONS ***
MSHA STANDARD-air:TWA 100 ppm (250 mg/m3)
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
3,165,1971
OSHA PEL (Gen Indu):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1910.1000,1994
OSHA PEL (Construc):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1926.55,1994
OSHA PEL (Shipyard):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1915.1000,1993
OSHA PEL (Fed Cont):8H TWA 100 ppm (250 mg/m3)
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
41,50-204.50,1994
*** OCCUPATIONAL EXPOSURE LIMITS ***
OEL-AUSTRALIA:TWA 100 ppm (250 mg/m3);STEL 150 ppm (375 mg/m3) JAN 1993
OEL-AUSTRIA:TWA 100 ppm (250 mg/m3) JAN 1993
OEL-BELGIUM:TWA 100 ppm (246 mg/m3);STEL 150 ppm (369 mg/m3) JAN 1993
OEL-DENMARK:TWA 100 ppm (250 mg/m3) JAN 1993
OEL-FINLAND:TWA 100 ppm (250 mg/m3);STEL 150 ppm (375 mg/m3) JAN 1993
OEL-FRANCE:TWA 100 ppm (250 mg/m3) JAN 1993
OEL-GERMANY:TWA 100 ppm (250 mg/m3) JAN 1993
OEL-THE NETHERLANDS:TWA 100 ppm (250 mg/m3);STEL 200 ppm JAN 1993
OEL-THE PHILIPPINES:TWA 100 ppm (250 mg/m3) JAN 1993
OEL-SWITZERLAND:TWA 100 ppm (250 mg/m3);STEL 200 ppm (500 mg/m3) JAN 1993
OEL-TURKEY:TWA 100 ppm (250 mg/m3) JAN 1993
OEL-UNITED KINGDOM:TWA 100 ppm (250 mg/m3);STEL 150 ppm JAN 1993
OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV
OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV
*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***
NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO METHYL FORMATE-air:10H TWA 100 ppm;STEL 150 ppm
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992
NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 33850
No. of Facilities: 80 (estimated)
No. of Industries: 6
No. of Occupations: 22
No. of Employees: 7738 (estimated)
No. of Female Employees: 1402 (estimated)
*** STATUS IN U.S. ***
EPA TSCA Section 8(b) CHEMICAL INVENTORY
EPA TSCA Section 8(d) unpublished health/safety studies
EPA TSCA TEST SUBMISSION (TSCATS) DATA BASE, JUNE 1998
*** END OF RECORD ***
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ALL Chemical Property And Toxicity Analysis PAGES IN THIS GROUP
| NAME | CAS |
Formhydroxamic acid
| 4312-87-2 |
Formic acid
| 64-18-6 |
Formic acid,1-benzyl-2-(4,6-dimethyl-3-pyridazinyl)hydrazide
| 17258-16-1 |
Formic acid, benzyl ester
| 104-57-4 |
Formic acid, 2,2-bis(2-chloroethyl)hydrazide
| 98069-43-3 |
Formic acid, butyl ester
| 592-84-7 |
Formic acid, 1-butylhydrazide
| 16120-70-0 |
Formic acid, cadmium salt
| 4464-23-7 |
Formic acid, calcium salt
| 544-17-2 |
Fobos M-2
| 78922-31-3 |
Formaldehyde, (5-nitro-2-pyridyl)hydrazone
| 28050-83-1 |
Formic acid, chloro-, allyl ester
| 2937-50-0 |
Formic acid, chloro-, 2-chloroethyl ester
| 627-11-2 |
Formic acid, chloro-, ethylene ester
| 124-05-0 |
Formic acid, chloro-, ethyl ester
| 541-41-3 |
Formic acid,4-(3-(2-chloroethyl)-3-nitrosoureido)cyclohexylester, (E)-
| 67227-29-6 |
Formic acid, chloro-, fluoren-9-ylmethyl ester
| 28920-43-6 |
Formic acid, chloro-, 2-fluoroethyl ester
| 462-27-1 |
Formic acid, chloro-, isopropyl ester
| 108-23-6 |
Formic acid, chloro-, 1-naphthyl ester
| 3759-61-3 |
Formic acid, chloro-, oxydiethylene ester
| 106-75-2 |
Formaldehyde, nitro-, p-tolylhydrazone
| 37703-97-2 |
Formic acid, chloro-, propyl ester
| 109-61-5 |
Formic acid, chlorothio-, S-methyl ester
| 18369-83-0 |
Formic acid, chlorothio-, S-propyl ester
| 13889-92-4 |
Formic acid, chloro-, trichloromethyl ester
| 503-38-8 |
Formic acid, chloro-, 2,4,6-trichlorophenyl ester
| 4511-19-7 |
Formic acid, cyano-, methyl ester
| 17640-15-2 |
Formic acid, compd. with cyclohexanamine (11)
| 34961-28-9 |
Formic acid,(((6,8-dibromo-3-(2-chlorophenyl)-3,4-dihydro-4-oxo-2-quinazolinyl)methyl) sulfonyl)-, methyl ester
| 108659-80-9 |
Formic acid,(((6,8-dibromo-3,4-dihydro-3-(2-methoxyphenyl)-4-oxo-2-quinazolinyl)methyl) sulfonyl)-, methyl ester
| 108659-75-2 |
Formic acid, compd. with1-((2-(diethylamino)ethyl)amino)-4-(hydroxymethyl)-9H-thioxanthen-9- one N-oxide (1:1)
| 64265-19-6 |
Formaldehyde, oxime
| 75-17-2 |
Formic acid, dithiobis(thio-, O,O-diethyl ester
| 502-55-6 |
Formic acid, dithiobis(thio-, O,O-dimethyl ester
| 1468-37-7 |
Formic acid, ethyl ester
| 109-94-4 |
Formic acid, 1-ethylhydrazide
| 74920-78-8 |
Formic acid, ethylidenemethylhydrazide
| 16568-02-8 |
Formic acid, 2-(4-(2-furyl)-2-thiazolyl)hydrazide
| 31873-81-1 |
Formic acid, heptyl ester
| 112-23-2 |
Formic acid, hexyl ester
| 629-33-4 |
Formic acid, hexylidenemethylhydrazide
| 57590-22-4 |
Formic acid, hydrazide
| 624-84-0 |
Formaldehyde, polymer with benzenamine
| 25214-70-4 |
Formic acid, hydrazodi-
| 628-36-4 |
Formic acid, indium(3+) salt
| 40521-21-9 |
Formic acid, isobutyl ester
| 542-55-2 |
Formic acid, isopropyl ester
| 625-55-8 |
Formic acid, methyl ester
| 107-31-3 |
Formic acid, methylhydrazide
| 758-17-8 |
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