LIDOCHEM INC -- PHORSPHORIC ACID 85% TECHNICAL GRADE
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Material Safety Data Sheet
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NIIN: 01-244-7686
MSDS Num: CKXXQ
MSDS NAME: PHORSPHORIC ACID 85% TECHNICAL GRADE
Responsible Party
Name: LIDOCHEM INC
Address: 20 VILLAGE CT
City: HAZLET NJ 07730-1532
Info Phone: 732-888-8000
Emergency Phone Number: 732-888-8000
Resp. Party Other MSDS No.: 417
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: LIDOCHEM INC
Address: 20 VILLAGE CT
City: HAZLET NJ 07730-1532
Phone: 732-888-8000
Name: TELECHEM INTERNATIONAL, INC
Address: 524 E WEDDELL DRIVE SUITE 3
City: SUNNYVALE CA 94089-2115
Phone: 916-941-3688
Contract Number: SP0450-01-M-D547
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Item Description Information
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Item Manager: S9G
Item Name: ORTHOPHOSPHORIC ACID,TECHNICAL
Specification Number: O-O-670B
Type/Grade/Class: CL 1
Unit of Issue: DR
Quantitative Expression: 00000000055GL
UI Container Qty: 0
Type of Container: DRUM
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Ingredients
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Cas: 7664-38-2
RTECS #: TB6300000
Name: PHOSPHORIC ACID
Percent by Wt: 85.
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: 3 MG/M3
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Health Hazards Data
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LD50 LC50 Mixture: LD50 ORAL RAT = 1530 MG/KG
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EYES: LIQUID CONTACT WILL CAUSE SEVERE BURNS, WHICH MAY
RESULT IN BLINDNESS. MIST (IF FORMED) CAN IRRITATE. SKIN: PROLONGED CONTACT
OF ACID WITH SKIN WILL CAUSE SEVERE BURNS. MIST (IF FORMED) CAN IRRI TATE.
INGESTION: CORROSION OF MOUTH, GULLET AND DIGESTIVE TRACT, NAUSEA, VOMITING,
POSSIBLE CIRCULATORY SHOCK AND LOSS OF CONSCIOUSNESS, CAN BE FATAL.
INHALATION: MIST IF FORMED, WILL IRRITATE MUCOUS MEMBRANES AND RESPIRATORY
TRACT, MAY CAUSE LACRIMATION, COUGHING, SNEEZING, SALIVATION, AND LABORED
BREATHING. SEVERE EXPOSURES MAY CAUSE CHEMICAL PNEUMONITIS.
Explanation Of Carcinogenicity: THIS PRODUCT DOES NOT CONTAIN ANY SUBSTANCES
THAT ARE CONSIDERED BY OSHA, IARC OR ACGIH TO BE PROBABLE OR SUSPECTED HUMAN
CARCINOGEN.
Signs And Symptions Of Overexposure: EYES: LIQUID CONTACT WILL CAUSE SEVERE
BURNS, WHICH MAY RESULT IN BLINDNESS. MIST (IF FORMED) CAN IRRITATE. SKIN:
SEVER BURNS. MIST (IF FORMED) CAN IRRITATE. INGESTION: CORROSION OF MOUTH,
GULLET AND DIGESTIVE TRACT. NAUSEA, VOMITING, POSSIBLE CIRCULATORY SHOCK AND
LOSS OF CONSCIOUSNESS. INHALATION MIST, IF FORMED, WILL IRRITATE MUCOUS
MEMBRANES AND RESPIRATORY TRACT, MAY CAUSE LACRIMATION, COUGHI NG, SNEEZING,
SALIVATION, AND LABORED BREATHING. SEVERE EXPOSURES MAY CAUSE CHEMICAL
PNEUMONITIS.
First Aid: INGESTION: IF VICTIM IS CONSCIOUS AND ALERT , GIVE 2-3 GLASSES OF
WATER TO DRINK AND DO NOT INDUCE VOMITING. NEVER GIVE ANYTHING TO EAT OR
DRINK TO SOMEONE WHO IS UNCONSCIOUS, HAVING CONSULSIONS, OR U NABLE TO
SWALLOW. SEEK IMMEDIATE MEDICAL ATTENTION. DO NOT LEAVE VICTIM UNATTENDED. TO
PREVENT ASPIRATION OF SWALLOWED PRODUCT, LAY VICTIM ON SIDE WITH HEAD LOWER
THAN WAIST. VOMITING MAY OCCUR SPONTA NEOUSLY. IF VOMITING OCCURS AND THE
VICTIM IS CONSCIOUS, GIVE WATER TO FURTHER DILUTE THE CHEMICAL. EYES: FLUSH
WITH RUNNING WATER FOR 15 MINUTES WHILE HOLDING EYELIDS APART. .. SEE "OTHER
INFORMATIO N" SECTION.
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Handling and Disposal
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Spill Release Procedures: IF POSSIBE, DIKE SPILL AND MOP OR PUMP INTO PLASTIC
POLY-LINED OR LACQUER LINED DRUMS, LABEL "CORROSIVE" AND STORE AWAY FROM HEAT
AND OUT OF DIRECT SUNLIGHT. RESIDUAL MAY BE NEUTRALIED WITH SODA ASH.
Neutralizing Agent: SODA ASH.
Waste Disposal Methods: IN CASE OF SPILL, CONTAIN MATERIAL AND CALL LOCAL
AUTHORITIES FOR EMERGENCY ASSISTANCE. NEUTRALIZE THE SPILLED ACID WITH SODA
ASH OR LIME. COLLECT IN APPROPRIATE CONTAINERS. DISPOSE OF WASTE AT AN APP
ROPRITAE WASTE FACILITY ACCORDING TO CURRENT APPLICABLE LAWS AND REGULATIONS,
AND PRODUCT CHARACTERI STICS AT TIME OF DISPOSAL.
Handling And Storage Precautions: USE APPROPRIATE PERSONAL PROTECTIVE
EQUIPMENT. STORE & HANDLE IN A WELL VENTILATED AREA. LIQUID PHOSPHORIC
ACID WILL ATTACK SOME FORM OF PLASTICS. KEEP CONTAINERS CLOSED. STORE ABOVE
FREEZING POINT (> 70F) TO PREVENT CYSTALLIZATION. KEEP SEPARATE FROM
STRONG BASES.
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Fire and Explosion Hazard Information
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Flash Point Text: NON COMBUSTIBLE
Extinguishing Media: USE WATER SPRAY. AVOID SPRAYING INTO CONTAINERS. IF ONLY A
SMALL AMOUNT OF COMBUSTIBLES IS PRESENT, SMOTHER FIRE WITH DRY CHEMICAL. ALL
STANDARD AGENTS ARE ACCEPTABLE.
Fire Fighting Procedures: PHOSPHONIC ACID DOES NOT SUPPORT COMBUSTION, BUT LIKE
MOST ACIDS IT CAN ATTACK METALS WITH CONSEQUENT GENERATION OF HYDROGEN,
GIVING RISK TO POTENTIIALLY INFLAMMABLE AND EXPLOSIVE MIXTURES. USE WATER
SPRAY TO KEEP CONTAINERS COOL AND TO FLUSH ANY SPILLAGE AWAY FROM METALS AND
FIRES.
Unusual Fire/Explosion Hazard: CONTACT WITH COMMON METAL PRODUCES HYDROGEN,
WHICH MAY FORM FLAMMABLE OR EXPLOSIVE MIXTURES WITH AIR. SEE HAZARDOUS
DECOMPOSTION PRODUCTS.
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Control Measures
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Respiratory Protection: WHEN RESPIRATORS ARE REQUIRED, SELECT NIOSH/MSHA
APPROVED EQUIPMENT BASED ON ACTUAL OR POTENTIAL AIRBORNE CONCENTRATIONS AND
IN ACCORDANCE WITH THE LASTEST OSHA STANDARD (29CFR 1910.134) AND/OR ANSI Z
88.2 RECOMMENDATIONS. ALWAYS WEAR NIOSH APPROVED ACID GAS RESPIRATOR WITH
FULL FACE PIECE WHEN VAPOR OR MIST MAY EXCEED APPLICABLE CONCENTRATION
LIMITS.
Ventilation: LOCAL EXHAUST VENTILATION AT THE POINT OF GENERATION.
Protective Gloves: NEOPRENE CHEMICAL RESISTANT GLOVES.
Eye Protection: CHEMICAL SPLASH GOGGLES AND FACE SHIELD.
Other Protective Equipment: IMPERVIOUS ACID RESISTANT CLOTHING SHOULD BE WORN.
NIOSH APPROVED DUST AND MIST RESPIRATOR SHOULD BE USED. EYE-WASH AND SAFETY
SHOWER.
Work Hygienic Practices: ALL FOOD/SMOKING MATERIALS SHOULD BE KEPT IN A
SEPARATE AREA AWAY FROM STORAGE/ USE AREA. EATING, DRINKING, SMOKING SHOULD
BE POHIBITED WHRE THIS MATERILA IS BEING USED.
Supplemental Safety and Health: REMOVE CONTAMINATED CLOTHING & SHOES,
LAUNDER BEFORE REUSE. CLEANSE SKIN THOROUGLY AFTER CONTACT., BEFORE MEALS AND
END OF WORK PERIOD.
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Physical/Chemical Properties
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HCC: C1
Boiling Point: =158.C, 316.4F
Melt/Freeze Pt: =21.C, 69.8F
Vapor Pres: 2.2
Spec Gravity: 1.685
PH: 1.0
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR ODORLESS LIQUID
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THIS PRODUCT IS STABLE UNDER NORMAL AMBIENT
CONDITIONS OF TEMPERATURE AND PRESSURE. CONDITIONS TO AVOID: HEAT.
Materials To Avoid: FLUORINE, STRONG OXIDIZING AGENTS, STRONG REDUCING AGENTS,
BASES, METALS, SULFUR TRIOXIDE PHOSPHORUS PENTOXIDE.
Hazardous Decomposition Products: FIRST FORMED IS THE ORTHO PHOSPHORIC ACID.
FURTHER HEATING FORMS THE PYRO & LATER THE METAPHOSPHRIC ACIDS, WHICH ARE
ALSO CORROSIVE BUT TO A LESSER DEGREE. OXIDES OF PHOSPHORUS, PHOSPHINE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: EYE EFFECTS: MATERIAL IS CORROSIVE TO EYES (119 MG
RABBIT). SKIN EFFECTS: MATERIAL IS CORROSIVE TO SKIN (595 MG/24 HR RABBIT).
DERMAL TOXICITY: LD50 DERMAL (RABBIT) = 2740 MG/KG. INHALATION EFFECTS: N OT
AVAILABLE. SENSITIZATION EFFECTS: NOT AVAILABLE. INGESTION EFFECTS: LD50 RATS
= 1530 MG/KG. REPRODUCTIVE & MUTAGENICITY EFFECTS: NOT AVAIABLE. TARGET
ORGANS: CAN CAUSE GASTROINTESTINAL TRACT, RESPI RATORY TRACT AND CIRCULATORY
SYSTEM DAMAGE.
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Ecological Information
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Ecological: BIODGRADABLITY: ANAEROBIC.ECOTOXICITY: NOT AVAILABLE. BIOLOGICAL
OXYGEN DEMAND (BOD): NOT AVAILABLE. CHEMICAL OXYGEN DEMAND: NOT AVAILABLE.
ACTIVATED SLUDGE RESPIRATION INHIBITION TEST: NOT AVAILAB LE. ADDITIONAL
INFO: HIGH CONCENTRATION IN RECEIVING WATERS, WILL INJURE AQUATIC LIFE BY THE
EFFECTS ON PH. IN THE WATER ACID IS HYDROLYSED TO ORTHOPHOSPHATE, WHICH MAY
ACT AS PLANT NUTRIENT ( CAUSING EUTROFICATION) OR PRECIPITATE HEAVY METALS.
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MSDS Transport Information
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Transport Information: PSN: PHOSPHORIC ACID SOLUTION, 8, UN1805, III. LABEL:
CORROSIVE.
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Regulatory Information
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Sara Title III Information: HAZARD CLASSES SEC 311/312: IMMEDIATE (ACUTE)
HEALTH HAZARD. SEC 313: THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICALS
SUBJECT TO THE REPORTING REQUIREMENTT OF SEC 313 OF EPCRA: PHOSPHORIC ACID
85% . CERCLA 40 CFR 117, 302:THIS PRODUST DOES NOT CONTAIN INGREDIENTS
SPECIFIED IN THE LIST OF EXTREMELY HAZARDOUS SUBSTANCES. CERCLA LISTED
SUBSTANCES ARE: PHOSPHORIC ACID, CAS #7664-38-2, RQ = 5000 LBS . SUPERFUND
SEC 110:THIS PRODUST DOES NOT CONTAIN INGREDIENTS LISTED AS HAZARDOUS
SUBSTANCES ON THE PRIORITY LIST OF CERCLA HAZARDOUS SUBSTANCES.
Federal Regulatory Information: OSHA STATUS: THIS PRODUCT IS HAZARDOUS UNDER
THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29 CFR
1910.1200. TSCA STATUS: LISTED/ NON-REPORTABLE.
State Regulatory Information: CALIFORNIA PROPOSITION 65: THIS PRODUCT DOES NOT
CONTAIN ANY CHEMICALS WHICH REQUIRE WARINING UNDER PROPOSITION 65. MICHIGAN
CRITICAL MATERIALS: THIS PRODUCT DOES NOT CONTAIN INGREDIENTS LISTED ON TH E
MICHIGAN CRITICAL MATERIALS REGISTER. CAA: NONE KNOWN. CWA:NONE KNOWN. RCRA:
NOT CONSIDERED A HAZARDOUS WASTE. CANADA CEPA: ALL INGREDIENTS ARE LISTED ON
DSL. CANADA W: PRODUCT IS CONTROLLED UND ER W.
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Other Information
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Other Information: CONT'D FIRST AID: REMOVE CONTACT LENSES, IF WEARING. DO NOT
RUB EYES. DO NOT TRY TO NEUTRALIZE WITH CHEMICALS. SEEK MEDICAL HELP
IMMMEDIATELY. SKIN: REMOVE CONTAMINATED CLOTHING, WASH AREA WITH SOAP &
WATER. WASH CLOTHING BEFORE REUSE. INHALATION: REMOVE TO FRESH AREA. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE
OXYGEN. SEEK MEDICAL HELP IMMEDIATELY. NFPA HAZARD RATINGS: HEALTH = 3;
FIRE=0; REACTIVIT=0; SPECIAL = N/A.
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Transportation Information
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Trans ID NO: 155855
MSDS NAME: PHORSPHORIC ACID 85% TECHNICAL GRADE
MSDS Prepared Date: 03/22/2000
Review Date: 01/25/2001
Net Unit Weight: 772 LB/DR
Multiple KIT Number: 0
Unit Of Issue: DR
Container QTY: 0
Type Of Container: DRUM
Additional Data: U/I: 55 GALLONS DRUM. RQ = 5000 LBS. THIS SHIPPMENT IS
FORBIDDEN BY AIR, INCLUDING PASSENGER AND CAR GO AIRCRAFT, AS IT EXCEEDS
LIMITS OF 5L AND 60L RESPECTIVELY.
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Detail DOT Information
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DOT PSN Code: LPJ
DOT Proper Shipping Name: PHOSPHORIC ACID
Hazard Class: 8
UN ID Num: UN1805
DOT Packaging Group: III
Label: CORROSIVE
Special Provision: A7,N34,T7
Packaging Exception: 154
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: LSR
IMO Proper Shipping Name: PHOSPHORIC ACID, LIQUID
IMDG Page Number: 8204
UN Number: 1805
UN Hazard Class: 8
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 8-08
MED First Aid Guide NUM: 700
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Detail IATA Information
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IATA PSN Code: TVT
IATA UN ID Num: 1805
IATA Proper Shipping Name: PHOSPHORIC ACID
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: III
Packing Note Passenger: 819
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 821
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Detail AFI Information
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AFI PSN Code: TVT
AFI Proper Shipping Name: PHOSPHORIC ACID
AFI Hazard Class: 8
AFI UN ID NUM: UN1805
AFI Packing Group: III
Special Provisions: P5, A7, N34
Back Pack Reference: A12.3
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HAZCOM Label
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MSDS NAME: PHORSPHORIC ACID 85% TECHNICAL GRADE
Company: LIDOCHEM INC
Street: 20 VILLAGE CT
City: HAZLET NJ
Zipcode: 07730-1532
Health Emergency Phone: 732-888-8000
Label Required IND: Y
Date Of Label Review: 01/25/2001
Status Code: A
Year Procured: 2001
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: CORROSIVE! CAUSES SEVERE BURNS. SEVERELY IRRITATING TO
SKIN, EYES, RESPIRATORY TRACT. CAUSES CORROSION OF THE MOUTH AND DIGESTIVE
TRACT. FIRST AID: EYE: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES. CA LL
PHYSICIAN. SKIN: FLUSH WITH PLENTY OFWATER. REMOVE CONTAMINATED CLOTHINGS.
WASH CLOTHING BEFORE REUSE. INHALATION: MOVE TO FRESH AIR. PROVIDE
CPR/OXYGEN IF NEEDED. INGESTION: DO NOT INDUCE VOMITIN G, GIVE 2 GLASSES OF
WATER. NEVER GIVE FLUID OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAS
CONVULSIONS. CALL A PHYSICIAN IMMEDIATELY. IF VOMITING OCCURS, KEEP HEAD
BELOW KNEES.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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