rubber binder; (sbr &/or natural rubber) asbestos, chrysotile inert inorganic fillers efts of overexp: respiratory & gi tract. medical & historical ing 4: from asbestos expos. it is recommended that those working ing 5: this prod may result in release of toxic gases &/or asbestos other precs: 30 years. note: asbestos & other fibers contained in ing 7: matrix. airborne asbestos hazs are eliminated if composite ing 8: hndlg new sheet or new cut gaskets. if matl is to be cut, drilled ing 9: process, see sections on health hazards, special protection &
PROAMIANTO COMERCIO E EXPORT A -- COMPRESSED RUBBER-BONDED ASBESTOS GASKET
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CGTNY
MSDS NAME: COMPRESSED RUBBER-BONDED ASBESTOS GASKET
Responsible Party
Name: PROAMIANTO COMERCIO E EXPORT ACAO, SA
Address: AV AUTOMOVEL CLUBE 3939
City: RIO DE JANERIO, BRAZIL NK 00000
Info Phone: 55-21-372-7555
Emergency Phone Number: 55-21-372-7555
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: PROAMIANTO COMERCIO E EXPORTACAO S/A
Address: AV AUTOMOVEL CLUBE, 8939
Box: 3641
City: RIO DE JANERIO, BRAZIL NK 00000
Phone: 55-021-372-7555
Name: PROAMIANTO COMERCIO E EXPORTACAO, SA
Address: UNKNOWN
Box: UNKNOW
City: UNKNOWN NK 00000
Phone: UNKNOWN
=======================================================
Ingredients
=======================================================
Name: RUBBER BINDER; (SBR &/OR NATURAL RUBBER)
% Wt: <40
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Cas: 12001-29-5
RTECS #: CI6478500
Name: ASBESTOS, CHRYSOTILE
% Wt: 60-90
OSHA PEL: 0.2 FIBERS, CC
ACGIH TLV: 2 FIBERS, CC
------------------------------
Name: INERT INORGANIC FILLERS
% Wt: 5-30
OSHA PEL: N/K (FP N)
ACGIH TLV: N/K (FP N)
-----------------------------
Name: EFTS OF OVEREXP: RESPIRATORY & GI TRACT. MEDICAL & HISTORICAL
DATA INDICATE SMOKERS HAVE GREATER INCREASED RISK
-----------------------------
Name: ING 4: FROM ASBESTOS EXPOS. IT IS RECOMMENDED THAT THOSE WORKING
W/ASBESTOS-CONTAINING PRODS NOT SMOKE. IGNIT OF
-----------------------------
Name: ING 5: THIS PROD MAY RESULT IN RELEASE OF TOXIC GASES &/OR ASBESTOS
PARTICULATE.
-----------------------------
Name: OTHER PRECS: 30 YEARS. NOTE: ASBESTOS & OTHER FIBERS CONTAINED IN
THIS MATL ARE BONDED W/VULCANIZED RUBBER
-----------------------------
Name: ING 7: MATRIX. AIRBORNE ASBESTOS HAZS ARE ELIMINATED IF COMPOSITE
STRUCTRUE REMAINS INTACT, AS IT WOULD WHEN
-----------------------------
Name: ING 8: HNDLG NEW SHEET OR NEW CUT GASKETS. IF MATL IS TO BE CUT, DRILLED
OR SUBJECT TO ANY OTHER DUST-PROOFING
-----------------------------
Name: ING 9: PROCESS, SEE SECTIONS ON HEALTH HAZARDS, SPECIAL PROTECTION &
OTHER PRECAUTIONS AND COMMENTS.
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Health Hazards Data
=======================================================
LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: NO
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: THE PRINCIPAL HEALTH HAZ RESULTS FROM RELEASE OF ASBESTOS
FIBERS INTO AIR. NORMAL HNDLG OF SHEET OR NEW CUT GASKETS SHOULD NOT RESULT
IN EXPOS TO ASBESTOS IN EXCESS OF CURRENT OSHA REQS (2 FIBERS CC>5 UM
LENGTHS). GASKET CUTTING OPERATIONSSHOULD SAMPLE AIR FOR ASBESTOS FIBERS ON A
REGULAR BASIS I/A/W (EFTS OF OVEREXP)
Explanation Of Carcinogenicity: ASBESTOS, CHRYSOTILE: IARC MONOGRAPHS,
SUPPLEMENT, VOL 7, PG 106, 1987:GROUP 1. NTP 7TH ANNUAL REPORT ON (SUPDAT)
Signs And Symptions Of Overexposure: HLTH HAZ: 29 CFR 1010.1001. SAWING,
SANDING, DRILLING OR GRINDING SHOULD BE AVOIDED W/OUT ADEQ DUST
EXTRACTION/SUPPRESSION PROCEDURES. CHRONIC EXPOSURE TO ASBESTOS IN EXCESS OF
TLV CAN CAUSE PERM DISA BLING DISEASES INCLUDING BUT NOT LIMITED TO
ASBESTOSIS, LUNG CANCER, MESOTHLIAMA & VARIOUS OTHER CANCERS OF
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: INGEST: CALL MD IMMEDIATELY (FP N). INHAL: REMOVE TO FRESH AIR.
SUPPORT BREATHING (GIVE OXYGEN/ARTIFICIAL RESPIRATION) (FP N). EYES:
IMMEDIATELY FLUSH W/POTABLE WATER FOR A MINIMUM OF 15 MINUTES, SEEK
ASSISTANCE FROM MD (FP N). SKIN: FLUSHW/COPIOUS AMOUNTS OF WATER. CALL MD (FP
N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: NONE SPECIFIED BY MANUFACTURER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER.
Waste Disposal Methods: BURY WASTES IN SOLID LANDFILL AS REQD IN 29 CFR
1910.1001. ALSO COMPLY W/APPLIC FEDERAL, STATE & LOCAL REGS. WASTES
SHOULD BE IN SEALED CNTNR, MARKED W/APPROP WARNING LABEL. HIGH TEMP
INCINERATION MAY BE AN OPTION. CHECK STATE & LOCAL REGS.
Handling And Storage Precautions: HNDL SO ANY RELS OF FIBERS FROM MATL WILL BE
ELIMINATED OR CONTROLLED. SMOKERS HAVE MUCH GREATER RISK THAN NON-SMOKERS
FROM INHAL OF ASBESTOS FIBERS.
Other Precautions: MONITOR AREAS WHERE ASBESTOS DUST IS RELEASED TO BE CERTAIN
FIBER CONTENT IS WELL W/IN OSHA LIMITS. PROVIDE ANNUAL MED EXAMS FOR
EMPLOYEES EXPOSED TO ASBESTOS DUST. KEEP MONITORING RSLTS & EMPLOYEES H
EALTH RECORDS FOR AT LEAST
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: EXTINGUISHING AGENTS MAY BE WATER OR FOAM.
Fire Fighting Procedures: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT
(FP N).
Unusual Fire/Explosion Hazard: COMBUSTIBILITY OF THIS MATERIAL RESULTS FROM THE
RUBBER BINDER. TOXIC GASES, INCLUDING HCL, CARBON MONOXIDE & VARIOUS
NITROGEN OXIDES MAY BE RELEASED (SUPDAT)
=======================================================
Control Measures
=======================================================
Respiratory Protection: USE OF NIOSH APPROVED DUST RESPIRATORS MAY BE REQUIRED.
SEE CFR 1910.1001.
Ventilation: WHEN SUBJECT TO ANY DUST-PRODUCING PROCESS, LOCAL FILTERED DUST
EXTRACTION SHOULD BE USED.
Protective Gloves: IMPERVIOUS GLOVES (FP N).
Eye Protection: ANSI APPRVD CHEM WORKERS GOGGLES (FP N).
Other Protective Equipment: ANSI APPROVED EYE WASH & DELUGE SHOWER (FP N).
Work Hygienic Practices: WHEN CHANGING DETERIORATED PACKING MFR SUGGESTS
WETTING MATL TO PVNT FURTHER FIBER DISPERSAL. DISP I/A/W DISP PROCS.
Supplemental Safety and Health: APPEAR/ODOR: MAY BE IN FORM OF CUT GASKET
SHAPES. U30B-BLACK; A31W-WHITE. NO ODOR. EXPLO HAZ: IN A FIRE. ASBESTOS
PARTICULATE MAY ALSO BE RELEASED IN FIRE. EXPLAN OF CARCIN: CARCINOGENS,
1994: KNOWN T O BE CARCINOGEN. OSHA REGULATED: CFR 291910.1008.
=======================================================
Physical/Chemical Properties
=======================================================
Spec Gravity: 1.2-2.0(H*2O=1)
Appearance and Odor: FLAT OR ROLLED SHEETS RANGING FROM 1/64"-3/4" IN THICKNESS
OR MATERIAL (SUPDAT)
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: STABLE UNDER NORMAL USE, HANDLING AND STORAGE
CONDITIONS. SHELF LIFE IS MEASURED IN YEARS, IN SERVICE.
Materials To Avoid: AVOID INCOMPATIBLE MEDIA. THE IMPORTER CAN PROVIDE CHEMICAL
RESISTANCE DATA UPON WRITTEN REQUEST.
Hazardous Decomposition Products: NONE SPECIFIED BY MANUFACTURER.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
=======================================================
Toxicological Information
=======================================================
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
=======================================================
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HAZCOM Label
=======================================================
MSDS NAME: COMPRESSED RUBBER-BONDED ASBESTOS GASKET
Assigned IND: Y
Company: PROAMIANTO COMERCIO E EXPORTACAO S/A
Street: AV AUTOMOVEL CLUBE, 8939
PO Box: 3641
City: RIO DE JANERIO, BRAZIL NK
Zipcode: 00000
Health Emergency Phone: 55-21-372-7555
Label Required IND: Y
Date Of Label Review: 04/07/1998
Status Code: C
Label Date: 04/07/1998
Origination Code: G
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: CAUTION
Respiratory Protection IND: YES
Health Hazard: Slight
Contact Hazard: Slight
Fire Hazard: Slight
Reactivity Hazard: None
Hazard And Precautions: ACUTE: NONE LISTED BY MANUFACTURER. CHRONIC: CANCER
HAZARD. CONTAINS ASBESTOS, CHRYSOTILE WHICH IS LISTED AS A HUMAN LUNG
CARCINOGEN (FP N). CAN CAUSE PERMANENT DISABLING DISEASES INCLUDING BUT NOT
LI MITED TO ASBESTOSIS, LUNG CANCER, MESOTHLIAMA AND VARIOUS OTHER CANCERS OF
THE RESPIRATORY AND GASTROINTESTINAL TRACTS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.