DSM COPOLYMER, INC. -- CARBOMIX BLACK MASTERBATCH, 1847, 1848, 3830,
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Material Safety Data Sheet
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MSDS Num: CLDBJ
MSDS NAME: CARBOMIX BLACK MASTERBATCH, 1847, 1848, 3830, 3838L
Responsible Party
Name: DSM COPOLYMER, INC.
Address: 5955 SCENIC HIGHWAY
Box: 2591
City: BATON ROUGE LA 70805
Info Phone: (504) 355-5655;(800) 535-9960
Emergency Phone Number: 504-355-5655
Resp. Party Other MSDS No.: SUPERSEDES CR 2256(R9/90)
Review Ind: Y
Published: Y
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Contractor Summary
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Name: DSM COPOLYMER, INC.
Address: 5955 SCENIC HIGHWAY
Box: 2591
City: BATON ROUGE LA 70805
Phone: (504) 355-5655;(800) 535-9960
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Ingredients
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Cas: 1333-86-4
RTECS #: FF5800000
Name: CARBON BLACK (LD50: UNKNOWN. LC50: UNKNOWN. HAZARD: NUISANCE DUST).
Percent by Wt: 40.
OSHA PEL: 3.5 MG/M3
ACGIH TLV: 3.5 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 9003-55-8
RTECS #: WL6478000
Name: STYRENE-BUTADIENE RUBBER
Percent by Wt: 52.
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Cas: 61790-12-3
Name: DISPROPORTIONATED TALL OIL. (MFR CAS# 8052-10-5)
Percent by Wt: 4.5
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Cas: 64742-04-7
RTECS #: PY8042500
Name: AROMATIC PETROLEUM OIL (LD50 (ORAL,RAT): 5-15 GM/KG. LC50: UNKNOWN.
HAZARD: CARCINOGEN).
Percent by Wt: 28.
OSHA PEL: 5 MG/M3
ACGIH TLV: 5 MG/M3
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Health Hazards Data
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LD50 LC50 Mixture: LD50=NE; LC50=N/A.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: CANCER HAZARD. CONTAINS STYRENE-BUTADIENE RUBBER, AROMATIC
PETROLEUM OIL AND CARBON BLACK, WHICH ARE LISTED AS RESPIRATORY, INTESTINAL
AND SKIN CARCINOGENS (FP N). NO ACUTE HAZARDS OR EFFECTS KNOWN. A ROMATIC
PETROLEUM OIL HAS BEEN SHOWN TO CAUSE SKIN TUMORS IN LABORATORY ANIMALS.
EYES: NOT A PROBABLE SOURCE OF EXPOSURE. PARTICULATES MAY SCRATCH EYE SURFACE
OR CAUSE IRRITATION. SKIN: SINGLE, PROLO NGEDEXPOSURE NOT LIKELY TO RESULT IN
MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS. REPEATED PROLONGED
EXPOSURE MAY CAUSE SKIN IRRITATION AND INCREASE RISK OF SKIN CANCER. EXPOSURE
TO (OVERE XPOSURE)
Explanation Of Carcinogenicity: CARBON BLACK: IARC GROUP 2B, VOLUME 65, PAGE
149, 1996. AROMATIC PETROLEUM OIL: IARC GROUP 1, VOLUME 7, PAGE 252, 1987.
STYRENE-BUTADIENE RUBBER (RUBBER INDUSTRY): IARC GROUP 1, SUPPLEMENT 7, PAGE
23 2, 1987. CARBON BLACK (COAL TAR & COAL TAR PITCH VOLATILES): OSHA
1910.1029.
Signs And Symptions Of Overexposure: HEALTH HAZARDS, ACUTE/CHRONIC (CONT'D):
HOT MATERIAL MAY CAUSE THERMAL BURNS. INGESTION: NOT A PROBABLE SOURCE OF
EXPOSURE. INHALATION: NOT A PROBABLE SOURCE OF EXPOSURE UNDER CONDITIONS OF
NORMAL US E. HOT FUMES OR VAPORS WHICH MAY FORM DURING PROCESSING CAN CAUSE
IRRITATION TO RESPIRATORY TRACT.
Medical Cond Aggravated By Exposure: SOME INDIVIDUALS WITH SPECIFIC
SENSITIVITIES MAY EXHIBIT EYE, NOSE, THROAT OR THERMAL IRRIT W/ PROLONGED
EXPOS TO PROCESSING FUMES/VAPORS.INDIVIDUALS W/PRE-EXISTING SKIN DISORDERS
SHOULD AVOID CONTACT.
First Aid: EYE CONTACT: REMOVE AS FOR ANY FOREIGN OBJECT. FLUSH WITH CLEAN
WATER FOR 15 MINUTES. OBTAIN MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN:
WASH WITH SOAP AND WATER. REMOVE CONTAMINATED CLOTHING. IF THERMAL
IRRITATION, FLUSH AFFECTED AREA WITH COLD WATER TO DISSIPATE HEAT, THEN COVER
WITH CLEAN COTTON SHEETING OR GAUZE AND GET PROMPT MEDICAL ATTENTION.
INHALATION: IF DUST, FUMES OR VAPOR ARE INHA LED, MOVE TO FRESH AIR, AID
BREATHING IF NECESSARY. OBTAIN MEDICAL ATTENTION IF IRRITATION PERSISTS.
INGESTION: UNLIKELY TO OCCUR (MFR). CONTACT A PHYSICIAN IMMEDIATELY (FP N).
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Handling and Disposal
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Spill Release Procedures: REPACKAGE UNCONTAMINATED RUBBER. REUSE OR DISPOSE OF
AS NOTED IN DISPOSAL SECTION IF CONTAMINATED.
Waste Disposal Methods: REUSE IF POSSIBLE. DISPOSE IAW LOCAL, STATE &
FEDERAL REGULATIONS & APPLICABLE ENVIRONMENTAL REGULATIONS. MATERIAL AS
SUPPLIED IS NOT CHARACTERIZED AS HAZARDOUS UNDER RCRA.
Handling And Storage Precautions: STORE AT AMBIENT TEMPERATURE, KEEP AWAY FROM
EXCESSIVE HEAT AND FLAME AND STORE IN ABSENCE OF DIRECT, NATURAL OR ARTIFICAL
LIGHT.
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Fire and Explosion Hazard Information
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Flash Point Method: COC
Flash Point: =210.C, 410.F
Autoignition Temp: >388.C, 730.4F
Extinguishing Media: MOST FIRE EXTINGUISHING MEDIA PERMITTED. WATER
RECOMMENDED; CARBON DIOXIDE NOT RECOMMENDED.
Fire Fighting Procedures: TREAT AS A HYDROCARBON FIRE. WEAR NIOSH-APPROVED
SELF-CONTAINED BREATHING APPARATUS (SCBA) & FULL FACESHIELD. PERSONNEL
NOT HAVING SUITABLE RESPIRATORY PROTECTION SHOULD LEAVE THE AREA TO PREVENT
EXPO SURE TO TOXIC COMBUSTION GASES. SENSITIVITY TO IMPACT/SHOCK: NA.
SENSITIVITY TO STATIC DISCHARGE: NA.
Unusual Fire/Explosion Hazard: IGNITION TEMP: ABOVE 210C (410F). COMBUSTIBLE:
YES, W/PRESENCE OF IGNITION SYSTEM. HAZARDOUS COMBUSTIONS PRODUCTS: CARBON
MONOXIDE, CARBON DIOXIDE, PRODUCTS FROM INCOMPLETE COMBUSTION, OXIDES OF
NITRO GEN & SULFUR, ACID FUMES & TOXIC GASES. COMBUSTIBLE: YES, WITH
PRESENCE OF AN IGNITION SYSTEM. UP/LOW EXPLOS LEVEL: NA.
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Control Measures
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Respiratory Protection: NOT NORMALLY REQ'D AT AMBIENT TEMPERATURES. IF
PROCESSING IN AREA WHERE VENTILATION IS INADEQUATE, WEAR A NIOSH-APPROVED
ORGANIC VAPOR RESPIRATOR WITH MECHANICAL FILTRATION. IF PROCESSING CONDITIONS
G ENERATE DUST ABOVE PEL, WEAR NIOSH APPROVED RESPIRATOR FOR NUISANCE DUST.
Ventilation: LOCAL EXHAUST VENTILATION IS RECOMMENDED DURING ALL HOT PROCESSING
OPERATIONS.
Protective Gloves: IMPERVIOUS GLOVES (FP N). WHERE CONTACT W/ HOT
MATERIAL:THERMAL RESIST GLOVES.
Eye Protection: ANSI APPROVED CHEMCIAL SAFETY GOGGLES AND FACESHIELD (FP N).
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). WEAR CLOTHING APPROPRIATE TO PREVENT SKIN CONTACT. WEAR ARM
PROTECTION. USE GLOVES RESISTANT TO CHEMICAL & PETROLEUM DISTILLATES.
Work Hygienic Practices: AVOID SKIN & EYE CONTACT, PRACTICE GOOD PERSONAL
HYGIENE. AVOID INHALATION OF FUMES OR VAPORS FROM HOT RUBBERS, COMPOUNDS &
VULCANIZATES. AVOID GENERATION OF AND PROLONGED BREATHING OF DUST.
Supplemental Safety and Health: PHYSICAL/CHEMICAL PROPERTIES (CONT'D): IGNITION
TEMPERATURE: ABOVE 210C (410F). ODOR THRESHOLD: NE. COEFFICIENT IN WATER/OIL
DISTRIBUTION: NE.
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Physical/Chemical Properties
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Spec Gravity: 1.10-1.15
Solubility in Water: @20C - INSOLUBLE
Appearance and Odor: SOLID, BALES, BLACK, WITH GREY BALE COATING. ODOR:NONE.
Percent Volatiles by Volume: 0.75 MAX
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: IGNITION SOURCE; PRODUCT IS COMBUSTIBLE. PRODUCT
IS STABLE AT AMBIENT TEMPERATURE AND PRESSURE.
Materials To Avoid: NONE KNOWN.
Hazardous Decomposition Products: COMBUSTION PRODUCTS WILL BE CARBON MONOXIDE,
CARBON DIOXIDE, COMBUSTION PRODUCTS OF SULFUR AND NITROGEN AND PRODUCTS FROM
INCOMPLETE COMBUSTION.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: AROMATIC PETROLEUM OIL [COMPONENT]: CARCINOGENIC
ACCORDING TO IARC & HAZARDOUS COMMUNICATION STANDARD 29CFR 1910.1200.
CARBON BLACK IS CONSIDERED A NUISANCE DUST BY 29CFR 1910.1000. REPRODUCTIVE
EFFEC T, TERATOGENICITY, MUTAGENICITY: NONE REPORTED. OTHERS: SKIN IRRIT:
OLEIC ACID 15 MG/3D-I (HUMANS): MODERATE. AROMATIC PETROLEUM OIL: 3.5/8.0
(RABBIT) MODERATE. ADDITIONAL PROD INFO: CHEMICAL NAME: ST YRENE-BUTADIENE
RUBBER, AROMATIC OIL-EXTENDED. CARBON BLACK MASTERBATCH. PRODUCT USE: RUBBER
ARTICLES/RUBBER-MODIFIED ARTICLES. CAS NUMBER: NA/MIXTURE. CAS NAME (RUBBER
ONLY): 1,3-BUTADIENE POLYMER WI TH ETHENYLBENZENE.
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Ecological Information
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Ecological: N/P. OTHER INFO (CONT'D): INGREDIENT KNOWN TO BE CARCINOGENIC AS A
CARCINOGEN, IF NO TEST DATA ON THE MIXTURE IS AVAILABLE. NOTE 3: CARBON
BLACK, WHEN INCORPORATED INTO RUBBER IN THE FORM DELIVERED, I S NO LONGER
BELIEVED TO BE A NUISANCE DUST HAZARD BY DSM COPOLYMER. NOTE 4: AROMATIC
PETROLEUM OILS HAVE CAUSED SKIN CANCER IN LAB ANIMALS ACCORDING TO REPORTS OF
IARC. THEY CONTAIN POLYNUCLEAR AROMAT IC SUBSTANCES WHICH HAVE CAUSED CANCER
IN LAB ANIMALS. IT IS NOT KNOWN WHETHER OR NOT THE REPEATED, PROLONGED SKIN
CONTACT OF THE RUBBER CONTAINING THE AROMATIC PETROLEUM OIL PRESENTS A SKIN
CANCER RI SK TO HUMANS. NOTE 5: (TRANSPORT INFO)
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MSDS Transport Information
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Transport Information: DOT: U.S.-DESIGNATION & LABELING NOT APPLICABLE AS
PRODUCT IS NOT DEFINED OR DESIGNATED AS A HAZ MATL BY U.S. DEPT OF
TRANSPORATION UNDER TITLE 49 OF CFR. CANADA: NOT REGULATED UNDER CANADIAN
TRANSPOR TATION OF DANGEROUS GOODS REGULATIONS. ECOLOGICAL INFORMATION
(CONT'D): SPECIFIC EXPOSURE STANDARDS FOR THIS PRODUCT & ITS COMPONENTS
HAVE NOT BEEN ESTABLISHED. THE LIMITS SHOWN IN CONTROL MEASURES AR E
SUGGESTED AS MINIMUM CONTROL GUIDELINES. STANDARDS FOR PARTICULATE POLYCYCLIC
AROMATIC HYDROCARBON (PPAH) & COAL TAR PITCH VOLATILES (CTPV) AS BENZENE
SOLUBLES ARE BASED UPON COAL COKING & NOT UPON THE SPECIFIC PETROLEUM
(STATE INFO)
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Regulatory Information
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Sara Title III Information: SECTION 302/304-EXTREMELY HAZARDOUS SUBSTANCES:
NONE. SECTION 311-HAZARDOUS SUBSTANCES:NOT APPLICABLE. SECTION 313:HIS
PRODUCT IS NOT SUBJECT TO REPORTING REQUIREMENTS (SEE 40 CFR372). (FED
REG)-TSCA: COMPONENTS OF PRODUCT ARE LISTED UNDER TSCA CHEMICAL SUBSTANCE
INVENTORY. FDA: NOT APPROVED FOR FOOD OR DIRECT FOOD CONTACT. LABELS: OSHA/W:
REQUIRED.
Federal Regulatory Information: W: THIS PRODUCT IS CONSIDERED A CONTROLLED
PRODUCT UNDER CANADA'S WORKPLACE HAZ MATL INFORMATION SYSTEM BECAUSE IT
CONTAINS 1.0-2.0 WEIGHT PERCENT OLEIC ACID, CAS NO. 112-80-1 (A COMPONENT IN
THE DISPROPORTIONATED TALL OIL) CARBON BLACK & AROMATIC PETOLEUM OIL.
OLEIC ACID: LD50-74 GM/KG 9 (RAT ORAL) LC50-UNKNOWN [HAZARD: SKIN IRRITANT].
AROMATIC OIL: 5-15 GM/KG (RAT ORAL). LC50-UNKNOWN. [HAZAR D: CARCINOGEN].
CARBON BLACK: LD50-UNKNOWN. LC50-UNKNOWN [HAZARD: NUISANCE DUST]. CEPA:
COMPONENTS O F THIS PRODUCT ARE INCLUDED IN CANADA'S DSL. EEC: AROMATIC
PETROLEUM OILS ARE CONSIDERED HAZ BY THE EUROPEAN ECONOMIC COMMUNITY. (SARA)
State Regulatory Information: N/P. TRANSPORT INFORMATION (CONT'D): EXTRACT OIL.
THESE EXPOSURE LIMITS APPLY ONLY IF AEROSOLS ARE EMITTED FROM THIS PRODUCT.
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Other Information
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Other Information: NFPA: HEALTH-1. FIRE-1. REACTIVITY-0. CARBON BLACK, WHEN
INCORPORATED INTO THE RUBBER IN THE FORM DELIVERED, IS NO LONGER BELIEVED TO
BE A NUISANCE DUST HAZARD BY DSM COPOLYMER. ALUMINUM SILICATE MAY POSE A
NUISANCE DUST HAZARD DURING PROCESSING. ADDITIONAL INFO: NOTE 1: THIS DATA
REPRESENTS LOWEST POSSIBLE LIMIT & IS FOR THE AROMATIC PETROLEUM OIL
INGREDIENT. AROMATIC PETROLEUM OIL IS SOLUBLE IN THE SBR COMPONENT &
DATA ON THE BLEND HASN'T BEEN ESTABLISHED. NOTE 2: OSHA 29 CFR 1910.1200
& W (CANADA) & MANY U.S. STATE RIGHT-TO-KNOW LEGISLATION CONSIDERS
PRODUCTS CONTAINING 0.1% BY WEIGHT O R MORE OF AN (CONT'D IN ECOLOGICAL)
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HAZCOM Label
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MSDS NAME: CARBOMIX BLACK MASTERBATCH, 1847, 1848, 3830, 3838L
Assigned IND: Y
Company: DSM COPOLYMER, INC.
Street: 5955 SCENIC HIGHWAY
PO Box: 2591
City: BATON ROUGE LA
Zipcode: 70805
Health Emergency Phone: 504-355-5655
Label Required IND: Y
Date Of Label Review: 05/23/2001
Status Code: A
Origination Code: G
Hazard And Precautions: CANCER HAZARD. CONTAINS STYRENE-BUTADIENE RUBBER,
AROMATIC PETROLEUM OIL AND CARBON BLACK, WHICH ARE LISTED AS RESPIRATORY,
INTESTINAL AND SKIN CARCINOGENS (FP N). NO ACUTE HAZARDS OR EFFECTS KNOWN. A
ROMATIC PETROLEUM OIL HAS BEEN SHOWN TO CAUSE SKIN TUMORS IN LABORATORY
ANIMALS. EYES: NOT A PROBABLE SOURCE OF EXPOSURE. PARTICULATES MAY SCRATCH
EYE SURFACE OR CAUSE IRRITATION. SKIN: SINGLE, PROLO NGEDEXPOSURE NOT LIKELY
TO RESULT IN MATERIAL BEING ABSORBED THROUGH SKIN IN HARMFUL AMOUNTS.
REPEATED PROLONGED EXPOSURE MAY CAUSE SKIN IRRITATION AND INCREASE RISK OF
SKIN CANCER. EXPOSURE TO (OVERE XPOSURE)
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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