ICI PAINTS -- ZY6008, PREM QUAL SPRAY FLAT WHITE
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Material Safety Data Sheet
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MSDS Num: CKGBF
MSDS NAME: ZY6008, PREM QUAL SPRAY FLAT WHITE
Responsible Party
Name: ICI PAINTS
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Info Phone: 800-545-2643
Emergency Phone Number: 800-545-2643
Resp. Party Other MSDS No.: M 0000000001 1100
Review Ind: Y
Published: Y
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Contractor Summary
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Name: GLIDDEN PAINT, ICI PAINTS NORTH AMERICA
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643/216-344-8207
Name: ICI PAINTS
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643
Name: ICI PAINTS DIV GLIDDEN
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: 800-545-2643
Name: ICI PAINTS INC
Address: 925 EUCLID AVE
City: CLEVELAND OH 44115
Phone: (216) 344-8000
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Ingredients
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Cas: 68476-86-8
Name: PETROLEUM GASES, LIQUEFIED, SWEETENED (LIQUIFIED PETROLEUM GASES,
SWEETENED)
% low Wt: 20.
% high Wt: 30.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: NO ESTABLISHED
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
ACGIH STEL: NOT ESTABLISHED
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Cas: 108-88-3
RTECS #: XS5250000
Name: BENZENE, METHYL- (TOLUENE)
% low Wt: 10.
% high Wt: 20.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 100 PPM
OSHA STEL: 150 PPM
ACGIH TLV: 188 MG/M3;50 PPM
ACGIH STEL: 150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 71-43-2
RTECS #: CY1400000
Name: BENZENE
% low Wt: .01
% high Wt: .1
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 1 PPM
OSHA STEL: 5 PPM
ACGIH TLV: 32 MG/M3;10 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Cas: 67-64-1
RTECS #: AL3150000
Name: ACETONE
% low Wt: 20.
% high Wt: 30.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 2400 MG/M3;1000 PPM
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: 1780 MG/M3;750 PPM
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 68131-77-1
Name: DISTILLATES (PETROLEUM), STEAM-CRACKED, POLYMD. (PETROLEUM RESINS)
% low Wt: 1.
% high Wt: 5.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 5 MG/M3
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 64742-89-8
Name: SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPHATIC. (LIGHT ALIPHATIC SOLVENT
NAPHTHA (PETROLEUM))
% low Wt: 6.
% high Wt: 15.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 300 PPM
OSHA STEL: 400 PPM
ACGIH TLV: 300 PPM
ACGIH STEL: NOT ESTABLISHED
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Cas: 1330-20-7
RTECS #: ZE2100000
Name: BENZENE, DIMETHYL- (XYLENE)
% low Wt: 1.
% high Wt: 5.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 100 PPM
OSHA STEL: 150 PPM
ACGIH TLV: 434 MG/M3;100 PPM
ACGIH STEL: 651 MG/M3;150 PPM
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
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Cas: 13463-67-7
RTECS #: XR2275000
Name: TITANIUM OXIDE, (TITANIUM DIOXIDE)
% low Wt: 1.
% high Wt: 5.
Other REC Limits: NOT ESTABLISHED
OSHA PEL: 10 MG/M3
OSHA STEL: NOT ESTABLISHED
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 14807-96-6
RTECS #: WW2710000
Name: TALC
% low Wt: 1.
% high Wt: 5.
OSHA PEL: SEE TABLE Z-3
ACGIH TLV: 2 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: PRIMARY ROUTE(S) OF EXPOSURE: INHALATION, SKIN CONTACT,
EYE CONTACT, INGESTION. EFFECTS OF OVEREXPOSURE: INHALATION: IRRITATION OF
THE RESPIRATORY TRACT. PROLONGED INHALATION MAY LEAD TO MUCOUS MEMBR ANE
IRRITATION, FATIGUE, DROWSINESS, DIZZINESS AND/OR LIGHTHEADEDNESS, HEADACHE,
UNCOORDINATION, NAUSEA, VOMITING, ABDOMINAL PAIN, COUGHING, DIFFICULTY WITH
SPEECH, CENTRAL NERVOUS SYSTEM DEPRESSION, RESPIRATORY PROBLEMS,
INTOXICATION, CONFUSION, ANESTHETIC EFFECT OF NARCOSIS, DIFFICULTY OF
BREATHING, BLOOD ABNORMALITIES, LIVER DAMAGE, KIDNEY DAMAGE, LOSS OF
CONSCIOUSNESS, RESPIRATORY FAILURE, ASP HYXIATION, DEATH. (EFFECTS OF
OVEREXP)
Explanation Of Carcinogenicity: BENZENE: OSHA REGULATED CARCINOGEN, 29 CFR
1910.1028; GROUP 1 CARCINOGEN, IARC MONOGRAPHS VOLUME 29, PAGE 93, 1982;
KNOWN CARCINOGEN, NTP 8TH ANNUAL REPORT ON CARCINOGENS, 1998.
Signs And Symptions Of Overexposure: HEALTH HAZ (CONT): SKIN CONTACT:
IRRITATION OF SKIN. PROLONGED OR REPEATED CONTACT CAN CAUSE DERMATITIS,
DEFATTING. EYE CONTACT: IRRITATION OF EYES. PROLONGED OR REPEATED CONTACT
CAN CAUSE CONJUNCTIV ITIS, BLURRED VISION, TEARING OF EYES, REDNESS OF EYES,
SEVERE EYE IRRITATION, CORNEAL INJURY. INGESTION: INGESTION MAY CAUSE
INFLAMATION AND DAM,AGE DUE TO ASPIRATION OF MATERIAL INTO LUNGS, MUCOUS
MEMBRANE IRRITATION, NAUSEA, VOMITING, DIARRHEA, GASTRO-INTESTINAL
DISTURBANCES, CENTRAL NERVOUS SYSTEM DEPRESSION. TOLUENE APPEARS ON THE NAVY
OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N).
Medical Cond Aggravated By Exposure: EYE, SKIN, RESPIRATORY DISORDERS. LUNG
DISORDERS. CARDIAC ABNORMALITIES. KIDNEY DISORDERS. LIVER DISORDERS.
First Aid: INHALATION: REMOVE TO FRESH AIR. RESTORE AND SUPPORT CONTINUED
BREATHING. GET EMERGENCY MEDICAL ATTENTION. HAVE TRAINED PERSON GIVE OXYGEN
IF NECESSARY. GET MEDICAL HELP FOR ANY BREATHING DIFFICULTY. SKIN CONTACT:
FLUSH FROM SKIN WITH WATER. THEN WASH THOROUGHLY WITH SOAP AND WATER. REMOVE
CONTAMINATED CLOTHING. WASH CONTAMINATED CLOTHING BEFORE RE-USE. EYE
CONTACT: FLUSH IMMEDIATELY WITH LARGE AMOUNTS OF WATER, ESPECIALLY UNDER
LIDS FOR AT LEAST 15 MINUTES. IF IRRITATION OR OTHER EFFECTS PERSIST, OBTAIN
MEDICAL TREATMENT. INGESTION: IF SWALLOWED, OBTAIN MEDICAL TREATMENT
IMMEDIATELY.
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Handling and Disposal
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Spill Release Procedures: COMPLY WITH ALL APPLICABLE HEALTH AND ENVIRONMENTAL
REGULATIONS. ELIMINATE ALL SOURCES OF IGNITION. VENTILATE AREA WITH
EXPLOSION-PROOF EQUIPMENT. SPILLS MAY BE COLLECTED WITH ABSORBENT MATERIALS.
USE NON-SPARKING TOOLS. EVACUATE UNNECESSARY PERSONNEL. PLACE COLLECTED
MATERIAL IN PROPER CONTAINER. COMPLETE PERSONAL PROTECTIVE EQUIPMENT MUST BE
USED DURING CLEANUP. LARGE SPILLS - (ECOLOGICAL INFO)
Waste Disposal Methods: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE REGULATIONS.
AVOID DISCHARGE INTO NATURAL WATERS.
Handling And Storage Precautions: STORE BELOW 80F (27C). KEEP AWAY FROM HEAT,
SPARKS & OPEN FLAME. KEEP CONTAINERS TIGHTLY CLOSED & UPRIGHT WHEN
NOT IN USE. GROUND EQUIP WHEN TRANSFERRING TO PREVENT ACCUM OF STATIC CHARGE.
EMPTY CONTA INERS MAY CONTAIN HAZARDOUS REIDUES. USE ONLY W/ ADEQUATE
VENTILATION. DO NOT TAKE INTERNALLY.
Other Precautions: KEEP OUT OF REACH OF CHILDREN. AVOID CONTACT WITH SKIN &
EYES, & BREATHING OF VAPORS. WASH HANDS THOROUGHLY AFTER HANDLING, ESP
BEFORE EATING/SMOKING. AVOID CONDS WHICH RESULT IN FORM OF INHALABLE PAR
TICLES I.E. SPRAYING OR ABRADING (SANDING) PAINTED SURF. IF CAN'T BE AVOIDED,
USE APPROP RESP PROT A S DIR IN PROT INFO.
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Fire and Explosion Hazard Information
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Flash Point Method: SCC
Flash Point: =-17.2C, 1.F
Lower Limits: 2.5
Upper Limits: 13.0
Extinguishing Media: DRY CHEMICAL OR FOAM. WATER FOG. CARBON DIOXIDE.
Fire Fighting Procedures: WATER MAY BE USED TO COOL AND PROTECT EXPOSED
CONTAINERS. FIREFIGHTERS SHOULD USE FULL PROTECTIVE CLOTHING, EYE PROTECTION,
AND SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED TO
EXTREME HEAT OR FIRE. VAPORS MAY IGNITE EXPLOSIVELY AT AMBIENT TEMPERATURES.
VAPORS ARE HEAVIER THANAIR AND MAY TRAVEL LONG DISTANCES TO A SOURCE OF IGNIT
ION AND FLASH BACK. MAY DECOMPOSE UNDER FIRE CONDITIONS EMITTING IRRITANT
AND/OR TOXIC GASES.
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Control Measures
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Respiratory Protection: CONTROL ENVIRONMENTAL CONCENTRATIONS BELOW APPLICABLE
STANDARDS. WHERE RESPIRATORY PROTECTION IS REQUIRED, USE ONLY NIOSH APPROVED
RESPIRATORS IN ACCORDANCE WITH OSHA STANDARD 29 CFR 1910.134.
Ventilation: PROVIDE DILUTION VENTILATION OR LOCAL EXHAUST TO PREVENT BUILD-UP
OF VAPORS. USE EXPLOSION PROOF EQUIPMENT. USE NON-SPARKING EQUIPMENT.
Protective Gloves: IMPERVIOUS GLOVES
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N).
Other Protective Equipment: EYE WASH AND SAFETY SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). IMPERVIOUS CLOTHING, APRON, BOOTS.
Supplemental Safety and Health: CONTAINS A CHEMICAL THAT IS MODERATELY TOXIC BY
INGESTION. OTHER EFFECTS OF OVEREXPOSURE MAY INCLUDE TOXICITY TO LIVER,
KIDNEY, CENTRAL NERVOUS SYSTEM, BLOOD, HEART. MAY BE ABSORBED THROUGH SKIN.
THE INTERNATIONAL AGENCY FOR RESEARCH ON CANCER (IARC) HAS DETERMINED THAT
THERE IS SUFFICIENT EVIDENCE FOR THE (OTHER INFO)
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Physical/Chemical Properties
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B.P. Text: 133-527F
Vapor Pres: NOT DETERMINED
Spec Gravity: .765, WT PER GAL: 6.37
PH: NOT DETERMINED
Solubility in Water: NOT DETERMINED
Appearance and Odor: WHITE AEROSOL PAINT
Percent Volatiles by Volume: 94.76
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: ELEVATED TEPERATURES, CONTACT WITH OXIDIZING
AGENT, SPARKS, OPEN FLAME, IGNITION SOURCES.
Materials To Avoid: OXIDIZERS, ACIDS, BASES, AMINES, NITRIC ACID, VINYL
POLYMERS.
Hazardous Decomposition Products: CARBON MONOXIDE, CARBON DIOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR
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Toxicological Information
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Toxicological Information: LIQUIFIED PETROLEUM GASES, SWEETENED - LD50: NOT
ESTABLISHED. TOLUENE - LD50: 5000.00 MG/KG ORAL RAT. BENZENE - LD50: NOT
ESTABLISHED. ACETONE - LD50: 5800.00 MG/KG ORAL RAT. PETROLEUM RESINS - LD5
0: NOT ESTABLISHEDLIGHT ALIPHATIC SOLVENT NAPHTHA (PETROLEUM) - LD50: 8.00
ML/KG ORAL RAT. XYLENE - LD50: 4300 MG/KG ORAL RAT. TITANIUM DIOXIDE -
LD50: 24.00 GM/KG ORAL RAT.
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Ecological Information
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Ecological: N/P. SPILL PROC (CONT): SHUT OFF LEAK IF SAFE TO DO SO. DIKE AND
CONTAIN SPILL. PUMP TO STORAGE OR SALVAGE VESSELS. USE ABSORBENT TO PICK UP
EXCESS RESIDUE. KEEP SALVAGABLE MATERIAL AND RINSE WATER O UT OF SEWERS AND
WATER COURSES. SMALL SPILLS - USE ABSORBENT TO PICK UP RESIDUE AND DISPOSE OF
PROPERLY.
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MSDS Transport Information
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Transport Information: DOT: PAINT, 3, UN1263, PG II, CONSUMER COMMODITY, ORM-D.
IMDG: AEROSOLS, CLASS 2, UN1950, LIMITED QUANTITY. IATA: NOT DETERMINED.
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Regulatory Information
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Sara Title III Information: THESE CHEMICALS ARE SUBJECT TO SARA 313 REPORTING
REQUIREMENTS (40 CFR PART 372): TOLUENE, BENZENE, XYLENE.
Federal Regulatory Information: THESE CHEMICALS ARE A HAZARDOUS SUBSTANCE AS
DEFINED BY CERCLA (40 CFR PART 302.4): TOLUENE, BENZENE, ACETONE, XYLENE.
State Regulatory Information: N/P. OTHER INFO (CONT): INHALATION.
ADDITIONALLY, DELIBERATE INHALATION OF TOLUENE MAY RESULT IN CARDIAC
SENSITIZATION WHICH CAN CAUSE IRREGULAR HEART RHYTHM AND SUDDEN DEATH.
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Other Information
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Other Information: CARCINOGENICITY OF BENZENE TO HUMANS AND EXPERIMENTAL
ANIMALS (GROUP 1). THE NATIONAL TOXICOLOGY PROGRAM (NTP) HAS DETERMINED THAT
BENZENE IS KNOWN TO BE CARCINOGENIC. BENZENE IS REGULATED BY OSHA AS A
CARCINOGEN. NOTICE - REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED
OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM
DAMAGE. INTENTIONAL MISUSE BY CONCENTRATING AND INHA LING THE CONTENTS MAY BE
HARMFUL OR FATAL. DILIBERATE INHALATION OF TOLUENE HAS BEEN ASSOCIATED WITH
NEONATAL EFFECTS IN HUMANS. DEVELOPMENTAL TOXICITY HAS ALSO BEEN DEMONSTRATED
IN LABORATORY ANIMALS EXPOSED TO TOLUENE BY (STATE REGS)
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HAZCOM Label
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MSDS NAME: ZY6008, PREM QUAL SPRAY FLAT WHITE
Assigned IND: Y
Company: ICI PAINTS
Street: 925 EUCLID AVE
City: CLEVELAND OH
Zipcode: 44115
Health Emergency Phone: 800-545-2643
Label Required IND: Y
Date Of Label Review: 04/04/2000
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: Severe
Reactivity Hazard: None
Hazard And Precautions: FLAMM AEROSOL. ACUTE: INHAL: RESP TRACT IRRIT. MUC
MEMB IRRIT, FATIGUE, DROWSINESS, DIZZINESS, LTHEADED, HDACHE, UNCOORD,
NAUSEA, VOMIT, ABDOM PAIN, COUGH, DIFF SPEECH, CNS DEPRESS, RESP PROBS, INTOX
ICATION, CONFUSION, ANESTH EFFECT, NARCOSIS, DIFF BREATHING, BLOOD ABNORM,
LIVER DMG, KIDNEY DMG, UNCONSCIOUS, RESP FAILURE, ASPHYX, DEATH. SKIN:
IRRIT, DERMATITIS, DEFATTING. EYES: SEV IRRIT, CONJUN CT, BLUR VISION,
TEARING, REDNESS, CORNEAL INJURY. INGEST: ASP HAZARD, MUC MEMBIRRIT, NAUSEA,
VOMIT, DIARRHEA, GI DISTURB, CNS DEPRESS. CHRONIC: BENZENE IS REG AS A BLOOD
CARCIN (FP N). TOLUENE IS A NAVY OCCUP CHEMICAL REPRODUCTIVE HAZARD (FP N).
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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