DOW AGROSCIENCES LLC -- CONSERVE SC TURF & ORNAMENTAL INSECT CONTROL
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Material Safety Data Sheet
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NIIN: 01-457-6583
MSDS Num: CJYKJ
MSDS NAME: CONSERVE SC TURF & ORNAMENTAL INSECT CONTROL
Responsible Party
Name: DOW AGROSCIENCES LLC
Address: 9330 ZIONSVILLE ROAD
Box: 681428
City: INDIANAPOLIS IN 46268-1189
Info Phone: 800-992-5994
Emergency Phone Number: 800-992-5994
Resp. Party Other MSDS No.: 005864
Proprietary Ind: Y
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DOW AGROSCIENCES LLC
Address: 9330 ZIONSVILLE ROAD
Box: 681428
City: INDIANAPOLIS IN 46268-1189
Phone: 800-992-5994
Name: EHRLICH J C CHEMICAL CO INC
Address: 500 SPRING RIDGE DR
City: READING PA 19612-3848
Phone: 610-372-9700/FAX: 610-378-9744
Contract Number: SP0450-01-M-D695
Name: EHRLICH J C CHEMICAL CO INC
Address: 500 SPRING RIDGE DR
City: READING PA 19612-3848
Phone: 610-372-9700/FAX: 610-378-9744
Contract Number: SP0450-99-M-NG60
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Item Description Information
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Item Manager: S9G
Item Name: INSECTICIDE,SPINOSA
Unit of Issue: GL
UI Container Qty: 0
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: >5000 MG/KG RATS
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYE:MAY CAUSE SLIGHT EYE IRRITATION.SKIN: A SINGLE
PROLONGED EXPOSURE IS NOT LIKEY TO RESULT IN THE MATERIAL BEING ABSORBED
THROUGH SKIN IN HARMFUL AMOUNTS. PROLONGED EXPOSURE IS NOT LIKELY TO CAUSE S
IGNIFICANT SKIN IRRITATION. DID NOT CAUSE ALLERGIC SKIN IRRITATION OR
REACTIONS WHEN TESTED IN GUINEA PIGS.INGESTION: SINGLE DOSE ORAL TOXICITY IS
CONSIDERED EXTREMELY LOW. SMALL AMOUNTS SWALLOWED IN CIDENTAL TO NORMAL
HANDLING OPERATIONS ARE NOT LIKELY TO CAUSE INJURY; SWALLOWING AMOUNTS LARGER
MAY CAUSE INJURY. INHALATION:SINGLE EXPOSURE TO CONCENTRATE MIST IS NOT
LIKELY TO CAUSE ADVERSE EFFECT S.
Explanation Of Carcinogenicity: CANCER INFORMATION: FOR SPINOSAD, STUDIES WERE
NEGATIVE.
Signs And Symptions Of Overexposure: EYE:MAY CAUSE SLIGHT EYE IRRITATION.
First Aid: EYE: FLUSH EYES WITH PLENTY OF WATER. SKIN: WASH OFF IN FLOWING
WATER OR SHOWER. INGESTION: IF SWALLOWED, SEEK MEDICAL ATTENTION. DO NOT
INDUCE VOMITING UNLESS DIRECTED TO DO SO BY MEDICAL PERSONNEL. INHALATION:
REMOVE TO FRESH AIR IF EFFECTS OCCUR. CONSULT A PHYSICIAN. NOTE TO PHYSICIAN:
NO SPECIFIC ANTIDOTE. SUPPORTIVE CARE. TREATMENT BASED ON JUDGEMENT OF THE
PHYSICIAN IN RESPONSE TO REACTIONS OF THE PATIENT.
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Handling and Disposal
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Spill Release Procedures: USE NON-REACTIVE ABSORBENT TO ABSORB SMALL SPILLS AND
COLLECT FOR DISPOSAL. FOR LARGE SPILLS, REPORT TO CHEMTREC AND CONSULT DOW
AGRO SCIENCES FOR ASSISTANCE.
Waste Disposal Methods: IMPROPER DISPOSAL OF EXCESS PRODUCT,SPRAY MIXTURE, OR
RINSATE IS A VIOLATION OF THE FEDERAL LAW. IF THESE WASTES CANNOT BE DISPOSED
BY USE ACCORDING TO LABEL INSTRUCTION,CONTACT YOUR STATE PESTICIDE O R
ENVIRONMENTAL CONTROL AGENCY,OR THE HAZARDOUS WASTE REPRESENT-ATIVE AT THE
NEAREST EPA REGIONAL OF FICE FOR GUIDANCE.
Handling And Storage Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID EYE
CONTACT. DO NOT TAKE INTERNALLY. WASH THOROUGHLY AFTER HANDLING AND BEFORE
EATING, DRINKING, OR SMOKING. STORE PRODUCT IN ORIGINAL CONTAINER. SEE
PRODUCT LABEL FOR ADDITIONAL INSTRUCTIONS.
Other Precautions: U.S. PATENT NO. 5,496, 931. EPA REG. NO. 62719-291. KEEP OUT
OF REACH WITH CHILDREN. NOTICE: READ THE ENTIRE LABEL. USE ONLY ACCORDING TO
LAVEL DIRECTIONS. BEFORE BUYING OR USING THIS PRODUCT, READ "W ARRANTY
DISCLAIMER" AND "LIMITATION OF REMEDIES" ELSEWHERE ON THE LABLE.
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Fire and Explosion Hazard Information
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Flash Point Text: NOT DETERMINED
Lower Limits: ND
Upper Limits: ND
Extinguishing Media: TO EXTINGUISH COMBUSTIBLE RESIDUES OF THIS PRODUCT USE
WATER FOG, CARBON DIOXIDE, DRY CHEMICAL OR FOAM.
Fire Fighting Procedures: WEAR POSITIVE-PRESSURE, SELF-CONTAINED BREATHING
APPARATUS (SCBA) AND PROTECTIVE FIRE-FIGHTING CLOTHING (INCLUDES
FIRE-FIGHTING HELMET, COAT, PANTS, BOOTS, AND GLOVES). IF PROTECTIVE
EQUIPMENT IS NOT AVAILABLE OR NOT USED, FIGHT FIRE FROM A PROTECTED LOCATION
OR SAFE DISTANCE.
Unusual Fire/Explosion Hazard: KEEP PEOPLE AWAY. ISOLATE FIRE AREA AND DENY
UNNECESSARY ENTRY. UNDER FIRE CONDITIONS SOME COMPONETS OF THIS PRODUCT MAY
DECOMPOSE. THE SMOKE MAY CONTAIN UNIDENTIFIED TOXIC AND/OR IRRITATIONG
COMPOUND S.
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Control Measures
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Respiratory Protection: NO RESPIRATORY PROTECTION SHOULD BE NEEDED. THESE
PRECAUTIONS ARE SUGGESTED FOR CONDITIONS WITH A HIGH POTENTIAL FOR EXPOSURE.
IF HANDLING PROCEDURES ARE SUCH THAT THERE IS ONLY A LOW POTENTIAL FOR EX
POSURE, LESS PROTECTION MAY BE NEEDED. EMERGENCY CONDITIONS MAY REQUIRE
ADDITIONAL PRECAUTIONS.
Ventilation: GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT FOR MOST CONDITIONS.
Protective Gloves: NO PRECAUTIONS OTHER THAN CLEAN BODY-COVERING CLOTHING
SHOULD BE NEEDED.
Eye Protection: SAFETY GLASSES IS RECOMMENDED.
Supplemental Safety and Health: EXPOSURE GUIDE: PROPYLENE GLYCOL: AIHA WEEL IS
50 PPM TOTLA, 10 MG/M3 AEROSOL ONLY. THESE PRECAUTIONS ARE SUGGESTED FOR
CONDITIONS WITH A HIGH POTENTIAL FOR EXPOSURE. IF HANDLING PROCEDURES ARE
SUCH T HAT THERE IS ONLY A LOW POTENTIAL FOR EXPOSURE, LESS PROTECTION MAY BE
NEEDED. EMERGENCY CONDITIONS MAY REQUIRE MORE.
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Physical/Chemical Properties
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HCC: T4
Boiling Point: =100.C, 212.F
Vapor Pres: SIMILAR TO WATER
Solubility in Water: DISPERSIBLE
Appearance and Odor: OFF- WHITE TO LIGHT TAN LIQUID SUSPENSION, LOW ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THERMALLY STABLE AT TYPICAL USE TEMPERATURES.
SOME COMPONENTS OF THIS PRODUCT CAN DECOMPOSE AT ELEVATED TEMPERTURES.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: HAZARDOUS DECOMPOSITION PRODUCTS DEPEND UPON
TEMPERATURE, AIR SUPPLY, AND THE PRESENCE OF OTHER MATERIALS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT KNOWN TO OCCUR.
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Toxicological Information
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Toxicological Information: THE LD50 FOR SKIN ABSORPTION IN RABBITS IS >5000
MG/KG. THE ORAL LD50 FOR RATS IS >5000 MG/KG. SYSTEMIC (OTHER TARGET
ORGANS) EFFECTS: IN ANIMALS, HAS BEEN SHOWN TO CAUSE VACUOLATION OF CELLS IN
VARI OUS TISSUES AND CHANGES IN BLOOD AND SERUM BIOCHEMISTRY. DOSE LEVELS
PRODUCING THESE EFFECTS WERE MANY TIMES HIGHER THAN ANY DOSE LEVELS EXPECTED
FROM EXPOSURE DUE TO USE. TERATOLOGY: FOR SPINOSAD, DI D NOT CAUSE BIRTH
DEFECTS IN LAB ANIMALS. EVEN EXPOSURES HAVING AN ADVERSE EFFECT ON THE MOTHER
SHOULD HAVE NO EFFECT ON THE FETUS.
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Ecological Information
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Ecological: ENVIRONMENTAL FATE: MOVEMENT & PARTITIONING: BIOCONCENTRATION
POTENTIAL IS LOW. BIOCONCENTRATION FACTOR FOR RAINBOW TROUT ARE: SPINOSYN
A=19, SPINOSYN D=33. DEGRADATION AND PERSISTENCE: BASED ON INFOR MATION FOR
SPINOSYN A: THE PHOTOLYSIS HALF-LIFE IN SOIL IS 8.68 DAYS. THE PHOTOLYSIS
HALF-LIFE IN PH 7 BUFFER IS 0.96 DAYS. UNDER AEROBIC SOIL CONDITIONS THE HALF
LIFE IS 9.4 AND 14.5 DAYS. BASED ON I NFORMATION FOR SPINOSYN D: THE
PHOTOLYSIS HALF LIFE IN SOIL IS 9.44 DAYS. THE PHOTOLYSIS HALF-LIFE IN PH 7
BUFFER IS 0.84 DAYS. UNDER AEROBIC SOIL CONDITIONS THE HALF-LIFE IN 14.5
DAYS.
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MSDS Transport Information
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Transport Information: THIS PRODUCT IS NOT REGULATED BY DOT WHEN SHIPPED
DOMESTICALLY BY LAND.
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Regulatory Information
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Sara Title III Information: SARA 313 INFORMATION: TO THE BEST OF OUR KNOWLEDGE,
THIS PRODUCT CONTAINS NO CHEMICAL SUBJECT TO SARA TITLE III SECTION 313
SUPPLIER NOTIFICATION REQUIREMENTS. SARA HAZARD CATEGORY: THIS PRODUCT HAS B
EEN REVIEWED ACCORDING TO THE EPA "HAZARD CATEGORIES" PROMULGATED UNDER
SECTIONS 311 AND 312 OF THE (SARA TITLE III) AND IS CONSIDERED, UNDER
APPLICABLE DEFINITIONS, TO MEET THE FOLLOWING CATEGORIES: AN IMMEDIATE
HEALTH HAZARD.
Federal Regulatory Information: CERCLA OR SUPERFUND: TO THE BEST OF OUR
KNOWLEDGE, THIS PRODUCT CONTAINS NO CHEMICAL SUBJECT TO REPORTING UNDER
CERCLA.
State Regulatory Information: THE FOLLOWING PRODUCT COMPONENTS ARE CITED ON
CERTAIN STATE LISTS AS MENTIONED. NON-LISTED COMPONENTS MAY BE SHOWN IN THE
COMPOSITION SECTION OF THE MSDS. CHEMICAL NAME: 1,2-PROPANEDIOL. CAS NUMBER:
5 7-55-6. LIST: PA1. PA1=PENNSYLVANIA HAZARDOUS SUBSTANCE (PRESENT AT GREATER
THAN OR EQUAL TO 1.0).
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Other Information
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Other Information: ECOTOXICOLOGY: PRODUCT IS HIGHLY TOXIC TO MARINE MOLLUSCS ON
AN ACUTE BASIS (LC/EC50 BETWEEN 0.1 AND 1.0 MG/L IN MOST SENSITIVE SPECIES).
ACUTE EC50 FOR SHELL DEPOSITION INHIBITION IN EASTERN OYSTER ( CRASSOSTREA
VIRGINICA) IS 0.295 MG/L. PRODUCT IS MODERATELY TO SLIGHTLY TOXIC TO FISH ON
AN ACUTE BASIS (LC50 BETWEEN 1 AND 100 MG/L). ACUTE LC50 FOR MIRROR OR COMMON
CARP (CYPRINUS CARPIO) IS 3.49-4 .99 MG/L. ACUTE LC50 FOR BLUEGILL (LEPOMIS
MACROCHIRUS) IS 5.94 MG/L. ACUTE LC50 FOR SHEEPHEAD MINNOW (CYPRINODON
VARIEGETAS) IS 7.87 MG/L. ACUTE LC50 FOR RAINBOW TROUT (ONCORHYNCHUS MYKISS)
IS 30 MG/ L.
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Transportation Information
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Trans ID NO: 150975
MSDS NAME: CONSERVE SC TURF & ORNAMENTAL INSECT CONTROL
MSDS Prepared Date: 01/01/1998
Review Date: 01/08/2000
Net Unit Weight: 8.6 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: GL
Container QTY: 0
Additional Data: LTD QTY EXEMPT FROM LABEL+PLACARD (PKG GRP III ONLY,DOES NOT
SAY NO AIR):<=4 L/(5 KG SOLID). DRUG IF CONSUMER COMMODITY,RECLASSED AS
ORM-D(NO SHIPPING PAPER NEEDED):<= 250 ML OR 250 G IN COMBINATION
PACKAGING.ALL IN STRONG OUTER PACKAGING <=30 KG/66 LBS.
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Detail DOT Information
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DOT PSN Code: LKB
Symbols: G
DOT Proper Shipping Name: PESTICIDES, LIQUID, TOXIC, N.O.S.
Hazard Class: 6.1
UN ID Num: UN2902
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Special Provision: T14
Packaging Exception: 153
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 60 L
Max Qty Cargo: 220 L
Vessel Stow Req: A
Water/Ship/Other Req: 40
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Detail IMO Information
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IMO PSN Code: LKP
IMO Proper Shipping Name: PESTICIDE, LIQUID, TOXIC, N.O.S. o
IMDG Page Number: 6219
UN Number: 2902
UN Hazard Class: 6.1
IMO Packaging Group: I/II/III
Subsidiary Risk Label: -
EMS Number: 6.1-02
MED First Aid Guide NUM: *
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Detail IATA Information
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IATA PSN Code: TGT
IATA UN ID Num: 2902
IATA Proper Shipping Name: PESTICIDE, LIQUID, TOXIC, N.O.S. *
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 611
Max Quant Pass: 60L
Max Quant Cargo: 220L
Packaging Note Cargo: 618
Exceptions: A3,A4,A6
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Detail AFI Information
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AFI PSN Code: TGT
AFI Symbols: *
AFI Proper Shipping Name: PESTICIDES, LIQUID, TOXIC, N.O.S.
AFI Hazard Class: 6.1
AFI UN ID NUM: UN2902
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.5
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HAZCOM Label
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MSDS NAME: LABEL COVERED UNDER EPA REGS - HAZCOM LABEL NOT AUTHORIZED
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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