===================== Product Identification =====================
MSDS NAME:METHYL NORMAL AMYL KETONE
NIIN:00N014883
MSDS Number: BKMMQ
=== Responsible Party ===
Company:ASHLAND CHEMICAL COMPANY
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:606-324-1133
CAGE:34897
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Phone:614-790-3333/800-274-5263
CAGE:34897
============= Composition/Information on Ingredients =============
Name:METHYL N-AMYL KETONE
CAS:110-43-0
RTECS #:MJ5075000
Fraction by Wt: 100%
OSHA PEL:100 PPM
ACGIH TLV:50 PPM; 9192
Name:FIRST AID PROC: MOUTH TO UNCON PERSON. GET MED ATTN IMMED.
BRTHG: REMOVE TO FRESH AIR. IF BRTHG DFCLT, GIVE (ING 03)
RTECS #:9999999ZZ
Name:ING 02: OXYGEN. IF BRTHG STOPPED, GIVE ARTIFICIAL
RESPIRATION. KEEP PERSON WARM, QUIET AND GET MEDICAL ATTENTION.
RTECS #:9999999ZZ
Name:SPILL PROC: EXCLUDED FROM AREA OF SPILL UNTIL CLEAN UP HAS
BEEN COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF (ING 05)
RTECS #:9999999ZZ
Name:ING 04: SPILL TO PVNT SPREADING, PUMP LIQ TO SALVAGE TANK.
REMAINING LIQ MAY BE TAKEN UP ON SAND, CLAY, EARTH, (ING 06)
RTECS #:9999999ZZ
Name:ING 05: FLOOR ABSORBENT, OR OTHER ABSORBENT MATERIAL AND
SHOVELED INTO CONTAINERS.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CAN CAUSE MODERATE
IRRITATION, REDNESS, TEARING. SKIN: CAN CAUSE SLIGHT IRRITATION.
BRTHG: EXCESSIVE INHALATION OF VAPORS CAN CAUSE NASAL & RESPIRATORY
IRRITATION. INGEST: CAN CAUSE GI IR RITATION, NAUSEA, VOMITING, &
DIARRHEA.CHRONIC: OVEREXP TO MATL (OR COMPONENTS) HAS APPARENTLY
(SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: BEEN FOUND TO CAUSE THE FOLLOWING
EFFECTS IN LAB ANIMALS: ANEMIA, LIVER ABNORMALITIES, KIDNEY DAMAGE,
EYE DAMAGE, LUNG DAMAGE. OVEREXP HAS BEEN SUGGESTED AS A CAUSE OF
EYE DAMAGE IN HUMANS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: THORO WASH W/SOAP & WATER. REMOVE CONTAM CLTHG, LAUNDER
BEFORE REUSE. REMOVE CONTAM SHOES PROMPTLY. DISCARD SHOES SATURATED
W/PROD. EYES: FLUSH W/LG AMTS OF WATER FOR AT LEAST 15 MIN. LIFT
UPPER /LOWER LIDS OCCAS, GET MED ATTN. INGEST: IMMED DRINK 2
GLASSES WATER & INDUCE VOMITING BY EITHER GIVING IPECAC SYRUP OR BY
PLACING FINGER AT BACK OF THROAT. NEVER GIVE ANYTHING BY (SEE
INGRED 02)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:102F,39C
Lower Limits:1.1%
Extinguishing Media:REGULAR FOAM, WATER FOG, CO*2 OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA WITH FULL
FACEPIECE AND FULL PROTECTIVE EQUIPMENT . OPERATE IN THE POSITIVE
PRESSURE DEMAND MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPTY) BECAUSE PROD (EVEN RESIDUE) CAN IGNITE EXPLO.
VAPS ARE > AIR & MAY TRAVEL ALONG GROUND (SEE SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:SM SPILL: ABSORB LIQ ON PAPER, VERMICULITE,
FLOOR ABSORB, OR OTHER ABSORB MATL & TRANSFER TO HOOD. LG SPILL:
ELIMINATE ALL IGNITION SOURCES (FLARES, FLAMES INCLUDING PILOT
LIGHTS, ELEC SPARKS). PERSON S NOT WEARING PROT EQUIP SHOULD BE
(SEEINGRED 04)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN
EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ,
AND/OR SOLID), ALL HAZ PREC GIVEN MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT OF PROD/ANY
COMPONENT IS EXCEEDED, A NIOSH/MSHA APPROVED AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA RESPS (NEGATI VE PRESSURE TYPE) UNDER SPECIFIC
CNDTNS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLVS.
Protective Gloves:RESISTANT SUCH AS NITRILE RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: OR BE MOVED BY VENT & IGNITED BY HEAT, PILOT LIGHTS, OTHER
FLAMES & IGNITION SOURCES AT LOCATIONS DISTANT FROM MATL HANDLING
POINT. ALL 5 GAL PAILS & LARGER METAL CNTNRS INCLUDING TANK CARS
/TANK TRUCKS SHOULD BE GROUNDED AND/OR BONDED WHEN MATL IS
TRANSFERRED.
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:300F,149C
Vapor Pres:2.14 @ 20C
Vapor Density:3.9
Spec Gravity:0.811-0.814
Evaporation Rate & Reference:0.40 (N-BUTYL ACETATE=1)
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CO*2 AND CO,
ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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