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MSDS  : Nickel(II) carbonate (11)
CAS  : 3333-67-3
SYNONYMS  : * Carbonic acid, nickel salt (1:1) * C.I. 77779 * Nickel(2+) carbonate * Nickel monocarbonate * Nickelous carbonate
*** CHEMICAL IDENTIFICATION ***

RTECS NUMBER : QR6200000
CHEMICAL NAME : Nickel(II) carbonate (1:1)
CAS REGISTRY NUMBER : 3333-67-3
LAST UPDATED : 199712
DATA ITEMS CITED : 25
MOLECULAR FORMULA : C-Ni-O3
MOLECULAR WEIGHT : 118.72
WISWESSER LINE NOTATION : QVQ &-NI-
COMPOUND DESCRIPTOR : Tumorigen
Mutagen
SYNONYMS/TRADE NAMES :
* Carbonic acid, nickel salt (1:1)
* C.I. 77779
* Nickel(2+) carbonate
* Nickel monocarbonate
* Nickelous carbonate

*** HEALTH HAZARD DATA ***

** ACUTE TOXICITY DATA **

TYPE OF TEST : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE : Subcutaneous
SPECIES OBSERVED : Rodent - guinea pig
DOSE/DURATION : 32 mg/kg
TOXIC EFFECTS :
Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
(usually neuromuscular blockage)
Lungs, Thorax, or Respiration - dyspnea
Lungs, Thorax, or Respiration - other changes
REFERENCE :
JOHYAY Journal of Hygiene. (Cambridge Univ. Press, 32 E. 57th St., New
York, NY 10022) V.1- 1901- Volume(issue)/page/year: 8,565,1908

** TUMORIGENIC DATA **

TYPE OF TEST : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE : Implant
SPECIES OBSERVED : Rodent - rat
DOSE/DURATION : 95 mg/kg/78W-C
TOXIC EFFECTS :
Tumorigenic - equivocal tumorigenic agent by RTECS criteria
Tumorigenic - tumors at site of application
REFERENCE :
PAACA3 Proceedings of the American Association for Cancer Research. (Waverly
Press, 428 E. Preston St., Baltimore, MD 21202) V.1- 1954-
Volume(issue)/page/year: 5,50,1964

** MUTATION DATA **

TYPE OF TEST : DNA damage
ROUTE OF EXPOSURE : Intraperitoneal
TEST SYSTEM : Rodent - rat
DOSE/DURATION : 10 mg/kg/3H
REFERENCE :
CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year:
42,3544,1982

TYPE OF TEST : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE : Intraperitoneal
TEST SYSTEM : Rodent - rat
DOSE/DURATION : 40 mg/kg
REFERENCE :
CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & Chestnut
Sts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year:
44,3892,1984

*** REVIEWS ***

ACGIH TLV-TWA 1 mg(Ni)/m3
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
TLV/BEI,1997

IARC Cancer Review:Animal Sufficient Evidence
IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
V.1- 1972- Volume(issue)/page/year: 11,75,1976

IARC Cancer Review:Animal Limited Evidence
IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals
to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210)
V.1- 1972- Volume(issue)/page/year: 49,257,1990

TOXICOLOGY REVIEW
ACLSCP Annals of Clinical and Laboratory Science. (1833 Delancey Pl.,
Philadelphia, PA 19103) V.1- 1971- Volume(issue)/page/year: 3,156,1973

TOXICOLOGY REVIEW
FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For
publisher information, see FCTOD7. Volume(issue)/page/year: 9,105,1971

TOXICOLOGY REVIEW
85DHAX "Medical and Biologic Effects of Environmental Pollutants Series,"
Washington, DC, National Academy of Sciences, 1972-77
Volume(issue)/page/year: Ni,168,1975

*** U.S. STANDARDS AND REGULATIONS ***

MSHA STANDARD-air:TWA 1 mg(Ni)/m3
DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices
(BEIs) booklet issues by American Conference of Governmental Industrial
Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year:
3,178,1971

OSHA PEL (Gen Indu):8H TWA 1 mg(Ni)/m3
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1910.1000,1994

OSHA PEL (Construc):8H TWA 1 mg(Ni)/m3
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1926.55,1994

OSHA PEL (Shipyard):8H TWA 1 mg(Ni)/m3
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
29,1915.1000,1993

OSHA PEL (Fed Cont):8H TWA 1 mg(Ni)/m3
CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt.
of Documents, Washington, DC 20402) Volume(issue)/page/year:
41,50-204.50,1994

*** OCCUPATIONAL EXPOSURE LIMITS ***

OEL-GERMANY;Carcinogen JAN 1993

OEL-SWEDEN:TWA 0.1 mg/m3;Carcinogen JAN 1993

OEL-SWITZERLAND:TWA 0.5 mg/m3;Skin;Carcinogen JAN 1993

OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV

OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

*** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA ***

NIOSH RECOMMENDED EXPOSURE LEVEL (REL) :
NIOSH REL TO NICKEL, INORGANIC-air:10H CA TWA 0.015 mg(Ni)/m3
REFERENCE :
NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of
Health, Education, and Welfare, Reports and Memoranda.
Volume(issue)/page/year: DHHS #92-100,1992

NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA :
NOHS - National Occupational Hazard Survey (1974)
NOHS Hazard Code - 81905
No. of Facilities: 349 (estimated)
No. of Industries: 12
No. of Occupations: 9
No. of Employees: 4696 (estimated)

NOES - National Occupational Exposure Survey (1983)
NOES Hazard Code - 81905
No. of Facilities: 864 (estimated)
No. of Industries: 28
No. of Occupations: 23
No. of Employees: 13040 (estimated)
No. of Female Employees: 2017 (estimated)

*** STATUS IN U.S. ***

EPA TSCA Section 8(b) CHEMICAL INVENTORY

NTP 7th Annual Report on Carcinogens, 1992 : anticipated to be carcinogen


*** END OF RECORD ***
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NAMECAS
Nickel(II) carbonate (11) 3333-67-3
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Nickel carbonyl 13463-39-3
Nickel(II) chloride (12) 7718-54-9
Nickel(II) chloride, hexahydrate (126) 7791-20-0
Nickel chloride, trihydrate 65374-81-4
Nickel cyanide 557-19-7
Nickel, compd with pi-cyclopentadienyl (12) 1271-28-9
2-Naphthol, 1,6-dibromo- 16239-18-2
Nickel, dithiocyanatobis(triphenylphosphine)- 15709-62-3
Nickel,(ethanedioato(2-)-O,O')bis(3-methylbenzenamine)- 80660-65-7
Nickel,(ethanedioato(2-)-O,O')bis(3-((phenylamino)methyl)-2(3H)-benzoxazolone- N(sup N(sup 3),O(sup 2))- 82497-99-2
Nickel, (ethanedioato(2-)-O,O')bis(pyridine1-oxide-O)-, (SP-4-2)- 74167-24-1
Nickel(II) fluoborate 14708-14-6
Nickel(II) fluoride (12) 10028-18-9
Nickel(II) fluosilicate (11) 26043-11-8
Nickel-gallium alloy 56668-59-8
Nickel(II) hydroxide 12054-48-7
Nickel(III) hydroxide 12125-56-3
2-Naphthol, dichloro- 63980-33-6
Nickeline 1303-13-5
Nickel iron sulfide 59978-65-3
Nickel(II) isodecyl ortho-phosphate (32) 74203-45-5
Nickel(II) nitrate (12) 13138-45-9
Nickel(II) nitrate, hexahydrate (126) 13478-00-7
Nickel(II) oxide (11) 1313-99-1
Nickel(III) oxide 1314-06-3
Nickel oxide catalyst 1314-06-3
Nickel potassium cyanide 14220-17-8
Nickel refinery dustSUBSTANCE DEFINITION :Analysis: cupric oxide(3.4%), nickel sulfate(20.0%), nickel sulfide(57.0%),nickel oxide(6.3%), cobalt oxide(1.0%), ferric oxide(1.8%), silicondioxide(1.2%), misc.(2.0%), water(7.3%)REFERENCE :CNREA8 Cancer Research. (Public Ledger Building, Suit 816, 6th & ChestnutSts., Philadelphia, PA 19106) V.1- 1941- Volume(issue)/page/year:22,158,1962 14220-17-8
2-Naphthol,7,8-dihydro-6-phenyl-5-(p-(2-piperidinoethoxy)phenyl)-, hydrochloride 10059-68-4
Nickel selenide (Ni-Se) 1314-05-2
Nickel selenide (Ni3-Se2) 12137-13-2
Nickel (II) sulfamate 13770-89-3
Nickel(II) sulfate (11) 7786-81-4
Nickel(II) sulfate hexahydrate (116) 10101-97-0
Nickel sulfide 11113-75-0
Nickel sulfide 16812-54-7
Nickel sulfide 12035-51-7
Nickel sulfide, amorphous 12035-51-7
Nickel sulfide (32) 12035-72-2
2-Naphthol, 1-((2,5-dimethoxyphenyl)azo)- 6358-53-8
Nickel telluride 12142-88-0
Nickel titanium oxide 12035-39-1
Nickel(2+), tris(2,2'-bipyridine-N,N')-, dichloride,(OC-6-11)- 14751-84-9
Nickel(2+), tris(1,2-ethanediamine-N,N')-,(OC-6-11)-, (T-4)-tetraoxotungstate(2-) (1:1) 80660-45-3
Nickel(2+), tris(octamethylpyrophosphoramide)-,diperchlorate 26388-85-2
Nickel(2+), tris(1,2-propanediamine-N,N')-,(T-4)-tetraoxotungstate(2-) (1:1) 80660-44-2

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