LOS ANGELES CHEMICAL CO -- BLEACH SOLUTION
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Material Safety Data Sheet
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NIIN: 00-900-6276
MSDS Num: CHVWH
MSDS NAME: BLEACH SOLUTION
Responsible Party
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE STREET
Box: 1987
City: SOUTH GATE CA 90280-2534
Info Phone: 213-583-4761 / FAX 213-773-0909
Emergency Phone Number: 213-583-4761/562-9500
Preparer's Name: UNKNOWN
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE ST
Box: 1987
City: SOUTH GATE CA 90280
Phone: 213-562-9500
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Item Description Information
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Item Manager: S9G
Item Name: SODIUM HYPOCHLORITE SOLUTION
Unit of Issue: CN
Quantitative Expression: 00000000005GL
UI Container Qty: 1
Type of Container: CAN
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Ingredients
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Cas: 7778-54-3
RTECS #: NH3485000
Name: CALCIUM HYPOCHLORITE (CERCLA)
Other REC Limits: 3 MG/M3 (CEILING)MFR
OSHA PEL: 0.5 PPM (CL)
ACGIH TLV: 0.5PPM/1STEL(CL)9596
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Health Hazards Data
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LD50 LC50 Mixture: NO DATA AVAILABLE
Route Of Entry Inds - Inhalation: YES
Skin: NO
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- DUST IRRITATES RESPIRATORY TRACT & MAY CAUSE BURNS. CORROSIVE TO
EYES/SKIN. MAY CAUSE SEVERE IRRITATION AND/OR BURNS. IF SWALLOWED, CAUSES
IRRI TATION AND/OR BURNS OF ENTIRE GASTROINTESTINAL TRACT. CHRONIC- LUNG
DAMAGE, TISSUE DESTRUCTION, CORNEAL DAMAGE.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: SEVERE IRRITATION, PAIN, ULCERATION,
TEARING, BLINDNESS, SHORTNESS OF BREATH, COUGH, SORE THROAT, NASAL CONGESTION
Medical Cond Aggravated By Exposure: NO DATA AVAILABLE
First Aid: GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:MOVE TO FRESH AIR.
PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER FOR 15
MINUTES. HOLD EYELIDS OPEN. CALL PHYSICIAN. SKIN: FLUSH WITH PLE NTY OF
WATER. ORAL:IF CONSCIOUS, DRINK LARGE AMOUNT OF WATER. DO NOT INDUCE
VOMITING. GET MEDICAL ATTENTION OR TAKE VICTIM TO AN HOSPITAL EMERGENCY
IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: WEAR RESPIRATOR APPROVED FOR DUST/CHLORINE. VENTILATE
AREA. SWEEP UP AND MINIMIZE CONTAMINATION WITH ORGANIC MATERIALS. PLACE IN AN
APPROPRIATE CONTAINER FOR DISPOSAL. WASH AREA WITH WATER. DO NOT FLU SH TO
SEWER.
Neutralizing Agent: WEAK OR DILUTE ACID AND REDUCING AGENTS
Waste Disposal Methods: DISPOSAL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL
REGULATIONS. REPORTABLE QUANTITY: 100 LBS.
Handling And Storage Precautions: STORE IN COOL, DRY, VENTILATED AREA AWAY FROM
INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED. KEEP OUT OF REACH OF
CHILDREN.
Other Precautions: DO NOT TAKE INTERNALLY. AVOID CONTACT WITH EYES, SKIN/
CLOTHING. AVOID BREATHING DUST. CAUSES SEVERE IRRITATION AND BURNS. WASH
THOROUGHLY AFTER HANDLING. DO NOT STORE ABOVE 52C/125F.
=======================================================
Fire and Explosion Hazard Information
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Flash Point Text: NONE
Lower Limits: NOT RELEVANT
Upper Limits: NOT RELEVANT
Extinguishing Media: WATER SPRAY ONLY. NOT COMBUSTIBLE, BUT MAY IGNITE
COMBUSTIBLES. USE WATER SPRAY TO KEEP FIRE EXPOSED CONTAINERS COOL.
Fire Fighting Procedures: WEAR PROTECTIVE CLOTHING AND NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS. DO NOT USE DRY EXTINGUISHER CONTAINING
AMMONIUM COMPOUNDS.
Unusual Fire/Explosion Hazard: WILL EVOLVE CHLORINE GAS AT ELEVATED
TEMPERATURES.
=======================================================
Control Measures
=======================================================
Respiratory Protection: NONE REQUIRED WHERE ADEQUATE VENTILATION CONDITIONS
EXIST. IF AIRBORNE CONCENTRATION IS HIGH, WEAR A NIOSH-APPROVED DUST AND
CHLORINE RESPIRATOR OR SELF-CONTAINED BREATHING APPARATUS.
Ventilation: USE LOCAL EXHAUST VENTILATION TO MINIMIZE DUST AND CHLORINE
LEVELS.
Protective Gloves: NEOPRENE, PVC, RUBBER
Eye Protection: DUST-RESISTANT SAFETY GOGGLES
Other Protective Equipment: PROTECTIVE CLOTHING, EYE-WASH FACILITIES, SAFETY
SHOWER.
Work Hygienic Practices: OBSERVE GOOD INDUSTRIAL HYGIENE PRACTICES AND
RECOMMENDED PROCEDURES. WASH THOROUGHLY BEFORE EATING, DRINKING/SMOKING.
Supplemental Safety and Health: THIS NSN IS FOR SODIUM HYPOCHLORITE. THIS
PRODUCT IS CALCIUM HYPOCHLORITE.
=======================================================
Physical/Chemical Properties
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HCC: B1
NRC/State LIC No: NOT RELEVANT
B.P. Text: DECOMPOSES
Vapor Pres: 12.1
Spec Gravity: 1.175 @ 20C
PH: 11.0
Viscosity: NOT RELEVANT
Solubility in Water: SOLUBLE
Appearance and Odor: LIQUID SOLUTION WITH A STRAW YELLOW COLOR.
=======================================================
Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: TEMPERATURES ABOVE 125F/52C, HIGH HUMIDITY
Materials To Avoid: ACIDS, COMBUSTIBLES, ORGANICS, NITROGEN CONTAINING
COMPOUNDS, FLAMMABLE MATERIALS, DRY FIRE EXTINGUISHER (AMMONIUM CMPD)
Hazardous Decomposition Products: CHLORINE GAS
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT RELEVANT
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 90905
MSDS NAME: BLEACH SOLUTION
MSDS Prepared Date: 05/23/1996
Review Date: 11/15/1999
Net Unit Weight: 48.9 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CN
Container QTY: 1
Type Of Container: CAN
Additional Data: CARGO AIR ONLY. AFR-P5.
=======================================================
Detail DOT Information
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DOT PSN Code: HNU
DOT Proper Shipping Name: HYPOCHLORITE SOLUTION
Hazard Class: 8
UN ID Num: UN1791
DOT Packaging Group: III
Label: 8
Special Provision: B104,N34,T7
Packaging Exception: 154
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
Water/Ship/Other Req: 26
=======================================================
Detail IMO Information
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IMO PSN Code: IKL
IMO Proper Shipping Name: HYPOCHLORITE SOLUTION
IMDG Page Number: 8186
UN Number: 1791
UN Hazard Class: 8
IMO Packaging Group: II/III
Subsidiary Risk Label: -
EMS Number: 8-08
MED First Aid Guide NUM: 741
=======================================================
Detail IATA Information
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IATA PSN Code: NYC
IATA UN ID Num: 1791
IATA Proper Shipping Name: HYPOCHLORITE SOLUTION +
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: III
Packing Note Passenger: 819
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 821
=======================================================
Detail AFI Information
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AFI PSN Code: NYC
AFI Proper Shipping Name: HYPOCHLORITE SOLUTIONS
AFI PSN Modifier: WITH MORE THAN 5% BUT LESS THAN 16% AVAILABLE CHLORINE
AFI Hazard Class: 8
AFI UN ID NUM: UN1791
AFI Packing Group: III
Special Provisions: P5, N34
Back Pack Reference: A12.3
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: BLEACH SOLUTION
Company: LOS ANGELES CHEMICAL CO
Street: 4545 ARDINE ST
PO Box: 1987
City: SOUTH GATE CA
Zipcode: 90280
Health Emergency Phone: 213-583-4761/562-9500
Label Required IND: Y
Date Of Label Review: 09/14/1998
Status Code: C
MFG Label NO: UNKNOWN
Label Date: 09/14/1998
Year Procured: 1997
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: Slight
Hazard And Precautions: TARGET ORGANS:EYE, SKIN, RESPIRATORY & GI TRACTS.
ACUTE- DUST IRRITATES & MAY CAUSE BURNS. CORROSIVE TO EYES/SKIN. MAY
CAUSE SEVERE IRRITATION & BURNS. IF SWALLOWED, CAUSES IRRITATION &
BURNS OF GI TR ACT. CHRONIC- LUNG DAMAGE, TISSUE DESTRUCTION. STORE AWAY FROM
INCOMPATIBLES. SWEEP UP SPILL. PLACE IN AN APPROPRIATE CONTAINER FOR
DISPOSAL. FIRST AID- GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALED:M OVE TO
FRESH AIR. PROVIDE CPR/OXYGEN IF NEEDED. EYES:IMMEDIATELY FLUSH WITH WATER
FOR 15 MINUTES. HOLD EYELIDS OPEN. CALL PHYSICIAN. SKIN:FLUSH WITH PLENTY OF
WATER. ORAL:IF CONSCIOUS, DRINK LARGE AMO UNT OF WATER. DO NOT INDUCE
VOMITING. CALL DOCTOR.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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