EXXON CHEMICAL AMERICAS/A DIV -- TOLUENE
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Material Safety Data Sheet
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NIIN: 00-290-0048
MSDS Num: CJZVD
MSDS NAME: TOLUENE
Responsible Party
Name: EXXON CHEMICAL AMERICAS/A DIV OF EXXON CORP
Address: 13501 KATY FWY
Box: 3272
City: HOUSTON TX 77253-3272
Info Phone: 713-870-6000713-584-7600
Emergency Phone Number: 800-726-2015
Resp. Party Other MSDS No.: 92931650
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Item Description Information
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Item Manager: S9G
Item Name: TOLUENE,TECHNICAL
Specification Number: CID A-A-59107
Type/Grade/Class: NONE
Unit of Issue: CN
Quantitative Expression: 00000000005GL
UI Container Qty: 1
Type of Container: 1A1 METAL CAN
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Ingredients
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Name: *** PROPRIETARY ***
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Health Hazards Data
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LD50 LC50 Mixture: NOT PROVIDED.
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: POTENTIAL HEALTH EFFECTS: EYE CONTACT: IRRITATING, BUT
DOES NOT INJURE EYE TISSUE. SKIN CONTACT: FREQUENT/PROLONGED CONTACT MAY
IRRITATE AND CAUSE DERMATITIS. INHALATION: HIGH VAPOR/AEROSOL CONCENTRA TIONS
(>1000 PPM) ARE IRRITATING TO THE EYES AND RESPIRATORY TRACT. MAY CAUSE
HEADACHES, DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, CENTRAL
NERVOUS SYSTEM EFFECTS, BRAIN DAMAGE AND POSSIBLY D EATH. INGESTION: SMALL
AMOUNTS OF THIS PRODUCT ASPIRATED INTO THE RESPIRATORY SYSTEM DURING
INGESTION OR VOMITING MAY CAUSE MILD TO SEVERE PULMONARY INJURY, POSSIBLY
PROCESSING TO DEATH. CHRONIC: MAY CAUSE BRAIN AND NERVOUS SYSTEM DAMAGE.
Explanation Of Carcinogenicity: NONE
Signs And Symptions Of Overexposure: EYE CONTACT: IRRITATING, BUT DOES NOT
INJURE EYE TISSUE. SKIN CONTACT: FREQUENT/PROLONGED CONTACT MAY IRRITATE AND
CAUSE DERMATITIS. INHALATION: HIGH VAPOR/AEROSOL CONCENTRATIONS (>1000
PPM) ARE IRRIT ATING TO THE EYES AND RESPIRATORY TRACT. MAY CAUSE HEADACHES,
DIZZINESS, ANESTHESIA, DROWSINESS, UNCONSCIOUSNESS, CENTRAL NERVOUS SYSTEM
EFFECTS, BRAIN DAMAGE AND POSSIBLY DEATH. INGESTION: SMALL AMOU NTS OF THIS
PRODUCT ASPIRATED INTO THE RESPIRATORY SYSTEM DURING INGESTION OR VOMITING
MAY CAUSE MILD TO SEVERE PULMONARY INJURY, POSSIBLY PROCESSING TO DEATH.
Medical Cond Aggravated By Exposure: SKIN CONTACT MAY AGGRAVATE AN EXISTING
DERMATITIS CONDITION.
First Aid: EYE CONTACT: FLUSH EYES WITH LARGE AMOUNT OF WATER UNTIL IRRITATION
SUBSIDES. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. SKIN CONTACT: FLUSH
WITH LARGE AMOUNT OF WATER; USE SOAP IF AVAILABLE. REM OVE GROSSLY
CONTAMINATED CLOTHING, INCLUDING SHOES, AND LAUNDER BEFORE REUSE. INHALATION:
USING PROPER RESPIRATORY PROTECTION, IMMEDIATELY REMOVE THE AFFECTED VICTIM
FROM EXPOSURE. ADMINISTER ARTIFICI AL RESPIRATION IF BREATHING IS STOPPED.
KEEP AT REST. CALL FOR PROMPT MEDICAL ATTENTION. INGESTION: IF SWALLOWED, DO
NOT INDUCE VOMITING. KEEP AT REST. GET PROMPT MEDICAL ATTENTION.
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Handling and Disposal
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Spill Release Procedures: ELIMINATE IGNITION SOURCES. PREVENT ADDITIONAL
DISCHARGES, IF POSSIBLE. SMALL SPILLS: IMPLEMENT CLEANUP PROCEDURES; LARGE
SPILLS: IMPLEMENT CLEANUP PROCEDURES AND KEEP PUBLIC AWAY AND ADVISE
AUTHORITI ES. PREVENT LIQUID FROM ENTERING SEWERS, WATERCOURSES, OR LOW
AREAS. CONTAIN WITH SAND OR EARTH. DO NOT USE COMBUSTIBLE MATERIAL SUCH AS
SAWDUST. RECOVER WITH EXPLOSION-PROOF PUMP/SUITABLE ABSORBENT.
Neutralizing Agent: NOT RELEVANT
Waste Disposal Methods: CONSULT AN EXPERT ON DISPOSAL OF RECOVERED MATERIAL AND
ENSURE CONFORMITY TO LOCAL DISPOSAL REGULATIONS.
Handling And Storage Precautions: KEEP CONTAINER CLOSED. HANDLE AND OPEN
CONTAINERS WITH CARE. STORE IN A COOL, WELL VENTILATED PLACE AWAY FROM
INCOMPATIBLE MATERIALS. DO NOT HANDLE OR STORE NEAR AN OPEN FLAME, HEAT OR
OTHER SOURCES O F IGNITION. PROTECT MATERIAL FROM DIRECT SUNLIGHT.
Other Precautions: MATERIAL WILL ACCUMULATE STATIC CHARGES WHICH MAY CAUSE AN
ELECTRICAL SPARK (IGNITION SOURCE). USE PROPER GROUNDING PROCEDURES. DO NOT
PRESSURIZE, CUT, HEAT, OR WELD CONTAINERS. EMPTY PRODUCT CONTAINE RS MAY
RETAIN PRODUCT RESIDUE. DO NOT REUSE EMPTY CONTAINERS WITHOUT COMMERCIAL
CLEANING OR RECONDIT IONING.
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Fire and Explosion Hazard Information
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Flash Point Method: TCC
Flash Point: =7.2C, 45.F
Flash Point Text: TYPICAL
Autoignition Temp: =552.2C, 1026.F
Autoignition Temp Text: APPROX
Lower Limits: 1.4%
Upper Limits: 7.4%@77F
Extinguishing Media: EITHER ALLOW FIRE TO BURN OUT UNDER CONTROLLED CONDITIONS
OR EXTINGUISH WITH FOAM, OR DRY CHEMICAL. TRY TO COVER LIQUID SPILLS WITH
FOAM.
Fire Fighting Procedures: RESPIRATORY AND EYE PROTECTION REQUIRED FOR FIRE
FIGHTING PERSONNEL. AVOID SPRAYING WATER DIRECTLY INTO STORAGE CONTAINERS DUE
TO DANGER OF BOILOVER. SHUT OFF "FUEL" TO FIRE. IF A LEAK OR SPILL HAS NO T
IGNITED, USE WATER SPRAY TO DISPERSE THE VAPORS.
Unusual Fire/Explosion Hazard: THIS LIQUID IS VOLATILE AND GIVES OFF INVISIBLE
VAPORS. EITHER THE LIQUID OR VAPOR MAY SETTLE IN LOW AREAS OR TRAVEL SOME
DISTANCE ALONG THE GROUND OR SURFACE TO IGNITION SOURCES WHERE THEY MAY
IGNITE OR EXPLODE.
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Control Measures
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Respiratory Protection: WHERE CONCENTRATIONS IN AIR MAY EXCEED THE LIMITS GIVEN
AND ENGINEERING, WORK PRACTICE OR OTHER MEANS OF EXPOSURE REDUCTION ARE NOT
ADAQUATE, NIOSH/MSHA APPROVED RESPIRATORS MAY BE NECESSARY TO PREVEN T
OVEREXPOSURE BY INHALATION.
Ventilation: USE OF MECHANICAL DILUTION VENTILATION IS RECOMMENDED WHENEVER
THIS PRODUCT IS USED IN A CONFINED SPACE, IS HEATED ABOVE AMBIENT
TEMPERATURES, OR IS AGITATED.
Protective Gloves: CHEMICAL RESISTANT GLOVES
Eye Protection: SAFETY GLASSES WITH SIDE SHIELDS.
Other Protective Equipment: LONG SLEEVES AND CHEMICAL RESISTANT GLOVES.
LABORATORY SAMPLES SHOULD BE HANDLED IN A LAB HOOD. PROVIDE MECHANICAL
VENTILATION OF CONFINED SPACES.
Work Hygienic Practices: NOT PROVIDED.
Supplemental Safety and Health: NONE
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Physical/Chemical Properties
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HCC: F2
NRC/State LIC No: NOT RELEVANT
B.P. Text: 230F TO 232F
Melt/Freeze Pt: <-60.C, -76.F
Decomp Text: UNKNOWN
Vapor Pres: 22 @ 68F APPROXIMATE
Vapor Density: 3.20
Spec Gravity: 0.87 @ 60
Viscosity: 0.7 @ 77F
Evaporation Rate & Reference: 2.4 (N-BUTYL ACETATE=1)
Solubility in Water: 0.05% @ 77F CALCULATED
Appearance and Odor: CLEAR,COLORLESS LIQUID; AROMATIC ODOR
Percent Volatiles by Volume: 100
Corrosion Rate: NOT PROVIDED.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: NOT APPLICAPLE.
Materials To Avoid: STRONG OXIDIZING AGENTS, CONCENTRATED NITRIC OR SULPHURIC
ACID, HALOGENS, OR MOLTEN SULPHUR.
Hazardous Decomposition Products: NONE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: NOT APPLICAPLE.
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Toxicological Information
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Toxicological Information: SEE HEALTH SECTION.
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Ecological Information
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Ecological: SEE SPILL SECTION AND REGULATORY SECTIONS.
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MSDS Transport Information
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Transport Information: DOT SHIPPING DESCRIPTION: TOLUENE, 3, UN 1294, II
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Regulatory Information
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Sara Title III Information: UNDER THE PROVISIONS OF TITLE III, SECTIONS 311/312
OF THE SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT, THIS PRODUCT IS
CLASSIFIED INTO THE FOLLOWING HAZARD CATEGORIES: IMMEDIATE HEALTH, DELAYED
HEAL TH, FIRE. THIS INFORMATION MAY BE SUBJECT TO THE PROVISIONS OF THE
COMMUNITY RIGHT-TO-KNOW REPORTING REQUIREMENTS (40 CFR 370) IF THRESHOLD
QUANTITY CRITERIA ARE MET. THIS PRODUCT CONTAINS THE FOLLOWI NG SECTION 313
REPORTABLE INGREDIENTS: TOLUENE 108-88-3, 100.0%.
Federal Regulatory Information: THIS PRODUCT IS LISTED ON THE TOXIC SUBSTANCE
CONTROL ACT (TSCA) INVENTORY AS A UVCB (UNKNOWN., VARIABLE COMPOSITION OR
BIOLOGICAL) CHEMICAL AT CAS REGISTRY NUMBER 108-88-3.
CERCLA: IF THE REPORTABL E QUANTITY OF THIS PRODUCT IS ACCIDENTALLY SPILLED,
THE INCIDENT IS SUBJECT TO THE PROVISIONS OF THE COMPREHENSIVE ENVIRONMENTAL
RESPONSE, COMPENSATION AND LIABILITY ACT (CERCLA) AND MUST BE REPORTED TO
THE NATIONAL RESPONSE CENTER BY CALLING 800-424-8802. THE REPORTABLE QUANTITY
OF THIS PRODUCT IS 1,000 POUNDS. THIS PRODUCT CONTAINS TOLUENE.
State Regulatory Information: NOT PROVIDED.
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Other Information
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Transportation Information
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Trans ID NO: 151252
MSDS NAME: TOLUENE
MSDS Prepared Date: 03/21/1998
Review Date: 05/21/2001
Net Unit Weight: 36.2 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CN
Container QTY: 1
Type Of Container: 1A1 METAL CAN
Additional Data: THE MAXIMUM ALLOWED BY PASSENGER/CARGO AIR: 5L/60 L. PROPER
SHIPPING NAME, UN ID NUMBER, HAZARD CLAS S, AND PACKING GROUP PER MSDS.
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Detail DOT Information
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DOT PSN Code: OJY
DOT Proper Shipping Name: TOLUENE
Hazard Class: 3
UN ID Num: UN1294
DOT Packaging Group: II
Label: FLAMMABLE LIQUID
Special Provision: T1
Packaging Exception: 150
Non Bulk Pack: 202
Bulk Pack: 242
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
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Detail IMO Information
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IMO PSN Code: OSR
IMO Proper Shipping Name: TOLUENE
IMDG Page Number: 3285
UN Number: 1294
UN Hazard Class: 3.2
IMO Packaging Group: II
Subsidiary Risk Label: -
EMS Number: 3-07
MED First Aid Guide NUM: 310
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Detail IATA Information
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IATA PSN Code: YEL
IATA UN ID Num: 1294
IATA Proper Shipping Name: TOLUENE
IATA UN Class: 3
IATA Label: FLAMMABLE LIQUID
UN Packing Group: II
Packing Note Passenger: 305
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 307
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Detail AFI Information
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AFI PSN Code: YEL
AFI Proper Shipping Name: TOLUENE
AFI Hazard Class: 3
AFI UN ID NUM: UN1294
AFI Packing Group: II
Special Provisions: P5
Back Pack Reference: A7.3
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HAZCOM Label
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MSDS NAME: TOLUENE
Company: EXXONMOBIL CHEMICAL CO, DIV OF EXXON MOBILCORP.
Street: 13501 KATY FWY
PO Box: 3272
City: HOUSTON TX
Zipcode: 77253-3272
Health Emergency Phone: 800-726-2015
Label Required IND: Y
Date Of Label Review: 05/21/2001
Status Code: C
MFG Label NO: UNKNOWN.
Year Procured: 2000
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: NO
Health Hazard: Moderate
Contact Hazard: Slight
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: TOLUENE, WARNING! VAPOR HARMFUL, FLAMMABLE VAPOR
HAZARDS: FLAMMABLE LIQUID. TOXIC BY INHALATION, INGESTION AND ABSORPTION.
KEEP AWAY FROM HEAT, SPARKS & OPEN FLAMES. KEEP CONTAINER CLOSED. USE
WITH AD EQUATE VENTILATION.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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