===================== Product Identification =====================
MSDS NAME:MURIATIC ACID 20/22 BAUME
NIIN:00F007236
MSDS Number: BBXMX
=== Responsible Party ===
Company:VULCAN CHEMICALS DIV OF VULCAN MATERIALS
Address:NO 1 METROPLEX DR
Box:530390
City:BIRMINGHAM
State:AL
ZIP:35253-0390
Country:US
Info Phone Num:205-877-3000/316-524-5751
Emergency Phone Num:316-524-5751/205-877-3000
CAGE:EO675
=== Contractor Identification ===
Company:VULCAN CHEMICALS
Box:530390
City:BIRMINGHAM
State:AL
ZIP:35253-0390
Country:US
Phone:316-524-5751
CAGE:EO675
Company:VULCAN MATERIALS CO
Address:NO 1 METROPLEX DR
Box:530390
City:BIRMINGHAM
State:AL
ZIP:35253
Country:US
Phone:316-524-5751
CAGE:1B637
============= Composition/Information on Ingredients =============
Name:HYDROCHLORIC ACID, HYDROGEN CHLORIDE, MURIATIC ACID
HYDROCHLORIDE
CAS:7647-01-0
RTECS #:MW4025000
Fraction by Wt: 35%
Other REC Limits:7 PPM
OSHA PEL:5 PPM
ACGIH TLV:C 11 MG/CUM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: IRRITATION TO RESPIRATORY
TRACT, THROAT. 1000-2000 PPM CAN BE FATAL. SKIN: BURNS, IRRITATION,
DERMATITIS. EYES: IRRITATION, SEVERE BURNS. INGESTION: SEVERE BURNS
OF MOUTH, ESOPHAGUS & STOM ACH. DEPENDING UPON AMOUNT SWALLOWED,
HOLES IN THE INTESTINAL TRACT, KIDNEY INFLAMMATION, SHOCK & DEATH
CAN OCCUR.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, BURNING, CHOKING, COUGHING,
HEADACHES, RAPID HEARTBEAT, BREATHING DIFFICULTIES, BURNS,
BLINDNESS, NAUSEA, PAIN, VOMITING.
Medical Cond Aggravated by Exposure:ASTHMA, BRONCHITIS, EMPHYSEMA,
CHRONIC NOSE, SINUSE/THROAT CONDITIONS, SKIN/EYE CONDITIONS.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE CPR IF NEEDED. SKIN:
WASH THOROUGHLY W/WATER. EYES: WASH W/WATER FOR 15 MINS. INGESTION:
IF CONSCIOUS, GIVE LARGE QUANTITIES OF WATER. DON'T INDUCE
VOMITING. OBTA IN MEDICAL ATTENTION IN ALL CASES.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NONE
Fire Fighting Procedures:WEAR SELF CONTAINED POSITIVE-PRESSURE
BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:REACTION WITH METALS WILL RELEASE
FLAMMABLE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:EVACUATE AREA. WEAR PROTECTIVE EQUIPMENT.
CONTAIN ACID W/DIKES & PREVENT RUN-OFF INTO GROUND & SURFACE
WATERS/INTO SEWERS. NEUTRALIZE W/SODA ASH/DILUTE CAUSTIC SODA. IF
SPILLS OCCUR INDOORS, TURN OFF HEATING/AIR CONDITIONING SYSTEM.
Neutralizing Agent:SODA ASH/DILUTE CAUSTIC SODA.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN CLOSED, PROPERLY
LABELED/RUBBER-LINED STEEL, ACID-RESISTANT PLASTIC/GLASS
CONTAINERS. DON'T STORE NEAR STRONG ALKALIES/REACTIVE MATERIALS.
Other Precautions:DON'T REMOVE/DEFACE LABEL/TAG. HYDROGEN CHLORIDE CAN
REACT W/CYANIDE, FORMING LETHAL CONCENTRATIONS OF HYDROCYANIC ACID.
DON'T ENTER CONFINED SPACES SUCH AS TANKS/PITS W/O FOLLOWING PROPER
ENTRY PROCE DURES. AVOID CONTACT W/SKIN.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WHERE VAPOR CONCENTRATIONS EXCEEDS 5 PPM, USE
NIOSH/MSHA APPROVED FULL FACE RESPIRATOR W/ACID GAS CANISTER. A
NIOSH/MSHA APPROVED SCBA W/FULL FACE PIECE IS REQUIRED FOR AIR
CONCENTRATIONS >100 PPM.
Ventilation:AS NECESSARY TO MAINTAIN AIR CONCENTRATION <5 PPM
Protective Gloves:NEOPRENE
Eye Protection:CHEMICAL GOGGLES W/FACE SHIELD
Other Protective Equipment:POLYVINYL CHLORIDE RAIN SUIT, BOOTS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES
BEFORE REUSE. WASH THOROUGHLY PRIOR TO EATING, DRINKING/USING
RESTROOMS.
Supplemental Safety and Health
AVOID BREATHING VAPORS. DON'T EAT, DRINK/SMOKE IN WORK AREA.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:150-230F
Vapor Pres:78
Vapor Density:1.27
Spec Gravity:1.1600
Evaporation Rate & Reference:(BU AC =1) <1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR, COLORLESS LIQ W/PUNGENT, IRRITATING ODOR
Percent Volatiles by Volume:35
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BASES, METALS, MERCURIC SULFATE, PERCHLORIC ACID, CARBIDES OF CALCIUM,
CESIUM, RUBIDIUM, ACETYLIDES OF CESIUM & RUBIDIUM
Stability Condition to Avoid:N/K
_
Hazardous Decomposition Products:METALS: HYDROGEN GAS.
==================== Disposal Considerations ====================
Waste Disposal Methods:RECOVERED SOLIDS/LIQUIDS MAY BE SENT TO A
LICENSED RECLAIMER/DISPOSED OF IN A PERMITTED WASTE MANAGEMENT
FACILITY. DISPOSE OF IAW/FEDERAL, STATE & LOCAL REGULATIONS.
CORROSIVE, UN1789.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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