PPG INDUSTRIES INC -- CALCIUM HYPOCHLORITE TABLETS 65%, 0122
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Material Safety Data Sheet
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MSDS Num: CLCYZ
MSDS NAME: CALCIUM HYPOCHLORITE TABLETS 65%, 0122
Responsible Party
Name: PPG INDUSTRIES INC
Address: ONE PPG PLACE
City: PITTSBURGH PA 15272
Info Phone: 1-800-245-2974 (CAL HYPO)
Emergency Phone Number: 304-843-1300
Resp. Party Other MSDS No.: EDITION 7
Preparer's Name: PRODUCT SAFETY, CHEMICALS
Review Ind: Y
Published: Y
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Contractor Summary
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Name: PPG INDUSTRIES INC
Address: ONE PPG PLACE
City: PITTSBURGH PA 15272
Phone: 1-800-245-2974 (CAL HYPO)
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Ingredients
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Cas: 7778-54-3
RTECS #: NH3485000
Name: CALCIUM HYPOCHLORITE
> Wt: 65.
EPA Rpt Qty: 10 LBS
DOT Rpt Qty: 10 LBS
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Name: NOTE: 65% AVAILABLE CHLORINE. 35% INERT INGREDIENTS (INCLUDES 5.5-10%
MOISTURE).
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: DANGER! STRONG OXIDIZING AGENT! MIX
ONLY WITH WATER. CONTAMINATION MAY CAUSE FIRE OR EXPLOSION. DO NOT ADD THIS
PRODUCT TO ANY DISPENSING DEVICE CONTAINING REMNANTS OF ANY OTHER PR ODUCT.
PRECAUTIONS: DO NOT SWALLOW. SWALLOWING MAY CAUSE INJURY OR DEATH. DO NOT GET
IN EYES, ON SKIN, OR ON CLOTHING. MAY CAUSE BURNS. AVOID BREATHING DUST.
IRRITATING TO NOSE AND THROAT. WASH HANDS AFTER HANDLING. KEEP OUT OF REACH
OF CHILDREN. ACUTE: INHALATION: INHALATION OF DUST & DISPOSITION OF
PARTICLES IN RESP TRACT CAN LEAD TO IRRITATION OF TISSUE & CAUSE A
VARIETY OF EFFECTS DEPENDING O N CONCENTRATION & INCLUDE: (SIGNS/SYMPS)
Explanation Of Carcinogenicity: THIS PRODUCT IS NOT LISTED AS A
CARCINOGEN/SUSPECTED CARCINOGEN BY NTP, IARC, OSHA. CARCINOGENISIS: ALTHOUGH
NO STUDY HAS BEEN CONDUCTED WITH CALCIUM HYPOCHLORITE, THE CARCINOGENIC
POTENTIAL OF SODIUM HYPOCHLORITE WAS STUDIED IN F344 RATS. AFTER 104 WEEKS
OF DRINKING WATER CONTAINING UP TO 2000 PPM SODIUM HYPOCHLORITE, THERE WAS NO
(WORK HYGIENE)
Signs And Symptions Of Overexposure: HEALTH HAZARDS (CONT'D): UPPER RESP TRACT
IRRITATION, NASAL CONGESTION, COUGHING, SORE THROAT, LARYNGITIS &
SHORTNESS OF BREATH. IN OPERATIONS WHERE THERE ARE HIGH CONCENTRATIONS OF
RESPIRABLE PARTICU LATES, PULMONARY EDEMA (FLUID IN LUNG) MAY BE PRODUCED. IF
NOT TREATED IMMEDIATELY, PULMONARY EDEMA CAN BE LIFE THREATENING. SINCE THIS
PRODUCT IS IN GRANULAR/TABLET FORM, PARTICLES OF RESPIRABLE SIZE ARE NOT
GENERALLY ENCOUNTERED. EYE:CORROSIVE TO EYES. CONTACT, EVEN A MINUTE AMOUNT
FOR A SHORT DURATION, CAN CAUSE SEVERE IRRITATION & EVEN BLINDNESS. SKIN:
MAY CAUSE SEVERE IRRITATION, BURNS OR TIS SUE DESTRUCTION. (TOXICOLOGICAL
INFO)
Medical Cond Aggravated By Exposure: NONE KNOWN.
First Aid: INHALATION: MOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. IF BREATHING DIFFICULT,
GIVE OXYGEN. CALL A PHYSICIAN. EYE/SKIN: IMMEDIATELY FLUSH EYES & SKIN
W/PLENTY OF WATER (SOAP & WATER FOR SKIN) FOR AT LEAST 15 MINUTES, WHILE
REMOVING CONTAMINATED CLOTHING & SHOES. FOR EYE CONTACT, GET IMMED
MEDICAL ATTENTION. IF SKIN IRRITATION OCCURS, GET ME DICAL ATTENTION.
INGESTION: IF SWALLOWED, GIVE AT LEAST 3-4 GLASSES OF WATER, BUT DO NOT
INDUCE VOMITING. DO NOT GIVE ANYTHING BY MOUTH TO AN UNCONCIOUS OR CONVULSING
PERSON. GET MEDICAL ATTENTION. NO TE TO PHYSICIAN: TREAT SYMPTOMATICALLY.
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Handling and Disposal
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Spill Release Procedures: USE EXTREME CAUTION IN HANDLING SPILLED MATERIAL.
CONTAMINATION WITH ORGANIC/COMBUSTIBLE MATL MAY CAUSE FIRE/VIOLENT
DECOMPOSITION. IF FIRE/DECOMPOSITION OCCURS IN AREA OF SPILL, IMMED DOUSE
W/PLENTY OF WATER. OTHERWISE, SWEEP UP ALL VISIBLE MATL USING CLEAN, DRY
SHOVEL & BROOM & DISSOLVE MATL IN WATER. SPILLED MATL THAT HAS BEEN
SWEPT UP & DISSOLVED IN WATER SHOULD BE USED IMMED IN (OTHER INFO)
Neutralizing Agent: ONE PINT OF 35% HYDROGEN PEROXIDE SOLUTION PER POUND OF
CALCIUM HYPOCHLORITE TO BE NEUTRALIZED.
Waste Disposal Methods: DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE FEDERAL,
STATE AND LOCAL REGULATIONS (FP N). SPILLED MATERIAL THAT HAS BEEN SWEPT UP
AND DISSOLVED IN WATER SHOULD BE USED IMMEDIATELY IN THE NORMAL APPLIC ATION
FOR WHICH THIS PRODUCT IS BEING USED. IF THIS IS NOT POSSIBLE, CAREFULLY
NEUTRALIZE DISSOLVED MATERIAL BY ADDING HYDROGEN PEROXIDE (SARA INFO)
Handling And Storage Precautions: STORE IN COOL, DRY, WELL-VENTILATED PLACE.
KEEP IN ORIGINAL CONTAINER. KEEP CONTAINER CLOSED WHEN NOT IN USE. KEEP AWAY
FROM HEAT, SPARKS, FLAMES, DIRECT SUNLIGHT, & OTHER SOURCES OF HEAT,
INCLUDING L IGHTED TOBACCO PRODUCTS. USE ONLY A CLEAN, DRY SCOOP MADE OF
METAL OR PLASTIC EACH TIME (OTHER PREC)
Other Precautions: HAND/STOR (CONT'D): PRODUCT IS TAKEN FROM CONTAINER. DO NOT
ADD PROD TO ANY DISPENSING DEVICE CONTAINING REMNANTS OF ANY OTHER PRODUCT.
SUCH USE MAY CAUSE VIOLENT REACTION LEADING TO FIRE/EXPLOSION. A DD PRODUCT
ONLY TO WATER. MAY CAUSE FIRE/EXPLOS IF MIXED W/OTHER CHEMICALS. FIRE MAY
RESULT IF CONTA MINATED (STATE REGS)
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Extinguishing Media: WATER ONLY. SMOTHERING INEFFECTIVE - PRODUCT SUPPLIES OWN
OXYGEN.
Fire Fighting Procedures: FIREFIGHTERS MUST WEAR NIOSH APPROVED, PRESSURE
DEMAND, SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE FOR POSSIBLE
EXPOSURE TO HAZARDOUS GAS. PRODUCT DECOMPOSES AT 180C RELEASING OXYGEN GAS.
CONTAINER MAY RUPTURE.
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Control Measures
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Respiratory Protection: IF DUSTY CONDITIONS ARE ENCOUNTERED, USE NIOSH APPROVED
RESPIRATOR WITH ACID GAS CARTRIDGE AND DUST PREFILTER. THE RESPIRATORY USE
LIMITATIONS MADE BY NIOSH OR THE MANUFACTURER MUST BE OBSERVED. RESPI RATORY
PROTECTION PROGRAMS MUST BE IN ACCORDANCE WITH 29 CFR 1910.134.
Ventilation: NONE REQUIRED UNLESS DUSTY CONDITIONS ARE ENCOUNTERED.
Protective Gloves: NATURAL OR SYNTHETIC RUBBER.
Eye Protection: ANSI APPROVED CHEMICAL WORKER GOGGLES (FP N).
Other Protective Equipment: EYEWASH STATION AND DELUGE SHOWER MEETING ANSI
DESIGN CRITERIA (FP N). BOOTS, APRONS OR CHEMICAL SUITS SHOULD BE USED WHEN
NECESSARY TO PREVENT SKIN CONTACT. PERSONAL PROTECTIVE CLOTHING & (SUPP
SAFETY)
Work Hygienic Practices: N/P. CARCINOGENICITY (CONT'D): EVIDENCE THAT THIS
CHEMICAL PRODUCED ANY CARCINOGENIC RESPONSE. ALSO, THE EXPOSURE DID NOT
RESULT IN ANY ADVERSE EFFECT IN BLOOD,CLINICAL CHEMISTRY,OR OTHER TARGET
ORGANS.
Supplemental Safety and Health: OTHER PROTECTIVE EQUIPMENT: USE OF EQUIPMENT
MUST BE IN ACCORDANCE WITH 29 CFR 1910.132 (GENERAL REQUIREMENTS), .133 (EYE
AND FACE PROTECTION), AND .138 (HAND PROTECTION). PHYSICAL/CHEMICAL DATA:
BULK DENSITY: NA. HEAT OF SOLUTION: SLIGHTLY EXOTHERMIC. SYNONYMS: CALCIUM
HYPOCHLORITE TABLETS; CAL HYPO TABLETS; CA(OCL)2.
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Physical/Chemical Properties
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B.P. Text: DECOMPOSES AT 180C
PH: ALKALINE
Solubility in Water: 217 G/L @ 27C
Appearance and Odor: WHITE TABLETS. SLIGHT CHLORINE ODOR.
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: STABILITY: UNSTABLE ABOVE 177C. CONDITIONS TO
AVOID: CONTAMINATION. EXCESSIVE HEAT ABOVE 177C.
Materials To Avoid: ACIDS. COMBUSTIBLE MATERIALS. ORGANICS. REDUCING AGENTS.
Hazardous Decomposition Products: ACID OR AMMONIA CONTAMINATION WILL RELEASE
TOXIC GASES. EXCESSIVE HEAT WILL CAUSE DECOMPOSITION RESULTING IN THE RELEASE
OF OXYGEN AND CHLORINE GAS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
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Toxicological Information
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Toxicological Information: ACUTE ORAL LD50: (RAT) 850 MG/KG. SLIGHT TO VERY LOW
TOXICITY. ACUTE INHALATION LC50: (RAT) NO MORTALITY AT 3.5 MG/L (1 HOUR).
IRRITATING. ACUTE DERMAL LD50: (RABBIT) >1000 MG/KG. SLIGHT TO VERY LOW T
OXICITY. SKIN IRRITATION: CAUSES BURNS. EYE IRRITATION: CAUSES BURNS.
SIGNS/SYMPS OF OVEREXPOSURE (CONT'D): IN STUDIES UTILIZING RABBITS, THE SKIN
IRRITATION SCORE WAS 8/8 & THE EYE IRRITATION SCORE W AS 98.5/110.
INGESTION: IF SWALLOWED, CAUSES SEVERE BURNS TO DIGESTIVE TRACT & CAN BE
FATAL. CHRONIC: GENOTOXICITY: PRODUCED POSITIVE RESPONSES IN IN-VITRO ASSAYS
USING BACTERIAL SYSTEMS & CHROMOSOMAL ABERRATIONS IN CHINESE
(ECOLOGICAL)
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Ecological Information
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Ecological: HIGHLY TOXIC TO AQUATIC LIFE. 0.088 MG/L (BLUEGILL) 96-HOUR LC50.
TOXICOLOGICAL (CONT'D): HAMSTER FIBROBLASTS. IN A WHOLE ANIMAL EXPERIMENT
(MOUSE MICRONUCLEUS TEST), EXPOSURES RANGING FROM 20 TO 160 MG/KG PRODUCED
NO COMPOUND RELATED CHROMOSOMAL ABNORMALITIES. ONE OF THE MAJOR USES OF
CALCIUM HYPOCHLORITE IS AS A SOURCE OF CHLORINE FOR WATER SANITATION IN
DRINKING & RECREATIONAL WATER. STUDIES H AVE BEEN CONDUCTED TO DETERMINE
THE LONG-TERM EFFECTS OF CHLORINATED DRINKING WATER. SEVEN GENERATIONS OF
RATS WERE GIVEN 100 PPM CHLORINE IN THEIR DRINKING WATER. NO DIFFERENCE
INFERTILITY, GROWTH, B LOOD PARAMETERS, OR SPECIFIC (TRANSPORT)
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MSDS Transport Information
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Transport Information: PROPER SHIPPING NAME: CALCIUM HYPOCHLORITE, HYDRATED.
HAZARD CLASS: 5.1 (OXIDIZER). IDENTIFICATION NUMBER: UN2880. PACKING GROUP:
II. REPORTABLE QUANTITY: 10 LB/4.5 KG. ECOLOGICAL INFO (CONT'D): ORGA N
TOXICITY WAS OBSERVED BETWEEN CONTROL & EXPOSED ANIMALS. TWO SEPARATE
ANIMAL STUDIES CONDUCTED BY DIFFERENT GOVERNMENT AGENCIES DETERMINED THAT THE
CHLORINATION OF MUNICIPAL DRINKING WATER DID NOT R ESULT IN TOXICITY TO THE
DEVELOPING MOUSE FETUS. SAFE HANDLING OF THIS MATERIAL ON A LONG-TERM BASIS
SHOULD EMPHASIZE MINIMIZING REPEATED ACUTE EXPOSURES.
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Regulatory Information
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Sara Title III Information: SARA (311,312) HAZARD CLASS: ACUTE HEALTH HAZARD.
REACTIVE HAZARD. FIRE HAZARD. SARA (313) CHEMICALS: NOT LISTED. SARA SECTION
302: NOT LISTED AS AN EXTREMELY HAZARDOUS SUBSTANCE. DISPOSAL (CONT'D): ( ONE
PINT OF 35% HYDROGEN PEROXIDE SOLUTION PER POUND OF CALCIUM HYPOCHLORITE TO
BE NEUTRALIZED) THEN DILUTE THE NEUTRALIZED MATERIAL W/PLENTY OF WATER &
FLUSH TO SEWER. NOTE: ONLY PROPERLY NEUTRALIZED MATERIAL SHOULD BE FLUSHED
TO SEWER. UNNEUTRALIZED MATERIAL CAN CAUSE ENVIRONMENTAL DAMAGE TO RECEIVING
WATER OR CAN INTERFERE WITH TREATMENT PLANT OPERATION. FOR ON-SITE
NEUTRALIZATION, CAREFULLY & SLOWLY POUR APPROPRIATE (OTHER INFO)
Federal Regulatory Information: CERCLA HAZARDOUS SUBSTANCE: LISTED IN TABLE
302.4 OF 40 CFR PART 302 AS A HAZARDOUS SUBSTANCE WITH A REPORTABLE QUANTITY
OF 10 POUNDS. RELEASES TO AIR, LAND OR WATER WHICH EXCEED THE RQ MUST BE
REPORT ED TO THE NATIONAL RESPONSE CENTER, 800-424-8802. FIFRA: THIS PRODUCT
IS REGISTERED WITH EPA AS A PESTICIDE. TSCA: PRODUCT IS LISTED ON THE TSCA
INVENTORY. EUROPE EINECS: PRODUCT IS LISTED ON EINECS. CANADA DSL: PRODUCT
IS LISTED ON THE CANADIAN DSL. AUSTRALIA AICS: PRODUCT IS LISTED ON AICS.
KOREA ECL: PRODUCT IS LISTED ON ECL. JAPAN MITI (ENCS): PRODUCT IS LISTED ON
MITI. RCRA: WASTE CALCIUM HYPOCHLORITE & CONTAMINATED (STATE REGS)
State Regulatory Information: N/P. FEDERAL REGS (CONT'D): SOILS/MATERIALS FROM
SPILL CLEANUP ARE D001 HAZARDOUS WASTE AS PER 40 CFR 261.21(A)(4) & MUST
BE DISPOSED OF ACCORDINGLY UNDER RCRA. NSF DRINKING WATER TREATMENT CHEMICALS
LISTING: PPG CALCIUM HYPOCHLORITE IS CERTIFIED FOR MAXIMUM USE AT 46 MG/L
UNDER ANSI/NSF STD 60. OTHER PREC (CONT'D): W/ACIDS OR EASILY COMBUSTIBLE
MATLS SUCH AS OIL, KEROSENE, GASOLINE, PAINT PROD & MOST OTHER ORGANIC
MATLS. DO NOT REUSE CNTNR. RESIDUAL MATL REMAINING IN EMPTY DRUM CAN REACT TO
CAU SE FIRE. THOROUGHLY FLUSH EMPTY CNTNR W/WATER THEN DESTROY BY PLACING IN
TRASH COLLECTION. DO NOT CONTAM WATER, FOOD/ FEED BY STOR/DISPOSAL.
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Other Information
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Other Information: SPILL/RELEASE (CONT'D): NORMAL APPLICATION FOR WHICH THIS
PRODUCT IS BEING CONSUMED. SARA (CONT'D): QUANTITY OF 35% HYDROGEN PEROXIDE
SOLUTION OVER ALL SPILLED MATL &/OR THEIR CONTAINERS TO PREVENT EN
VIRONMENTAL CONTAMINATION. IT IS YOUR DUTY TO DISPOSE OF THE CHEMICAL
MATERIALS AND/OR THEIR CONTAINERS IN ACCORDANCE WITH THE CLEAN AIR ACT, THE
CLEAN WATER ACT, THE RESOURCE CONSERVATION AND RECOVER Y ACT, AS WELL AS ANY
OTHER RELEVANT FEDERAL, STATE, OR LOCAL LAWS/REGULATIONS REGARDING DISPOSAL.
EXPOSURE LIMITS: PPG (IPEL): 1 MG/CU. M. TWA. 2 MG/ CU. M. STEL.
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HAZCOM Label
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MSDS NAME: CALCIUM HYPOCHLORITE TABLETS 65%, 0122
Company: PPG INDUSTRIES INC
Street: ONE PPG PLACE
City: PITTSBURGH PA
Zipcode: 15272
Health Emergency Phone: 304-843-1300
Label Required IND: Y
Date Of Label Review: 05/22/2001
Status Code: A
Origination Code: G
Hazard And Precautions: EMERGENCY OVERVIEW: DANGER! STRONG OXIDIZING AGENT! MIX
ONLY WITH WATER. CONTAMINATION MAY CAUSE FIRE OR EXPLOSION. DO NOT ADD THIS
PRODUCT TO ANY DISPENSING DEVICE CONTAINING REMNANTS OF ANY OTHER PR ODUCT.
PRECAUTIONS: DO NOT SWALLOW. SWALLOWING MAY CAUSE INJURY OR DEATH. DO NOT GET
IN EYES, ON SKIN, OR ON CLOTHING. MAY CAUSE BURNS. AVOID BREATHING DUST.
IRRITATING TO NOSE AND THROAT. WASH HANDS AFTER HANDLING. KEEP OUT OF REACH
OF CHILDREN. ACUTE: INHALATION: INHALATION OF DUST & DISPOSITION OF
PARTICLES IN RESP TRACT CAN LEAD TO IRRITATION OF TISSUE & CAUSE A
VARIETY OF EFFECTS DEPENDING O N CONCENTRATION & INCLUDE: (SIGNS/SYMPS)
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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