HAYNES INTERNATIONAL SUB OF CA -- 2220, HAYNES GTD 222 ALLOY
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Material Safety Data Sheet
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MSDS Num: CLSGQ
MSDS NAME: 2220, HAYNES GTD 222 ALLOY
Responsible Party
Name: HAYNES INTERNATIONAL INC SUB OF CABOT CORP
Address: 1020 W PARK AVE
Box: 9013
City: KOKOMO IN 46902-9013
Info Phone: 317-456-6000
Emergency Phone Number: (800)424-9300
Resp. Party Other MSDS No.: H2071-3
Chemtrec IND/Phone: (800)424-9300
Review Ind: Y
Published: Y
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Contractor Summary
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Name: HAYNES INTERNATIONAL INC SUB OF CABOT CORP
Address: 1020 W PARK AVE
Box: 9013
City: KOKOMO IN 46904-9013
Phone: 318-263-2002;765-456-6614
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Ingredients
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Cas: 7439-89-6
RTECS #: NO4565500
Name: IRON
% Wt: 1MAX
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Cas: 7439-96-5
RTECS #: OO9275000
Name: MANGANESE
% Wt: 0.1MAX
OSHA PEL: C5 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
------------------------------
Cas: 7439-98-7
RTECS #: QA4680000
Name: MOLYBDENUM
% Wt: 1MAX
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 7440-02-0
RTECS #: QR5950000
Name: NICKEL
Percent by Wt: 50.
OSHA PEL: ]
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
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Cas: 7440-21-3
RTECS #: VW0400000
Name: SILICON
% Wt: 0.2MAX
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 7429-90-5
RTECS #: BD0330000
Name: ALUMINIUM
Percent by Wt: 1.2
OSHA PEL: 15 MG/M3
ACGIH TLV: 10 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 7440-42-8
RTECS #: ED7350000
Name: BORON
% Wt: 0.005
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Cas: 7440-03-1
RTECS #: QT9900000
Name: COLUMBIUM, NIOBIUM
Percent by Wt: .8
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Cas: 7440-32-6
RTECS #: XR1700000
Name: TITANIUM
Percent by Wt: 2.3
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Cas: 7440-50-8
RTECS #: GL5325000
Name: COPPER
% Wt: 0.1MAX
OSHA PEL: 1 MG/M3
ACGIH TLV: 1 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 5000 LBS
DOT Rpt Qty: 5000 LBS
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Cas: 7440-25-7
RTECS #: WW5505000
Name: TANTALUM
Percent by Wt: 1.
OSHA PEL: 5 MG/M3
ACGIH TLV: 5 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 7440-33-7
RTECS #: YO7175000
Name: TUNGSTEN
% Wt: 0.1MAX
ACGIH TLV: 5 MG/M3
ACGIH STEL: 10 MG/M3
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Cas: 7440-67-7
RTECS #: ZH7070000
Name: ZIRCONIUM
% Wt: 0.02MAX
ACGIH TLV: 5 MG/M3
ACGIH STEL: 10 MG/M3
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Cas: 7440-48-4
RTECS #: GF8750000
Name: COBALT
Percent by Wt: 19.
OSHA PEL: 0.1 MG/M3
ACGIH TLV: 0.02 MG/M3
ACGIH STEL: NOT ESTABLISHED
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Cas: 7440-47-3
RTECS #: GB4200000
Name: CHROMIUM
Percent by Wt: 22.5
OSHA PEL: 1 MG/M3
ACGIH TLV: 0.5 MG/M3
ACGIH STEL: NOT ESTABLISHED
EPA Rpt Qty: 1 LB
DOT Rpt Qty: 1 LB
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Health Hazards Data
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Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: YES
IARC: YES
OSHA: YES
Effects of Exposure: ACUTE: INHALATION-INHALED PARTICULATE MAY IRRITATE THE
RESPIRATORY TRACT. EXCESSIVE INHALATION OF ALUMINUM, COBALT, COPPER,
MANGANESE, NICKEL & ZINC CAN CAUSE RESPIRATORY IRRITATION, COUGH,
BRONCHITIS , CHILLS, "METAL FUME FEVER" & ASTHMA-LIKE SYMPTOMS. SKIN-SKIN
CONTACT WITH THESE MATERIALS MAY CAUSE IRRITATION & IN SOME INDIVIDUALS
AN ALLERGIC DERMATITIS WHEN ELEMENTS SUCH AS CHROME, COBALT & NIC KEL ARE
PRESENT. EYES-CONTACT WITH PARTICULATE METAL MAY INFLAME THE CONJUNCTIVA.
CHRONIC: RESPIRATORY DISEASE WITH SYMPTOMS RANGING FROM SHORTNESS OF BREATH
& COUGH TO PERMANENT DISABILITY DUE TO LOS S OF LUNG FUNCTION; "SEE OTHER
INFO"
Explanation Of Carcinogenicity: CHROMIUM AND ITS COMPOUNDS, COBALT AND IS
COMPOUNDS, AND NICKEL AND ITS COMPOUNDS ARE CLASSIFIED AS CARCINOGENS BY NTP
AND.OR IARC. WELDING FUMES-OSHA REQUIRES THAT WELDING FUMES BE CONSIDIERED AS
CAR CINOGENS BECAUSE THEY ARE CLASSIFIED BY IARC.
Signs And Symptions Of Overexposure: INGESTION OF LARGE DOSES MAY CAUSE NAUSEA,
VOMITING, AND DIARRHEA.
Medical Cond Aggravated By Exposure: INDIVIDUALS WHO MAY HAVE HAD A ALLERGIC
REACTION OR SENSITIVITY TO METAL MAY ENCOUNTER SKIN RASH OR DERMATITIS.
PERSONS WITH IMPAIRED PULMONARY FUNCTION MAY INCUR FUTHER DISABILITY.
First Aid: INHALATION-REMOVE TO FRESH AIR. IF BREATHING HAS STOPPED, PERFORM
ARTIFICIAL RESPIRATION & OBTAIN MEDICAL AID AT ONCE. INGESTION-NEVER GIVE
ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CONTACT A POISON CONTROL CENTER
(PCC). UNLESS THE PCC ADVISES ORTHERWISE, HAVE CONSCIOUS PERSON DRINK 1-2
GLASSES OF WATER TO DILUTE. DO NOT INDUCE VOMITING UNLESS LARGE AMOUNTS ARE
INGESTED. OBTAIN MEDICAL AID AT ON CE. SKIN-TREAT CUTS & ABRAISIONS WITH
STANDARD FIRST AID. IF IRRITATION OCCURS, OBTAIN MEDICAL AID. EYES-FLUSH
DUST/POWDER FROM EYES WITH CLEAN WATER FOR 15 MINS. IF IRRITATION PERSISTS,
OBTAIN MEDICA L AID.
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Handling and Disposal
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Spill Release Procedures: IN SOLID FORM THIS MATERIAL POSES NO SPECIAL CLEAN-UP
PROBLEMS. IF THIS MATERIAL IS IN POWDER OR DUST FORM, DO NOT DRY SWEEP,
NOTIFY SAFETY PERSONNEL, CLEAN-UP SHOULD BE CONDUCTED WITH A VACUUM SYSTEM
UTILIZING A HIGH EFFICIENCY PARTICULATE AIR (HEPA) FILTRATION SYSTEM.CAUTION
SHOULD BE TAKEN TO MINIMIZE AIRBORNE GENERATION OF POWDER OR DUST AND AVOID
CONTAMINATION OF AIR AND WATER.
Waste Disposal Methods: WHENEVER POSSIBLE, RECOVER ALLOYS FOR REUSE OR
RECYCLING. IF NECESSARY, DISPOSE OF WASTE MATERIAL IN ACCORDANCE WITH LOCAL
STATE OR FEDERAL REGULATIONS. FOR SPECIFIC LABELING, PACKING, STORAGE, TRANSP
ORTATION AND DISPOSAL PRECEDURES, CONTACT AN ENVIRONMENTAL ENGINEER OR
CONSULTANT FAMILIAR WITH WAST E DISPOSAL REGULATIONS.
Handling And Storage Precautions: HANDLING-THIS PRODUCT MUST BE HANDLED
ACCORDING TO THE SIZE, SHAPE AND QUANTITY OF MATERIAL INVOLVED. POWDERS
SHOULD BE MOVE OR TRANSPORTED TO MINIMIZE SPILL OR RELEASE POTENTIAL. AVOID
DUST INHALATIO N AND EYE OR SKIN CONTACT.
Other Precautions: STORAGE-IN SOLID FORM THIS MATERIAL POSES NO SPECIAL
PROBLEMS. STORE METAL POWDER IN A DRY AREA AWAY FROM HEAT, IGNITION SOURCES
AND INCOMPATIBLES. **SPILL-CLEANUP PERSONNEL SHOULD PROTECT AGAINST DUS T
INHALATION & SKIN OR EYE CONTACT. USE NON-SPARKING TOOLS. PROPERLY LABEL
ALL MATERIALS COLLECTED I N WASTE CONTAINER.
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Fire and Explosion Hazard Information
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Flash Point Text: NONE
Lower Limits: NONE
Upper Limits: NONE
Extinguishing Media: THESE ALLOYS IN SOLID WROUGHT FORM ARE NONCOMBUSTIBLE. USE
EXTINGUISHING MEDIA APPROPRIATE TO THE SURROUNGING FIRE.
Fire Fighting Procedures: TO EXTINGUISH A METAL POWDER FIRE USE DRY SAND, DRY
GRAPHITE OR OTHER CLASS "D" EXTINGUISHING POWDER.
Unusual Fire/Explosion Hazard: NO UNUSUAL FIRE OR EXPLOSION HAZARDS.
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Control Measures
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Respiratory Protection: USE NIOSH APPROVED RESPIRATORS AS SPECIFIED BY AN
INDUSTRIAL HYGIENIST OR QUALIFIED SAFETY PROFESSIONAL. LUNG FUNCTIONS TESTS
ARE RECOMMENDED FOR USERS OF NEGATIVE PRESSURE DEVICES. USE A FUME RESPIRA
TOR OR AN AIR SUPPLIED RESPIRATOR WHERE LOCAL EXHAUST OR VENTILATION DOES NOT
KEEP EXPOSURE BELOW THE OSHA LIMITS FOR AIR CONTAMINATION.
Ventilation: LOCAL EXHAUST VENTILATION SHOULD BE USED TO CONTROL EXPOSURE TO
AIRBORNE DUST AND FUME EMISSIONS NEAR THE SOURCE BELOW THE EXPOSURE LIMITS
CITED.
Protective Gloves: WEAR GLOVES TO PREVENT METAL CUTS & SKIN ABRASIONS.
Eye Protection: SAFETY GLASSES. (CONTACT LENSES SHOULD NOT BE WORN).
Other Protective Equipment: PROTECTIVE CLOTHING SUCH AS UNIFORMS, DISPOSABLE
COVERALLS, SAFETY SHOES, ETC.
Work Hygienic Practices: PRACTICE GOOD PERSONAL HYGIENE AFTER HANDLING DUST OR
POWDER FORMS OF THIS MATERIAL, ESPECIALLY BEFORE EATING, DRINKING, SMOKING OR
APPLYING COSMETICS.
Supplemental Safety and Health: IF PRIOR DAMAGE OR DISEASE TO THE NEUROLOGIC
(NERVOUS), CIRCULATORY, HEMATOLOGIC (BLOOD) OR RENAL (KIDNEY) SYSTEMS HAS
OCCURRED, PROPER SCREENING OR EXAMINATIONS SHOULD BE CONDUCTED ON INDIVIDUALS
WHO MAY BE EXPOSED TO FURTHER RISK IF HANDLING AND USE OF THESE MATERIAL
CAUSE EXCESSIVE EXPOSURE.
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Physical/Chemical Properties
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HCC: N1
Melt/Freeze Pt: =-1367.6C, ######F
Vapor Pres: NA
Vapor Density: NA
Spec Gravity: 0.298
PH: NA
Viscosity: NA
Evaporation Rate & Reference: NA
Solubility in Water: NONE
Appearance and Odor: SOLID-SILVER GRAY COLOR OR NO COLOR
Percent Volatiles by Volume: NONE
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: THESE ALLOYS ARE STABLE MATERIALS.
Materials To Avoid: AVOID CONTACT WITH MINERAL ACIDS AN OXIDIZING AGENTS WHICH
MAY GENERATE HYDROGEN GAS; THE EVOLUTION OF HYDROGEN MAY BE AN EXPLOSION
HAZARD.
Hazardous Decomposition Products: VARIOUS ELEMENTAL METALS & METAL OXIDES MAY
BE GENERATED FROM WELDING, CUTTING, GRINDING, MELTING OR DROSS HANDLING
OPERATIONS.
Hazardous Polymerization Indicator: NO
Conditions To Avoid Polymerization: DOES NOT OCCUR.
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Toxicological Information
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Toxicological Information: TOXICITY DATA: LD50 RAT (COBALT): 6171 MG/KG.
TERATOLOGY: RAT (NICKEL) ORAL: TDLO: 158 MG/KG. RAT (MOLYBDENUM) ORAL: 5800
MG/KG GIVEN TO FEMAL 30 WEEKS PRIOR TO MATING AND DURING DAYS 1-20 OF
PREGNACY CAUSED SPECIFIC MUSCULOSKELETAL SYSTEM DEVELOPMENT ABNORMALITIES.
REPRODUCTION: RAT (MOLYBDENUM) ORAL 6050 MG/KG. GIVEN TO FEMAL 35 WEEKS PRIOR
TO MATING PRODUCED PRE-, AND POST-IMPLANTATION MORTALI TY. RAT (COBALT)
UNSPECIFIED EXPOSURE ROUTE, O.05 MG/KG CONTINUOUS, ADMINISTERED THROUGHOUT
GASTATION TO FEMALE WAS EMBRYOTOXIC. MUTAGENICITY: HAMSTER (CHROMIUM III)
LUNG CELL: 34 MG/L CAUSED SISTER CHROMATID EXCHANGE.
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Ecological Information
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Ecological: ECOTOXICITY: FEW PLANTS ACCUMULATE COBALT AT GREATER THAN 100 PPM,
THE LEVEL AT WHICH SEVERE PHYTOXICITY WOULD OCCUR. THERE IS LITTLE TENDENCY
FOR CHROMIUM III BIOACCUMULATION ALONG THE FOOD CHAIN. MO LYBDENUM: FATHEAD
MINNOW), LC50: 370 MG/L/96 HOURS. TERRESTRIAL PLANTS CAN CONTAIN ENOUGH
MOLYBDENUM TO BE TOXIC TO ANIMALS BUT STILL GROW NORMALLY. ENVIONMENTAL
DEGRADATION: IN WATER, COBALT IS ADSO RBED GREATLY TO HYDROLYSATE OR OXIDATE
SEDIMENTS. IT MAY BE TAKEN INTO SOLUTION IN SMALL AMOUNTS THROUGH
BACTERIOLOGICAL ACTIVITY.
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MSDS Transport Information
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Regulatory Information
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Sara Title III Information: CHEMICALS SUBJECT TO THE REPORTING REQUIREMENTS OF
SECTION 313 OR TITLE II OF SARA AND 40 CFR PART 372: ALUMINUM (AS A FUME OR
DUST), CHROMIUM, COBALT, COPPER, MANGANESE, NICKEL (AS A POWDER OR DUST),
VANADIUM (AS A FUME OR DUST). SARA HAZARD CATERGORY: IMMEDIATE HAZARD AND
DELAYED HAZARD.
Federal Regulatory Information: OSHA: LISTED AS AN AIR CONTAMINANT (29 CFR
1910.1000). HAZAEDOUS BY DEFINITION OF HAZARD COMMUNICATION STANDARD (29 CFR
1910.1200). TSCA (TOXIC SUBSTANCE CONTROL ACT): COMPONENTS OF THIS MATERIAL
ARE LISTED ON THE TSCA INVENTORY.
CERCLA: HAZARDOUS SUBSTANCE (40 CFR 302.4): CHROMIUM (AS A POWDER): NICKEL (AS
A POWDER OR DUST). EXTREMELY HAZARDOUS SUBSTANCE (40 CFR 355): NOT LISTED.
State Regulatory Information: CALIFORNIA'S "SAFE DRINKING WATER & TOXIC
ENFORCEMENT ACT OF 1986" (PROPOSITION 65): DURING WELDING, THERMAL CUTTING
AND MELTING THESE PRODUCTS MAY PRODUCE COBALT OXIDE, NICKEL COMPOUNDS, AND
HEXAVALE NT CHROMIUM COMPOUNDS WHICH ARE KNOWN TO THE STATE OF CALIFORNIA TO
CAUSE CANCER. PENNSYLVANIA WORKER AND COMMUNITY RIGHT TO KNOW: ALUMINUM,
CHROMIUM AND VANADIUM (FUME OR DUST) ARE DESIGNATED ENVIRO NMENTAL HAZARDS ON
THE HAZARDOUS SUBSTANCE LIST. TITLE 34, PART XIII, CHAPTER 323.
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Other Information
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Other Information: HEALTH HAZARD: CENTRAL NERVOUS SYSTEM DEPRESSION HAS BEEN
IDENTIFIED WITH EXCESSIVE MANGANESE EXPOSURE. INSOLUBLE NICKEL COMPOUNDS
& HEXAVALENT CHROMIUM COMPOUNDS HAVE BEEN LINKED TO NASAL, BRONCHIAL
& LUNG CANCER. ALUMINUM AND IRON HAVE BEEN INDICATED TO CAUSE
GASTRO-INTESTINAL DISORDERS AND NON-SIGNIFICANT CHANGES IN THE LUNG. CHRONIC
HEALTH EFFECTS SPECIFIC TO AN ELEMENT(S) MAY BE DIFFICULT TO DETECT DUE TO
THE NUMEROUS ELEMENTAL CONSITIUENTS IN THESE ALLOYS.
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Transportation Information
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Trans ID NO: 160232
MSDS NAME: 2220, HAYNES GTD 222 ALLOY
MSDS Prepared Date: 07/31/1999
Review Date: 12/12/2001
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CY
Type Of Container: CYLINDER
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Detail DOT Information
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DOT PSN Code: ZZZ
DOT Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail IMO Information
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IMO PSN Code: ZZZ
IMO Proper Shipping Name: NOT REGULATED FOR THIS MODE OF TRANSPORTATION
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Detail IATA Information
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IATA PSN Code: ZZZ
IATA Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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Detail AFI Information
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AFI PSN Code: ZZZ
AFI Proper Shipping Name: NOT REGULATED BY THIS MODE OF TRANSPORTATION
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HAZCOM Label
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MSDS NAME: 2220, HAYNES GTD 222 ALLOY
Company: HAYNES INTERNATIONAL INC SUB OF CABOT CORP
Street: 1020 W PARK AVE
PO Box: 9013
City: KOKOMO IN
Zipcode: 46904-9013
Health Emergency Phone: (800)424-9300
Label Required IND: Y
Date Of Label Review: 12/12/2001
Status Code: A
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: NONE
Respiratory Protection IND: YES
Health Hazard: None
Contact Hazard: None
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: ACUTE: INHALATION-INHALED PARTICULATE MAY IRRITATE THE
RESPIRATORY TRACT. EXCESSIVE INHALATION OF ALUMINUM, COBALT, COPPER,
MANGANESE, NICKEL & ZINC CAN CAUSE RESPIRATORY IRRITATION, COUGH,
BRONCHITIS , CHILLS, "METAL FUME FEVER" & ASTHMA-LIKE SYMPTOMS. SKIN-SKIN
CONTACT WITH THESE MATERIALS MAY CAUSE IRRITATION & IN SOME INDIVIDUALS
AN ALLERGIC DERMATITIS WHEN ELEMENTS SUCH AS CHROME, COBALT & NIC KEL ARE
PRESENT. EYES-CONTACT WITH PARTICULATE METAL MAY INFLAME THE CONJUNCTIVA.
CHRONIC: RESPIRATORY DISEASE WITH SYMPTOMS RANGING FROM SHORTNESS OF BREATH
& COUGH TO PERMANENT DISABILITY DUE TO LOS S OF LUNG FUNCTION; "SEE OTHER
INFO"
=======================================================
Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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