HACH COMPANY -- PPB-4 NEUTRALIZER SOLUTION, 23688
=======================================================
Material Safety Data Sheet
=======================================================
MSDS Num: CLPCB
MSDS NAME: PPB-4 NEUTRALIZER SOLUTION, 23688
Responsible Party
Name: HACH COMPANY
Address: 5600 LINDBERGH DRIVE
Box: 389
City: LOVELAND CO 80539-8902
Info Phone: 970-669-3050
Emergency Phone Number: 515-232-2533/303-623-5716
Resp. Party Other MSDS No.: M00618
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Name: HACH CO
Address: 5600 LINDBERGH DR
Box: 389
City: LOVELAND CO 80539
Phone: 970-669-3050/ 303-623-5716
=======================================================
Ingredients
=======================================================
Cas: 1310-73-2
RTECS #: WB4900000
Name: SODIUM HYDROXIDE.
% low Wt: 1.
% high Wt: 10.
OSHA PEL: 2 MG/M3
ACGIH TLV: 2 MG/M3
ACGIH STEL: 2 MG/M3 (C)
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
------------------------------
Cas: 7732-18-5
RTECS #: ZC0110000
Name: DEMINERALIZED WATER.
% low Wt: 70.
% high Wt: 80.
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 77-86-1
RTECS #: TY2900000
Name: TRIS-(HYDROXYMETHYL)-AMINOMETHANE.
% low Wt: 15.
% high Wt: 25.
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
------------------------------
Cas: 87-69-4
RTECS #: WW7875000
Name: TARTARIC ACID.
< Wt: 5.
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: N/P.
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: EMERGENCY OVERVIEW: APPEARANCE: CLEAR, COLORLESS LIQUID.
ODOR: NONE. CAUSES BURNS. HARMFUL IF SWALLOWED. POTENTIAL HEALTH EFFECTS: EYE
CONTACT: CAUSES EYE BURNS. SKIN CONTACT: CAUSES BURNS. SKIN ABSOR PTION: NONE
REPORTED. TARGET ORGANS: NONE REPORTED. INGESTION: CAUSES: BURNS CAN CAUSE:
ABDOMINAL PAIN, COLLAPSE, VOMITING, DEATH, HYPOGLYCEMIA. INHALATION: NO DATA
REPORTED. SODIUM HYDROXIDE: HAZARD: CAUSES SEVERE BURNS. TOXIC.
DEMINERALIZED WATER: HAZARD: NO EFFECTS ANTICIPATED.
TRIS-(HYDROXYMETHYL)-AMINOMETHANE: HAZARD: MAY CAUSE IRRITATION. TARTARIC
ACID: HAZARD: MAY CAUSE IRRITATION. CHRONIC EFFECTS/TARGET ORGANS: NONE
REPORTED.
Explanation Of Carcinogenicity: THIS PRODUCT DOES NOT CONTAIN ANY OSHA, IARC,
NTP LISTED CARCINOGENS/CHEMICALS.
Signs And Symptions Of Overexposure: N/P.
Medical Cond Aggravated By Exposure: PRE-EXISTING: EYE CONDITIONS, SKIN
CONDITIONS.
First Aid: EYE CONTACT: IMMEDIATELY FLUSH EYES WITH WATER FOR 15 MINUTES. CALL
A PHYSICIAN. SKIN CONTACT: WASH SKIN WITH SOAP AND PLENTY OF WATER.
INGESTION: DO NOT INDUCE VOMITING. GIVE 1-2 GLASSES OF WATER. CA LL PHYSICIAN
IMMEDIATELY. INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING. CONTACT A
PHYSICIAN IMMEDIATELY (FP N).
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: ONLY PERSONS PROPERLY QUALIFIED TO RESPOND TO AN
EMERGENCY INVOLVING HAZARDOUS SUBSTANCES MAY RESPOND TO A SPILL ACCORDING TO
FEDERAL REGULATIONS (OSHA 29 CFR 1910.120(A)(V); PER YOUR COMPANY'S EMERGE
NCY RESPONSE PLAN AND GUIDELINES/PROCEDURES. SEE DISPOSAL SECTION FOR
DISPOSAL ASSISTANCE. CONTAINMENT TECHNIQUE: ABSORB SPILLED LIQUID WITH
NON-REACTIVE ABSORBENT MATERIAL. DIKE LARGE (ECOLOGICAL)
Waste Disposal Methods: EPA WASTE ID NUMBER: NONE. SPECIAL INSTRUCTIONS
(DISPOSAL): DILUTE TO 3 TO 5 TIMES VOLUME WITH COLD WATER. ADJUST TO A PH
BETWEEN 6 & 9 WITH AN ACID, SUCH AS SULFURIC OR CITRIC. OPEN COLD WATER
TAP CO MPLETELY, SLOWLY POUR THE REACTED MATERIAL TO THE DRAIN. FLUSH SYSTEM
WITH PLENTY OF WATER. EMPTY CO NTAINERS: RINSE THREE TIMES (OTHER
PRECAUTIONS)
Other Precautions: N/P. WASTE DISPOSAL METHOD (CON'T): WITH AN APPROPRIATE
SOLVENT. DISPOSE OF EMPTY CONTAINER AS NORMAL TRASH. NOTICE (DISPOSAL): THESE
DISPOSAL GUIDELINES ARE BASED ON FEDERAL REGULATIONS & MAY BE SUP ERSEDED
BY MORE STRINGENT STATE OR LOCAL REQUIREMENTS. CONSULT YOUR LOCAL
ENVIRONMENTAL REGULATORS F OR MORE INFORMATION.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Extinguishing Media: USE MEDIA APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures: AS IN ANY FIRE, WEAR NIOSH APPROVED SELF-CONTAINED
BREATHING APPARATUS PRESSURE-DEMAND AND FULL PROTECTIVE GEAR (FP N).
=======================================================
Control Measures
=======================================================
Respiratory Protection: A NIOSH APPROVED RESPIRATOR APPROPRIATE FOR THE
EXPOSURE OF CONCERN (FP N).
Ventilation: ADEQUATE VENTILATION.
Protective Gloves: DISPOSABLE LATEX GLOVES.
Eye Protection: ANSI APPROVED CHEMICAL SAFETY GOGGLES (FP N). SAFETY GLASSES
(SUPP SAFETY)
Other Protective Equipment: EYEWASH AND DELUGE SHOWER MEETING ANSI DESIGN
CRITERIA (FP N). LAB COAT.
Work Hygienic Practices: MAINTAIN GENERAL INDUSTRIAL HYGIENE PRACTICES WHEN
USING PRODUCT. AVOID CONTACT WITH: EYES, SKIN, CLOTHING. DO NOT BREATHE:
MIST/VAPOR. WASH THOROUGHLY AFTER HANDLING. KEEP AWAY FROM: ACIDS/ACID FUME.
Supplemental Safety and Health: EYE PROT (CON'T): WITH TOP AND SIDESHIELDS.
PHYSICAL/CHEMICAL DATA (CON'T): SOLUBILITY: ACID: SOLUBLE. OTHER: N/D. METAL
CORROSIVITY: STEEL: 0.00 IN/YR. ALUMINUM: 12.6 IN/YR. VOLATILE ORGANIC
COMPOU NDS CONTENT: N/A. PARTITION COEFFICIENT (N-OCTANOL/WATER): N/A.
MOLECULAR WT: N/A. INTENDED USE: LEAD TEST REAGENT.
=======================================================
Physical/Chemical Properties
=======================================================
Boiling Point: =99.C, 210.2F
Melt/Freeze Pt: =-3.C, 26.6F
Vapor Pres: NOT DETERMINED
Vapor Density: N/D
Spec Gravity: 1.066 (WATER=1)
PH: 12.3
Evaporation Rate & Reference: 0.891 (WATER=1)
Solubility in Water: SOLUBLE
Appearance and Odor: CLEAR, COLORLESS LIQUID. ODOR: NONE.
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXTREME TEMPERATURES. STABLE WHEN STORED UNDER
PROPER CONDITIONS.
Materials To Avoid: REACTIVITY/INCOMPATIBILITY: INCOMPATIBLE WITH: STRONG
ACIDS.
Hazardous Decomposition Products: TOXIC FUMES OF: NITROGEN OXIDES, SODIUM
OXIDES, CARBON MONOXIDE.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: WILL NOT OCCUR.
=======================================================
Toxicological Information
=======================================================
Toxicological Information: LD50/LC50: NONE REPORTED. DERMAL TOXICITY DATA/ SKIN
AND EYE IRRITATION DATA/ MUTATION DATA: NONE REPORTED. REPRODUCTIVE EFFECTS
DATA: NONE REPORTED. CANCER/REPRODUCTIVE TOXICITY INFO: NONE REPORTED. TOXIC
SYNERGISTIC PRODUCT: NONE REPORTED. INGREDIENT TOXICOLOGICAL DATA: SODIUM
HYDROXIDE: LD50: ORAL, RAT/RABBIT LDLO=500MG/KG. LC50: NONE REPORTED;
TARTARIC ACID: LD50: ORAL DOG LDLO=5G/KG. LC50: NO NE REPORTED;
TRIS(HYDROXYMETHYL) AMINOMETHANE: ORAL RAT LD50=5900 MG/KG. LC50: NONE
REPORTED. DEMINERALIZED WATER: LD50: NONE REPORTED. LC50: NONE REPORTED.
=======================================================
Ecological Information
=======================================================
Ecological: NO ECOLOGICAL DATA AVAILABLE FOR PRODUCT. INGREDIENT ECOLOGICAL
INFORMATION: NO ECOLOGICAL DATA AVAILABLE FOR INGREDIENTS OF PRODUCT.
SPILL/RELEASE (CON'T): SPILLS TO KEEP SPILLED MATERIAL FROM ENTE RING SEWAGE
& DRAINAGE SYSTEMS OR BODIES OF WATER. CLEAN-UP TECHNIQUE: COVER SPILLED
MATERIAL WITH A DRY ACID, SUCH AS CITRIC OR BORIC. SCOOP UP SLURRY INTO A
LARGE BEAKER. ADJUST TO A PH BETWEEN 6 & 9 WITH AN ACID, SUCH AS
SULFURIC OR CITRIC. FLUSH REACTED MATERIAL TO THE DRAIN WITH A LARGE EXCESS
OF WATER. DECONTAMINATE AREA OF SPILL WITH A WEAK ACID SOLUTION. EVACUATION
PROCEDURE: EVACUATE LOCA L AREA (OTHER INFORMATION)
=======================================================
MSDS Transport Information
=======================================================
Transport Information: D.O.T. PROPER SHIPPING NAME: SODIUM HYDROXIDE SOLUTION.
DOT HAZARD CLASS: 8, DOT SUBSIDIARY RISK: NA, DOT ID NUMBER: UN1824, DOT
PACKING GROUP: II. I.C.A.O. PROPER SHIPPING NAME: SODIUM HYDROXIDE SOL
UTION, ICAO HAZARD CLASS: 8, ICAO SUBSIDIARY RISK: NA, ICAO ID NUMBER:
UN1824, ICAO PACKING GROUP: II. I.M.O. PROPER SHIPPING NAME: SODIUM
HYDROXIDE, SOLUTION. I.M.O. HAZARD CLASS: 8, I.M.O. SUBSIDIAR Y RISK: NA,
I.M.O. ID NUMBER: UN1824, I.M.O. PACKING GROUP: II.
=======================================================
Regulatory Information
=======================================================
Federal Regulatory Information: OSHA: THIS PRODUCT MEETS THE CRITERIA FOR A
HAZARDOUS SUBSTANCE AS DEFINED IN THE HAZARD COMMUNICATION STANDARD. (29 CFR
1910.1200). INVENTORY STATUS: ALL INGREDIENTS IN THIS PRODUCT ARE LISTED ON
TS CA 8(B) INVENTORY (40 CFR 710). TSCA CAS NO.: N/A. TRADE SECRET RESGISTRY:
N/A.
State Regulatory Information: CALIFORNIA PROPOSITION 65: NO PROPOSITION. 65
LISTED CHEMICALS ARE PRESENT IN THE PRODUCT. IDENTIFICATION OF PROPOSITION 65
INGREDIENTS: NONE.
=======================================================
Other Information
=======================================================
=======================================================
HAZCOM Label
=======================================================
MSDS NAME: PPB-4 NEUTRALIZER SOLUTION, 23688
Company: HACH CO
Street: 5600 LINDBERGH DR
PO Box: 389
City: LOVELAND CO
Zipcode: 80539
Health Emergency Phone: 515-232-2533/303-623-5716
Label Required IND: Y
Date Of Label Review: 10/24/2001
Status Code: A
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: DANGER
Respiratory Protection IND: NO
Health Hazard: Severe
Contact Hazard: Severe
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: EMERGENCY OVERVIEW: CAUSES BURNS. HARMFUL IF SWALLOWED.
ACUTE: EYE CONTACT: CAUSES EYE BURNS. SKIN CONTACT: CAUSES BURNS. SKIN
ABSORPTION: NONE REPORTED. TARGET ORGANS: NONE REPORTED. INGESTION: HARMF UL
IF SWALLOWED. CAUSES BURNS. CAN CAUSE ABDOMINAL PAIN, COLLAPSE, VOMITING,
DEATH, HYPOGLYCEMIA. INHALATION: NO DATA REPORTED. SODIUM HYDROXIDE: HAZARD:
CAUSES SEVERE BURNS. TOXIC. DEMINERALIZED WATE R: HAZARD: NO EFFECTS
ANTICIPATED. TRIS-(HYDROXYMETHYL)-AMINOMETHANE: HAZARD: MAY CAUSE IRRITATION.
TARTARIC ACID: HAZARD: MAY CAUSE IRRITATION. CHRONIC EFFECTS: NONE REPORTED.
MEDICAL CONDITIONS AGGR AVATED: EYE AND SKIN CONDITIONS.
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
*** END OF RECORD *** |
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