LUCIER CHEMICAL INDUSTRY DBA L -- SODIUM FLUOROSILICATE
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Material Safety Data Sheet
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NIIN: 00-088-7252
MSDS Num: CKBLZ
MSDS NAME: SODIUM FLUOROSILICATE
Responsible Party
Name: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Address: 415 PABLO AVE N
Box: 49000
City: JACKSONVILLE BEACH FL 32240-9000
Info Phone: 904-241-1200
Emergency Phone Number: 904-241-1200
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Item Description Information
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Item Manager: S9G
Item Name: SODIUM SILICOFLUORIDE,TECHNICAL
Specification Number: AWWA STD B 702-89
Type/Grade/Class: NONE
Unit of Issue: DR
Quantitative Expression: 00000000050LB
UI Container Qty: 1
Type of Container: 1A2
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Ingredients
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Cas: 16893-85-9
RTECS #: VV8410000
Name: SODIUM SILICOFLUORIDE/FLUOROSILICATE (NA2SIF6)
Percent by Wt: 99.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Name: WATER (H2O)
Percent by Wt: .5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Name: NAF.HF
Percent by Wt: .5
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Health Hazards Data
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LD50 LC50 Mixture: ORAL LD50 (RAT) IS 125 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: NO
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: ACUTE:FLUORIDE DUST MAY CAUSE IRRITATION OF EYES, SKIN AND
REPIRATORY TRACT. INGESTION OF FLUORIDE DUST MAY CAUSE KIDNEY DAMAGE, LOSS OF
CONSCIOUSNESS, AN DEATH. CHRONIC: MAY CAUSE EXCESSIVE CALCIFICA TION OF
LIGEMENTS OF THE RIBS, PELVIS, AND SPINAL COLUMN, SCLEROSIS, ENZYME EFFECTS
AND PULMONARY FIBROSIS. MAY CAUSE ENZYME SYSTEM EFFECTS.
Explanation Of Carcinogenicity: NO INGREDIENT OF A CONCENTRATION OF 0.1% OR
GREATER IS LISTED AS A CARCINOGEN OR SUSPECTED CARCINOGEN. (PER MFG MSDS)
Signs And Symptions Of Overexposure: FLUORIDE DUST MAY CAUSE EYES AND
RESPIRATORY TRACT IRRITATION. INGESTION: FLUORIDE DUST MAY CAUSE NAUSEA,
VOMITING, ABDOMINAL PAIN, DISARRHEA, SHORTNESS OF BREATH, DIFFICULTY
SPEAKING, THRIST, WEAKNES S OF PULSE, DISTURBED COLOR VISION, MUSCULAR
WEAKNESS, LOSS OF CONSCIOUSNESS, AND DEATH. KIDNEY INJURY AND BLEEDING MAY
OCCUR. CHRONIC: STIFFNESS AND LIMITATION OF MOTIONS , LOSS OF WEIGHT,
ANOREXIA, ANORAXLA, ANEMIA, WASTING, CACHEXIA, DENTAL EFFECTS,SKIN RASH.
Medical Cond Aggravated By Exposure: PRE-EXISTING RESPIRATORY DISORDERS SUCH AS
ASTHMA AND EMPHYSEMA.
First Aid: INHALATION: REMOVE PERSON TO FRESH AIR. IF NEEDED, RESUSCITATE, IF
BREATHING DIFFICULT GIVE OXYGEN. GET MEDICAL ATTENTION. EYES: FLUSH WITH LOTS
OF WATER FOR 15 MINUTES. SEE DOCTOR. SKIN: REMOVE CONTA MINATED CLOTHES AND
WASH EXPOSED SKIN AREA WITH SOAP AND WATER. GET MEDICAL ATTENTION. INGESTION:
DO NOT INDUCE VOMITING! IF CONSCIOUS, GIVE SEVERAL GLASSES OF MILK OR WATER.
GET IMMEDIATE MEDICAL ATT ENTION.
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Handling and Disposal
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Spill Release Procedures: WEAR NIOSH APPROVED PROTECTIVE CLOTHING AND BREATHING
APPARATUS. ISOLATE AREA. SHOVEL MATERIAL AND PLACE IN CLEAN, DRY CONTAINER
AND COVER. REMOVE CONTAINER FROM SPILL SITE FOR DISPOSAL. CONTACT CHEM TREC
AT1-800-424-9300 FOR 24-HOUR EMERGENCY ASSISTANCE.
Neutralizing Agent: MFR GAVE NO INFORMATION OF MSDS.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE, AND
LOCAL REGULATIONS.
Handling And Storage Precautions: STORE IN A COOL, DRY PLACE AWAY FROM ACIDS.
USE ONLY WITH ADEQUATE VENTILATION, DUST MASK OR SCBA. ALWAYS WEAR PROTECTIVE
CLOTHING.
Other Precautions: AVOID CONTACT WITH EYES, SKIN AND CLOTHING. KEEP BAG OR
CONTAINER CLOSED WHEN NOT IN USE. AVOID BREATHING DUST OR MIST. DO NOT GET ON
SKIN, CLOTHING OR IN EYES. WASH OFF WITH WATER. DO NOT TAKE INTERN ALLY. DO
NOT BREATHE DUST.
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Fire and Explosion Hazard Information
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Flash Point Text: NOT FLAMMABLE
Lower Limits: N/A.
Upper Limits: N/A.
Extinguishing Media: CHEMICAL IS NOT FLAMMABLE. FOAM, DRY CHEMICALS OR CARBON
DIOXIDE MAY BE USED IN AREA WHERE IT IS STORED.
Fire Fighting Procedures: WHEN THIS PRODUCT IS HEATED TO DECOMPOSITION (500C)
IT WILL GENERATE HIGHLY TOXIC GASES SUCH AS HYDROGEN FLUORIDE.
Unusual Fire/Explosion Hazard: EXTREME TEMPERATURES WILL CAUSE DECOMPOSITION
AND FORMATION OF FLUORINE. FIRE FIGHTERS SHOULD WEAR FULL PROTECTIVE
CLOTHING AND SCBA.
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Control Measures
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Respiratory Protection: WEAR A NIOSH APPROVED RESPIRATOR. SELF-CONTAINED
BREATHING APPARATUS MAY BE REQUIRED WHEN CHEMICAL IS HEATED TO DECOMPOSITION
OR IN SPILL AREA.
Ventilation: ADEQUATE VENTILATION TO MAINTAIN FLUORIDE CONCENTRATIONS BELOW
APPLICABLE STANDARDS.
Protective Gloves: IMPERVIOUS GLOVES.
Eye Protection: WEAR EYE PROTECTION AT ALL TIMES. SPLASH PROOF GOGGLES AND FACE
SHIELD.
Other Protective Equipment: WEAR PROTECTIVE IMPERVIOUS CLOTHING TO PREVENT
CONTACT WITH SKIN. PROTECT OPEN WOUNDS. HEATING TO DECOMPOSITION REQUIRES
FULL PROTECTIVE CLOTHING AND SELF-CONTAINED BREATHING APPARATUS.
Work Hygienic Practices: MFR GAVE NO INFORMATION OF MSDS.
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Physical/Chemical Properties
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HCC: T4
NRC/State LIC No: NOT RELEVANT
B.P. Text: DECOMPOSES@500C
M.P/F.P Text: DECOMPOSES@ 500C
Decomp Temp: =500.C, 932.F
Vapor Pres: N/A.
Vapor Density: N/A.
Spec Gravity: 2.679
PH: 3.1
Viscosity: UNKNOWN
Evaporation Rate & Reference: N/A.
Solubility in Water: 0.76 GM/100ML WATER@25C
Appearance and Odor: WSOLID,GRANULES,W HITE, ODORLESS, GRANULAR, CRYSTALLINE
MATERIAL.
Corrosion Rate: UNKNOWNN
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: CONTACT WITH STRONG ACIDS AND ALKALIES WILL CAUSE
FORMATION OF HYDROGEN FLUORIDE GAS.
Materials To Avoid: STRONG ACIDS, ALKALIES.
Hazardous Decomposition Products: TEMPERATURES ABOVE 500C SUCH AS FIRES, WILL
CAUSE DECOMPOSITION AND FORMATION OF HYDROFLUORIC ACID AND FLUORINE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Ecological Information
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MSDS Transport Information
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Transport Information: DOT PROPER SHIPPING NAME: SODIUM FLUOROSILLICATE, CLASS
6.1 (POISON), PKG III, UN2674. PLACARDING REQUIREMENT: KEEP AWAY FROM FOOD.
IMDG PLACARDING REQUIREMENT: TOXIC. FOR INTERNATIONAL TRANSPORTATION , SODIUM
FLUOROSILICATE IS REGULATED BY THE IMO AND IATA FOR VESSEL AND AIR MOVEMENT
AS A CLASS 6.1 TOXIC AND NOT MARKED AS A MARINE POLLUTANT. (IMDG PG 6250).
PACKAGING, MARKING AND SHIPPING PAPER DE SCRIPTIONS MUST PRECISELY REFLECT
THE REGULATION FOR EXPORT MOVEMENT.
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Regulatory Information
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Federal Regulatory Information: RCRA STATUS OF UNUSED MATERIAL IF DISCARDED:
NOT LISTED. HAZARDOUS WASTE NUMBER: NOT LISTED. EPA REG. NO.: 19713-49.
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Other Information
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Transportation Information
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Trans ID NO: 151377
MSDS NAME: SODIUM FLUOROSILICATE
MSDS Prepared Date: 03/01/1999
Review Date: 02/28/2001
Net Unit Weight: 50 LBS
Multiple KIT Number: 0
Unit Of Issue: DR
Container QTY: 1
Type Of Container: 1A2
Additional Data: TRANSPORTATION PER MFR'S MSDS. FOR INTERNATIONAL
TRANSPORTATION, PRODUCT IS REGULATED BY IMO AND IAT A AS CLASS 6.1 TOXIC AND
NOT MARKED AS MARINE POLLUTANT. PACKAGING, MARKING, LABELING, SHIPPING PAPER
DESCRIPTIONS MUST PRECISELY REFLECT REGULATION FOR EXPORT.
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Detail DOT Information
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DOT PSN Code: NFM
DOT Proper Shipping Name: SODIUM FLUOROSILICATE
Hazard Class: 6.1
UN ID Num: UN2674
DOT Packaging Group: III
Label: KEEP AWAY FROM FOOD
Packaging Exception: 153
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 100 KG
Max Qty Cargo: 200 KG
Vessel Stow Req: A
Water/Ship/Other Req: 26
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Detail IMO Information
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IMO PSN Code: NRZ
IMO Proper Shipping Name: SODIUM FLUOROSILICATE
IMDG Page Number: 6250
UN Number: 2674
UN Hazard Class: 6.1
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 6.1-04
MED First Aid Guide NUM: 750
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Detail IATA Information
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IATA PSN Code: WQL
IATA UN ID Num: 2674
IATA Proper Shipping Name: SODIUM FLUOROSILICATE
IATA UN Class: 6.1
IATA Label: TOXIC
UN Packing Group: III
Packing Note Passenger: 619
Max Quant Pass: 100KG
Max Quant Cargo: 200KG
Packaging Note Cargo: 619
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Detail AFI Information
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AFI PSN Code: WQL
AFI Proper Shipping Name: SODIUM FLUOROSILICATE
AFI Hazard Class: 6.1
AFI UN ID NUM: UN2674
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A10.6
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HAZCOM Label
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MSDS NAME: SODIUM FLUOROSILICATE
Company: LUCIER CHEMICAL INDUSTRY DBA LCI LTD
Street: 415 PABLO AVE N
PO Box: 49000
City: JACKSONVILLE BEACH FL
Zipcode: 32240-9000
Health Emergency Phone: 904-241-1200
Label Required IND: Y
Date Of Label Review: 02/05/2000
Status Code: A
Label Date: 02/05/2000
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE:FLUORIDE DUST MAY CAUSE IRRITATION OF EYES, SKIN
AND REPIRATORY TRACT. INGESTION OF FLUORIDE DUST MAY CAUSE KIDNEY DAMAGE,
LOSS OF CONSCIOUSNESS, AN DEATH. CHRONIC: MAY CAUSE EXCESSIVE CALCIFICA TION
OF LIGEMENTS OF THE RIBS, PELVIS, AND SPINAL COLUMN, SCLEROSIS, ENZYME
EFFECTS AND PULMONARY FIBROSIS. MAY CAUSE ENZYME SYSTEM EFFECTS.FIRST AID:
GET MEDICAL HELP IF SYMPTOMS PERSIST. INHALATION : MOVE TO FRESH AIR. PROVIDE
CPR/OXYGEN IF NEEDED, EYES: FLUSH WITH WATER FOR 15MINUTES. SKIN: WASH WITH
SOAP AND WATER. INGESTION: IF CONSCIOUS DRINK SEVERAL GLASSES OF MILK OR LAGE
AMOUNTS OF WATER. DO NOT INDUCE VOMITING.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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