===================== Product Identification =====================
MSDS NAME:AMMONIUM HYDROXIDE
NIIN:00N014724
MSDS Number: BKMMD
=== Responsible Party ===
Company:ANACHEMIA CHEMICALS INC
Address:3 LINCOLN BLVD
City:ROUSES POINT
State:NY
ZIP:12979-9970
Country:US
Info Phone Num:518-297-4444
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:4A444
=== Contractor Identification ===
Company:ANACHEMIA CHEMICALS INC
Address:3 LINCOLN BLVD
Box:City:ROUSES POINT
State:NY
ZIP:12979
Country:US
Phone:518-297-4444
CAGE:4A444
============= Composition/Information on Ingredients =============
Name:AMMONIUM HYDROXIDE (SARA III)
CAS:1336-21-6
RTECS #:BQ9625000
Fraction by Wt: <44%
Other REC Limits:TRANS PEL:50 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORL,RAT)350 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:MAY CAUSE SEVERE BURNS AND
LOSS OF VISION. CAUSES IRRITATION. LACRYMATOR. SKIN:CAUSES SEVERE
BURNS. IRRITATION. DESTRUCTIVE TISSUE OF MUCOUS MEMBRANE. MAY BE
FATAL IF INHALED, SWALLOWED, OR ABSORBED THROUGH SKIN. INHAL:MAY
CAUSERESPIRATORY INFLAMMATION. MAY CAUSE DELAYED LUNG INJURY. (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INGEST:CAUSES GASTROINTESTINAL
IRRITATION. ABDOMINAL PAIN. CHRONIC:TOXICITY OF SUBSTANCE HAS NOT
BEEN FULLY INVESTIGATED.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
Eyes:WASH W/COPIOUS QTYS OF WATER FOR AT LEAST 15 MIN. CALL
MD. SKIN:WASH W/COPIOUS QTYS OF WATER FOR AT LEAST 15 MIN. REMOVE
CONTAMINATED CLOTHING. CALL MD. INHAL:REMOVE TO FRESH AIR. GIVE
APPRVD O2 SUPPLY IF BRTHG DIFFICULT. GIVE ARTF RESP OR CPR IF
BRTHG CEASED. CALL MD. INGEST:DO NOT INDUCE VOMITING. GIVE LG QTY
OF WATER TO DILUTE. CALL MD. NEVER GIVE ANYTHING BY MOUTH TO
UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:NONCOMBUSTIBLE. USE MEDIA APPROPRIATE TO
SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA W/FULL FACEPIECE
OPERATED IN PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE AND
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:WHEN HEATED FLAMMABLE AND TOXIC VAPORS
GIVEN OFF. BOIL OVER MAY OCCUR WHEN PRODUCT REACHES BOILING POINT
OF WATER.
================== Accidental Release Measures ==================
Spill Release Procedures:ABSORB ON SAND OR VERMICULITE & PLACE IN
CLOSED CONTAINER FOR DISPOSAL. EVACUATE & VENTILATE AREA. WASH
SPILL SITE AFTER PICK-UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY, WELL VENT AREA
AWAY FROM DIRECT SUNLIGHT. STORE AWAY FROM INCOMPATIBLE MATLS. KEEP
TIGHTLY CLOSED. STORE IN STRONG (SEE SUPP DATA)
Other Precautions:FUMES FORM WHEN AMMONIA WATER IS BROUGHT NEAR
VOLATILE ACIDS. DO NOT GET IN EYES, ON SKIN OR CLOTHING. AVOID
PRLNGD/RPTD EXPOSURE.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ADEQUATE VENTILATION TO MAINTAIN AIR BELOW 25
PPM. WEAR NIOSH/MSHA APPROVED RESPIRATOR IF TLV IS TO BE EXCEEDED.
Ventilation:ADEQUATE VENTILATION TO MAINTAIN AIR BELOW 25 PPM. CHEMICAL
FUME HOOD IS RECOMMENDED.
Protective Gloves:NEOPRENE GLOVES OR POLYETHYLENE GLOVES.
Eye Protection:CHEM WORKERS GOG & FULL LGTH FACESHLD
Other Protective Equipment:APRON OR CLOTHING TO PROTECT SKIN.
IMPERVIOUS BOOTS. EMERG. EYE WASH AND DELUGE SHOWERS.
Work Hygienic Practices:WASH WELL AFTER USE.
Supplemental Safety and Health
MATLS TO AVOID:DIMETHYL SULFATE, HALOGENS, (AU + AQUA REGIA), OLEUM,
B-PROPIOLACTONE, PROPYLENE OXIDE, AGNO3, AG2O, (AG2O+C2H5OH),
AGMNO4. HNDLG/STOR PREC:GLASS, PLASTIC OR RUBBER STOPPERED BOTTLES
NO T COMPLETELY FILLED. DO NOT ALLOW SMOKING & FOOD CONSUMPTION
WHILE HANDLING. I/A/W GOOD STORAGE/HNDLG PRACTICES.
================== Physical/Chemical Properties ==================
HCC:C2
Boiling Pt:B.P. Text:82.0F,27.8C
Melt/Freeze Pt:M.P/F.P Text:-77
Vapor Pres:570
Vapor Density:0.6
Spec Gravity:0.897
Solubility in Water:100%.
Appearance and Odor:COLORLESS LIQUID; INTENSE, PUNGENT SUFFOCATING
ODOR; ACRID TASTE.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ACIDS, COPPER, MERCURY, ALUMINUM, TIN, IRON, ACROLEIN, NITROMETHANE,
ACRYLIC ACID, CHLOROSULFONIC ACID, (SEE SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:NH3 AND NOX WHEN HEATED TO
DECOMPOSITION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W APPLICABLE REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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