LOS ANGELES CHEMICAL CO -- SULFAMIC ACID
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Material Safety Data Sheet
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NIIN: 00-146-1586
MSDS Num: BKQYM
MSDS NAME: SULFAMIC ACID
Responsible Party
Name: LOS ANGELES CHEMICAL CO
Address: 4545 ARDINE STREET
Box: 1987
City: SOUTH GATE CA 90280-2534
Info Phone: 213-583-4761 / FAX 213-773-0909
Emergency Phone Number: 213-583-4761/562-9500
Resp. Party Other MSDS No.: LACCO/72
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Item Description Information
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Item Manager: S9G
Item Name: SULFAMIC ACID,TECHNICAL
Specification Number: O-C-265
Unit of Issue: DR
Quantitative Expression: 00000000100LB
UI Container Qty: 0
Type of Container: SEE ADDN INFO
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Ingredients
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Cas: 5329-14-6
RTECS #: WO5950000
Name: SULFAMIC ACID
Percent by Wt: 100.
Other REC Limits: NONE RECOMMENDED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
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Health Hazards Data
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LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER.
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: TARGET ORGANS: N/P. IT IS IRRITATING TO THE SKIN, EYES,
AND MUCOUS MEMBRANES. CONCENTRATED ACID SOLUTIONS AND MISTS MAY PRODUCE
CORROSIVE EFFECTS SIMILAR TO THOSE OF MINERAL ACIDS. THE ACTION OF SULF AMIC
ACID ON THE SKIN APPEARS TO BE LIMITED TO THE EFFECTS OF LOW PH.
Explanation Of Carcinogenicity: PER MSDS:THIS PRODUCT NOT CONSIDERED CARCINOGEN
BY NTP/IARC/NTP.
Signs And Symptions Of Overexposure: IT IS IRRITATING TO THE SKIN, EYES, AND
MUCOUS MEMBRANES. CONCENTRATED ACID SOLUTIONS AND MISTS MAY PRODUCE CORROSIVE
EFFECTS SIMILAR TO THOSE OF MINERAL ACIDS. THE ACTION OF SULFAMIC ACID ON THE
SKIN APPEARS TO BE LIMITED TO THE EFFECTS OFLOW PH.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE CONTACT: IMMEDIATELY FLUSH EYES WITH RUNNING WATER, INCLUDING
UNDER THE EYELIDS, FOR 15 MINUTES. GET MEDICAL HELP. SKIN CONTACT: REMOVE
CONTAMINATED CLOTHING; FLUSH AFFECTED SKIN AREA WITH RUNNING WATER FOR 15
MINUTES. GET MEDICAL HELPIF EXPOSED AREA IS LARGE OR IF IRRITATION PERSISTS.
INHALATION: REMOVE VICTIM TO FRESH AIR. RESTORE AND/OR SUPPORT HIS BREATHING.
GET MEDICAL HELP. INGESTION: GE T MEDICAL HELP. IF MEDICAL HELP IS NOT
READILY AVAILABLE AND THE VICTIM IS CONSCIOUS AND ALERT, RINSE HIS MOUTH WITH
WATER,THEN GIVE HIM 2-3 GLASSES OF WATER OR MILK TO DILUTE THE MATERIAL.
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Handling and Disposal
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Spill Release Procedures: NOTIFY SAFTY PERSONNEL OF SULFAMIC ACID LEAK OR
SPILL. REMOVE SOURCES OR HIGH TEMPERATURE. PROVIDE ADEQUATE VENTILATION.
CLEANUP PERSONNEL NEED PROTECTION AGAINST DUST INHALATION AND EYE OR SKIN
CONTA CT. COLLECT SPILLED SOLID FOR DISPOSAL OR RECOVERY BY DAMP SWEEPING IT
UP AND SCOOPING IT INTO CONTAINERS CAREFULLY WHILE AVOIDING GENERATION OF
DUST. FLUSH TRACE RESIDUES WITH WATER.
Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. (: SODIUM BICARBONATE,
SODIUM CARBONATE)
Waste Disposal Methods: SCRAP MATERIAL CAN BE CAUTIOUSLY MIXED WITH COLD WATER
AND AGITATED TO NEUTRALIZE IT. AFTER NEUTRALIZATION SMALL AMOUNTS OF WASTE
CAN BE DISCHARGED WITH A LARGE EXCESS OF WATER. FOLLOW FEDERAL, STATE, AND
LOCAL REGULATIONS. NOTE: LARGE AMOUNTS OF SCRAP OR IMPURITIES IN THE SCRAP
MAY REQUIRE SPECIAL DISPOAL PROCEDURES.
Handling And Storage Precautions: STORE SULFAMIC ACID IN CLOSED CONTAINERS IN A
COOL, DRY, WELL-VENTILATED AREA AWAY FROM SOURCES OF HIGH TEMPERATURES.
PREVENT ABSORPTION OF MOISTURE AND POSSIBLE CAKING. PROTECT CONTAINERS FROM
PHYSIC AL DAMAGE.
Other Precautions: AVOID INHALING SULFAMIC ACID DUST OR MIST. AVOID CONTACT
WITH SKIN AND EYES. DO NOT INGEST THIS MATERIAL. USE GOOD HYGIENIC PRACTICES
TO KEEP EXPOSURE AT THE LOWEST LEVELS. WASH ALL EXPOSED SKIN SURFA CES PRIOR
TO EATING, DRINKING OR SMOKINGAFTER HANDLING MATERIAL.
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Fire and Explosion Hazard Information
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Extinguishing Media: USE MEDIA APPROPRIATE TO THE SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures: FIRE FIGHTERS MUST USE SELF-CONTAINED BREATHING
APPARATUS AND WEAR FULLY PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard: THIS MATERIAL CAN EMIT FUMES OF SULFUR DIOXIDE
(SO2), SULFUR TRIOXIDE (SO3), NITROGEN OXIDES (NOX), AND AMMONIA GAS (NH3)
WHEN IT IS INVOLVED IN A FIRE. WATER SOLUTIONS OF SULFAMIC ACID ARE STRONGLY
A CIDIC.
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Control Measures
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Respiratory Protection: AN APPROVED DUST MASK OR RESPIRATOR SHOULD BE AVAILABLE
FOR NONROUTINE OR EMERGENCY USE WHERE DUSTY CONDITIONS OCCUR.
Ventilation: PROVIDE ADEQUATE EXHAUST VENTILATION SUITABLE TO KEEP AIRBORNE
PARTICULATE @MINIMUM IN WORKPLACE.
Protective Gloves: ACID-RESISTANT GLOVES
Eye Protection: CHEMICAL SAFETY GOGGLES AND/OR FULL FACESHIELD WHERE SPLASHING
IS POSSIBLE
Other Protective Equipment: WEAR PROTECTIVE CLOTH APPROPRIATE FOR WORK
SITUATION TO MIN CONTACT OF SULFAMIC ACID ON SKIN.EYEWASH STATIONS,SAF
SHOWERS
Work Hygienic Practices: CONTACT LENSES POSE SPECIAL HAZARD; SOFT LENSES MAY
ABSORB IRRITANTS, AND ALL LENSES CONCENTRATE THEM.
Supplemental Safety and Health: NONE
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Physical/Chemical Properties
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HCC: C1
B.P. Text: DECOMPOSES
Melt/Freeze Pt: =200.C, 392.F
M.P/F.P Text: 392-399F
Decomp Temp: =205.C, 401.F
Spec Gravity: 2.1
PH: 1.18 (1% SOLN)
Evaporation Rate & Reference: NOT FOUND
Solubility in Water: G/100G H20:0C-14.7-70C-42
Appearance and Odor: WHITE CRYSTALLINE SOLID,ORTHOROMBIC
CRYSTALS,ODORLESS,NON-VOLATIL/HYGROSCOPIC
Percent Volatiles by Volume: NIL
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Reactivity Data
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Stability Indicator: YES
Stability Condition To Avoid: WATER SOLUTIONS SLOWLY HYDROLYZES AT ROOM
TEMPERATURE TO FORM SULFATE AND BISULFATE. HYDROLYSIS IS RAPID AT ELEVATED
TEMPERATURES.
Materials To Avoid: HYPOCHLOROUS ACID, HYPOCHLORITES, CYANIDES, SULFIDES,
CARBONATES, METAL OXIDES, HYDROXIDES, ACTIVE METALS. CHLORINE, BROMINE,
POTASSIUM CHLORATE OR NITROUS ACID WILL OXIDIZE SULFAMIC ACID TO SULFURIC
ACID AND NITROGEN.
Hazardous Decomposition Products: THERMAL DECOMPOSITION @408.2F (209C).
PRODUCTS OF THERMAL OXIDATIVE DEGRADATION MAY INCLUDE SULFUR OXIDES, NITROGEN
OXIDES, AND AMMONIA GAS
Hazardous Polymerization Indicator: NO
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Toxicological Information
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Toxicological Information: HUMAN ORAL LDL0: 500 MG/KG; RAT, ORAL, LDL0: 1600
MG/KG
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Ecological Information
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MSDS Transport Information
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Regulatory Information
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Other Information
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Transportation Information
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Trans ID NO: 50833
MSDS NAME: SULFAMIC ACID
MSDS Prepared Date: 01/01/1997
Review Date: 09/22/1999
Net Unit Weight: 100 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: DR
Container QTY: 0
Type Of Container: SEE ADDN INFO
Additional Data: CARGO AIRCRAFT ONLY. PER MSDS:DOT CLASS:SULFAMIC ACID, 8,
UN2967, PKG III. PER CTDF:UN CERTIFIED 1G FIBER DRUM;DRUM SHALL HAVE MIN
3MIL POLYBAG LINER;BAG SHALL BE HEAT SEALED OR TIED W/PLASTIC COATED
WIRE;MARK IAW ALL UN REQMTS.
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Detail DOT Information
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DOT PSN Code: NSE
DOT Proper Shipping Name: SULFAMIC ACID
Hazard Class: 8
UN ID Num: UN2967
DOT Packaging Group: III
Label: CORROSIVE
Packaging Exception: 154
Non Bulk Pack: 213
Bulk Pack: 240
Max Qty Pass: 25 KG
Max Qty Cargo: 100 KG
Vessel Stow Req: A
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Detail IMO Information
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IMO PSN Code: ODS
IMO Proper Shipping Name: SULPHAMIC ACID
IMDG Page Number: 8229
UN Number: 2967
UN Hazard Class: 8
IMO Packaging Group: III
Subsidiary Risk Label: -
EMS Number: 8-08
MED First Aid Guide NUM: 700
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Detail IATA Information
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IATA PSN Code: XHJ
IATA UN ID Num: 2967
IATA Proper Shipping Name: SULPHAMIC ACID
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: III
Packing Note Passenger: 822
Max Quant Pass: 25KG
Max Quant Cargo: 100KG
Packaging Note Cargo: 823
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Detail AFI Information
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AFI PSN Code: XHJ
AFI Proper Shipping Name: SULPHAMIC ACID
AFI Hazard Class: 8
AFI UN ID NUM: UN2967
AFI Packing Group: III
Special Provisions: P5
Back Pack Reference: A12.4
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HAZCOM Label
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MSDS NAME: SULFAMIC ACID
Company: LOS ANGELES CHEMICAL CO
Street: 4545 ARDINE ST
PO Box: 1987
City: SOUTH GATE CA
Zipcode: 90280
Health Emergency Phone: 213-583-4761/562-9500
Label Required IND: Y
Date Of Label Review: 09/22/1999
Status Code: C
MFG Label NO: UNKNOWN
Year Procured: 1999
Origination Code: F
Chronic Hazard IND: Y
Eye Protection IND: NO
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: NO
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: TARGET ORGANS: N/P. IT IS IRRITATING TO SKIN, EYES,
AND MUCOUS MEMBRANES. FIRST AID: EYE CONTACT: IMMEDIATELY FLUSH EYES WITH
RUNNING WATER, INCLUDING UNDER EYELIDS, FOR 15 MINUTES. GET MEDICAL HELP.
SKIN CONTACT: FLUSH AFFECTED SKIN AREAWITH RUNNING WATER FOR 15 MINUTES. GET
MEDICAL HELP IF EXPOSED AREA IS LARGE OR IF IRRITATION PERSISTS. INHALATION:
REMOVE VICTIM TO FRESH AIR. RESTORE AND/OR SU PPORT HIS BREATHING. GET
MEDICAL HELP. INGESTION: GET MEDICAL HELP. IF MEDICALHELP IS NOT READILY
AVAILABLE AND THE VICTIM IS CONSCIOUS AND ALERT, RINSE HIS MOUTH WITH
WATER,THEN GIVE HIM 2-3 GLASSES OF WATER OR MILK TO DILUTE THE MATERIAL.
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Disclaimer (provided with this information by the compiling agencies): This
information is formulated for use by elements of the Department of Defense.
The United States of America in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the Department of Defense
nor any person or persons contracting with any instrumentality of the United
States of America and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
United States of America should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding Department
of Defense or other government situation.
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