UNION CARBIDE CHEMICALS & PLAS -- ETHYLENE GLYCOL, INDUSTRIAL GRADE, 35194
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Material Safety Data Sheet
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MSDS Num: CDWQV
MSDS NAME: ETHYLENE GLYCOL, INDUSTRIAL GRADE, 35194
Responsible Party
Name: UNION CARBIDE CHEMICALS & PLASTICS CO INC
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Info Phone: 304-744-3487
Emergency Phone Number: 800-822-4357
Published: Y
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Contractor Summary
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Name: UNION CARBIDE CHEM & PLASTICS CO INC
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Phone: 203-794-6753/304-744-3487
Name: UNION CARBIDE CORP LINDE DIV
Address: 39 OLD RIDGEBURY RD
City: DANBURY CT 06817-0001
Phone: 800-822-4357; 304-744-3487
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Ingredients
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Cas: 107-21-1
RTECS #: KW2975000
Name: ETHYLENE GLYCOL (SARA 313) (CERCLA)
% Wt: 100
OSHA PEL: N/K (FP N)
ACGIH TLV: 50 PPM, VAPOR, C
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Cas: 123-91-1
RTECS #: JG8225000
Name: P-DIOXANE; (DIOXANE) (SARA 313) (CERCLA)
% Wt: 0.0026
OSHA PEL: 100 PPM, S
ACGIH TLV: 25 PPM, S
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Cas: 75-21-8
RTECS #: KX2450000
Name: ETHYLENE OXIDE (SARA 302/313) (CERCLA)
% Wt: 0.0001
OSHA PEL: 1 PPM
ACGIH TLV: 1 PPM
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 67-56-1
RTECS #: PC1400000
Name: METHANOL (SARA 313) (CERCLA)
% Wt: 0.0024
OSHA PEL: 200 PPM, S
ACGIH TLV: 200 PPM; 250 STEL, S
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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RTECS #: 9999999VO
Name: VOLATILE ORGANIC COMPOUND: 1111.16 G/L. VP: 0.04 @ 20C.
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
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Name: ING 5:DOSE OF ETHYLENE GLYCOL TO ADULTS IS OF ORDER OF 1.0 ML/KG. IT IS
METABOLIZED BY ALCOHOL DEHYDROGENASE TO
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Name: ING 6: VARIOUS METABOLITES INCL GLYCOALDEHYDE, GLYCOLIC ACID & OXALIC
ACID; CAUSES ELEVATED ANION-GAP METABOLIC
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Name: ING 7:ACIDOSIS & RENAL TUBULAR INJURY. POIS SYMPS ARE THOSE OF
METABOLIC ACIDOSIS, CNS DEPRESS, KIDNEY INJURY.
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Name: ING 8: URINALYSIS MAY SHOW ALBUMINURIA, HEMATURIA & OXALURIA.
CLINICAL CHEM MAY REVEAL ANION-GAP METABOLIC
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Name: ING 9:ACIDOSIS & UREMIA. RECD MED MANAGEMENT OF POIS INCLS ELIM OF
ETHYLENE GLYCOL & METABOLITES, CORRECTION OF
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Name: ING 10:METABOLIC ACIDOSIS & PVNT OF KIDNEY INJURY. IT IS ESSNTL TO
HAVE IMMED & FOLLOW-UP URINALYSIS & CLINICAL
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Name: ING 11: CHEM. EMPHASIS SHOULD BE ON ACID-BASE BALANCE & RENAL FUNC
TESTS. CONTINUOUS INFUSION OF 5% SODIUM
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Name: ING 12: BICARBONATE W/FREQUENT MONITORING OF ELECTROLYTES & FLUID
BALANCE IS USED TO ACHIEVE CORRECTION OF
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Name: ING 13: METABOLIC ACIDOSIS & FORCED DIURESIS. AS COMPETITIVE
SUBSTRATE FOR ALCOHOL DEHYDROGENASE, ETHANOL IS
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Name: ING 14:ANTIDOTAL. GIVEN IN EARLY INTOXICATION STAGE, IT BLOCKS FORM OF
NEPHROTOXIC METABOLITES. THERAPEUTICALLY
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Name: ING 15:EFTIVE BLOOD CONC OF ETHANOL IS IN 100-150MG/DL RANGE; ACHIEVE BY
RAPID LOADING DOSE & MAINTAINED BY IV.
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Name: ING 16:SEV &/OR DETERIORATING CASES MAY REQ HEMODIALYSIS. CONSIDER
DIALYSIS FOR PATIENTS WHO ARE SYMP, HAVE SEV
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Name: ING 17:METABOLIC ACIDOSIS, BLOOD ETHYLENE GLYCOL CONCS >25 GM/DL OR
COMPROMISE OF RENAL FUNCS. 4-METHYLPYRAZOLE,
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Name: ING 18: POTENT INHIBITOR OF ALCOHOL DEHYDROGENASES, HAS BEEN EFTIVELY
USED TO DECR METABOLIC CONSEQUENCES OF
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Name: ING 19: POIS BEFORE METABOLIC ACIDOSIS, COMA, SEIZURES & RENAL
FAILURE OCCUR. ADDNL MEASURES MAY INCL ADMIN OF
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Name: ING 20:COFACTORS INVOLVED IN METABOLISM OF ETHYLENE GLYCOL. GIVE
TIAMINE(100MG) & PYRIDOXINE(50MG) EVERY 6 HRS.
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Name: ING 21: PULM EDEMA W/HYPOXEMIA IN SOME PATIENTS AFTER POIS; APPEARS
NON-CARDIOGENIC IN ORIGIN IN SEVERAL CASES.
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Name: ING 22:RESP SUPPORT W/MECH VENT & POS END-EXPIRATORY PRESS MAY BE
REQD. MAY BE CRANIAL NERVE INVOLVEMENT IN LATE
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Name: ING 23:STAGES OF TOX. IN PARTICULAR, EFTS REPORTED INVOLVING SEVENTH,
EIGHTH & NINTH CRANIAL NERVES, PRESENTING
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Name: ING 24: W/BILATERAL FACIAL PARALYSIS, DIMINISHED HEARING & DYSPHAGIA.
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INGEST:MAY CAUSE ABDOM DISCOMFORT/PAIN, NAUS, VOMIT, DIZZ,
DROW, MALAISE, BLURRED VISION, IRRITABILITY, LUMBAR PAIN, OLIGURIA, UREMIA
& CNS EFTS INCL IRREGULAR EYE MOVEMENT, CONVLS & COMA. CARD FAILUR E,
PULM EDEMA, SEV KIDNEY DMG POSS. MAYBE FATAL. RPTS OF FACIAL MUSC WEAK,
DIMINISHED HEARING & DFCLTY(EFTS OF OVEREXP)
Explanation Of Carcinogenicity: NOT RELEVANT
Signs And Symptions Of Overexposure: HLTH HAZ:SWALLOWING. INHAL:MAY CAUSE IRRIT
OF NOSE & THROAT W/HDCH. HIGH CONCS MAY PRDCE NAUS, VOMIT, HDCH, DIZZ
& IRREGULAR EYE MOVEMENT. EYE:IRRIT, STINGING, EXCESS BLINKING & TEAR
PRODUCTION W/EXCE SS REDNESS OF CONJ. RPTD INHAL OF MIST MAY PRDCE SIGNS OF
CNS INVOLVEMENT ESP DIZZ & NYSTAGMUS. RPTD SKIN CNTCT (SUPDAT)
Medical Cond Aggravated By Exposure: MAY AGGRAVATE AN EXISTING KIDNEY DISEASE.
First Aid: INGEST:IF CONSCIOUS, GIVE 2 GLASSES OF WATER. INDUCE VOMIT. OBTAIN
MED ATTN W/OUT DELAY. IF MED ADVICE IS DELAYED & IF PERSON SWALLED MOD
VOL OF MATL (FEW OZ), GIVE 3-4 OZ OF HARD LIQUOR SUCH AS WHISK EY; GIVE
CHILDREN PROPORTIONALLY LESS ACCRD TO WT. SKIN:REMOVE CONTAMD CLTHG. WASH
SKIN W/SOAP & WATER. IF IRRIT PERSISTS/IF CNTCT PRLNGD, OBTAIN MED ATTN.
INHAL:REMOVE TO FRESH AIR. OBTAIN MED
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Handling and Disposal
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Spill Release Procedures: SMALL SPILLS CAN BE FLUSHED WITH LARGE AMOUNTS OF
WATER; LARGER SPILLS SHOULD BE COLLECTED FOR DISPOSAL. WEAR SUITABLE
PROTECTIVE EQUIPMENT.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: AT VERY LOW CONCENTRATIONS IN WATER, THIS PRODUCT IS
BIODEGRADABLE IN BIOLOGICAL WASTEWATER TREATMENT PLANT. INCINERATE IN A
FURNACE WHERE PERMITTED UNDER FEDERAL, STATE AND LOCAL REGULATIONS.
Handling And Storage Precautions: HARMFUL/FATAL IF SWALLOWED. KEEP CNTNR CLSD.
USE W/ADEQ VENT. EVAL PROD USE IN ELEVATED-TEMP PROCESSES TO ESTABLISH &
MAINTAIN SAFE OPERATING CNDTNS.
Other Precautions: SUDDEN RELS OF HOT ORG CHEM VAPS/MISTS FROM PROCESS EQUIP
OPERATING AT ELEVATED TEMP & PRESS OR SUDDEN INGRESS OF AIR INTO VACUUM
EQUIP MAY RSLT IN IGNITS W/OUT PRESENCE OF OBVIOUS IGNIT SOURCES. CNTC T NEHC
FOR MORE INFO (FP N).
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point Text: 240F,116C
Lower Limits: 3.2%
Upper Limits: 15.3%
Extinguishing Media: APPLY ALCOHOL-TYPE OR ALL PURPOSE-TYPE FOAM FOR LG FIRES.
USE CARBON DIOXIDE OR DRY CHEMICAL MEDIA FOR SM FIRES.
Fire Fighting Procedures: NIOSH APPRVD SCBA & FULL PROT EQUIP (FP N). DO
NOT DIRECT A SOLID STREAM OF WATER/FOAM INTO HOT, BURNING POOLS; THIS MAY
CAUSE FROTHING & INCR FIRE INTENSITY.
Unusual Fire/Explosion Hazard: NONE.
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Control Measures
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Respiratory Protection: NIOSH APPROVED BREATHING AIR EQUIPMENT OR NIOSH
APPROVED FACE MASK WITH ORGANIC VAPOR CARTRIDGE AND DUST OR MIST PRE-FILTER.
Ventilation: GEN (MECH) ROOM VENT. IF AMBIENT TEMPS ARE EXCEEDED OR OPERATIONS
EXIST WHICH PRDCE MISTING, LOC EXHST VENT IS REQD.
Protective Gloves: PVC-COATED, RUBBER.
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: DO NOT SWALLOW/BREATHE MIST FROM SPRAY. AVOID
PRLNGD/RPTD BRTHG OF VAP. WASH THOROUGHLY AFTER HNDLG. FOR INDUS USE ONLY.
Supplemental Safety and Health: EFTS OF OVEREXP:MAY, IN VERY SM PROPORTION OF
CASES, CAUSE SENSIT W/DEVELOPMENT OF ALLERGIC CNTCT DERM. INCIDENCE IS
SIGNIFICANTLY <1% W/UNDILUTED MATL. ETHYLENE GLYCOL HAS PRDCED TERATOGENIC
EFTS IN RATS & MICE. CONTACT NEHC FOR MORE INFOON HLTH HAZS (FP N).
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Physical/Chemical Properties
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B.P. Text: >387F,>197C
M.P/F.P Text: 9F,-13C
Vapor Pres: 0.08 @ 20C
Vapor Density: 2.1
Spec Gravity: 1.115 (H*2O=1)
Evaporation Rate & Reference: 0.01 (BUTYL ACETATE=1)
Solubility in Water: 100% BY WT
Appearance and Odor: TRANSPARENT, COLORLESS LIQUID; MILD SWEET ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NONE KNOWN.
Materials To Avoid: AVOID STRONG ACIDS OR STRONG BASES, STRONG OXIDIZING AGENTS
AND MATERIALS REACTIVE WITH HYDROXYL COMPOUNDS.
Hazardous Decomposition Products: BURNING CAN PRODUCE THE FOLLOWING COMBUSTION
PRODUCTS: CARBON MONOXIDE AND/OR CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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HAZCOM Label
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MSDS NAME: ETHYLENE GLYCOL, INDUSTRIAL GRADE, 35194
Assigned IND: Y
Company: UNION CARBIDE CHEM & PLASTICS CO INC
Street: 39 OLD RIDGEBURY RD
City: DANBURY CT
Zipcode: 06817-0001
Health Emergency Phone: 800-822-4357
Label Required IND: Y
Date Of Label Review: 07/02/1997
Status Code: C
Label Date: 07/02/1997
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Moderate
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INGESTION: MAY CAUSE ABDOMINAL DISCOMFORT OR
PAIN, NAUSEA, VOMITING, DIZZINESS, DROWSINESS, MALAISE, BLURRED VISION,
IRRITABILITY, LUMBAR PAIN, OLIGURIA, UREMIA AND CNS EFFECTS INCLUDING IRREGU
LAR EYE MOVEMENTS, CONVULSIONS AND COMA. CARDIAC FAILURE, PULMONARY EDEMA,
SEVERE KIDNEY DAMAGE POSSIBLE. MAY BE FATAL. INHALATION: MAY CAUSE IRRITATION
OF THE NOSE AND THROAT WITH HEADACHE, NAUSEA, V OMITING, DIZZINESS, IRREGULAR
EYE MOVEMENTS. EYES: IRRITATION; STINGING, EXCESSBLINKING AND TEAR PRODUCTION
WITH EXCESS REDNESS OF CONJUNCTIVA. CHRONIC: CNS EFFECTS; DIZZINESS AND
NYSTAGMUS.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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