===================== Product Identification =====================
MSDS NAME:LA 2600
NIIN:00N014882
MSDS Number: BKMMP
=== Responsible Party ===
Company:ASHLAND CHEMICAL COMPANY
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333
Emergency Phone Num:606-324-1133
CAGE:34897
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Box:2219
City:COLUMBUS
State:OH
ZIP:43216-2219
Country:US
Phone:614-790-3333/800-274-5263
CAGE:34897
============= Composition/Information on Ingredients =============
Name:ING 05: OR OTHER ABSORB MATL & SHOVELED INTO CNTNRS. PVNT
RUN OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. (ING 07)
RTECS #:9999999ZZ
Name:ING 06: IF RUN OFF OCCURS, NOTIFY PROPER AUTHORITIES AS
REQUIRED THAT A SPILL HAS OCCURED.
RTECS #:9999999ZZ
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 64%
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:FIRST AID PROC: GET MED ATTN IMMED. BRTHG: REMOVE TO FRESH
AIR. IF BRTHG DFCLT, GIVE OXYGEN. IF BRTHG STOPPED, (ING 03)
RTECS #:9999999ZZ
Name:ING 02: GIVE ARTIFICIAL RESPIRATION. KEEP PERSON WARM,
QUIET AND GET MED ATTN IMMED.
RTECS #:9999999ZZ
Name:SPILL PROC: AREA OF SPILL UNTIL CLEAN UP HAS BEEN
COMPLETED. STOP SPILL AT SOURCE, DIKE AREA OF SPILL TO PVNT (ING
05)
RTECS #:9999999ZZ
Name:ING 04: SPREADING, PUMP LIQ TO SALVAGE TANK. REMAINING LIQ
MAY BE TAKEN UP ON SAND, CLAY, EARTH, FLOOR ABSORB, (ING 06)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYES: CAN CAUSE SEVERE
IRRITATION, REDNESS, TEARING, BLURRED VISION. SKIN: PRLNG/RPTD
CNTCT CAN CAUSE MODERATE IRRITATION, DEFAT, DERM. BRTHG: EXCESS
INHAL OF VAPORS CAN CAUSE NASAL & RESP IRRI T, CNS EFTS INCLUDING
DIZZ, WEAK, FATG,NAUS, HDCH & POSS UNCON, & EVEN DEATH. INGEST: CAN
CAUSE (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:NONE SPECIFIED BY MANUFACTURER.
Effects of Overexposure:HLTH HAZ: GI IRRITATION, NAUS, VOMIT, DIARR,
BLINDNESS & DEATH. CHRONIC: OVEREXP HAS APPARENTLY BEEN FOUND TO
CAUSE THE FOLLOWING EFTS IN LAB ANIMALS: LIVER ABNORMALITIES,
KIDNEY/EYE/LUNG/SPLEEN/BRAIN /NERVOUS SYSTEM DAMAGE. OVEREXP HAS
BEEN SUGGESTED AS A CAUSE OF EYE DAMAGE IN HUMANS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
======================= First Aid Measures =======================
First Aid:SKIN: THORO WASH W/SOAP & WATER. REMOVE CONTAM CLTHG. LAUNDER
BEFORE REUSE. REMOVE CONTAM SHOES PROMPTLY. DISCAR SHOES SATURATED
W/PROD. EYES: FLUSH W/LG AMTS OF WATER. LIFT UPPER/LOWER LIDS
OCCAS, GE T MED ATTN. INGEST: IMMED DRINK 2 GLASSES WATER & INDUCE
VOMIT BY EITHER GIVING IPECAC SYRUP OR BY PLACING FINGER AT BACK OF
THROAT. NEVER GIVE ANYTHING MY MOUTH TO AN UNCON PERSON. (SEE
INGRED 02)
===================== Fire Fighting Measures =====================
Flash Point Method:TCC
Flash Point:20.0F,-6.7C
Lower Limits:6.0%
Extinguishing Media:ALCOHOL FOAM, WATER FOG, CO*2 OR DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA WITH A FULL
FACEPIECE AND FULL PROTECTIVE EQUIPMENT . OPERATE IN THE POSITIVE
PRESSURE DEMAND MODE WHEN FIGHTING FIRES.
Unusual Fire/Explosion Hazard:NEVER USE WELDING/CUTTING TORCH ON/NEAR
DRUM (EVEN EMPTY) BECAUSE PROD (EVEN RESIUE) CAN IGNITE
EXPLOSIVELY. ALL 5 GAL PAILS & LARGER METAL (SEE SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:SM SPILL: ABSORB LIQ ON PAPER, VERMICULITE,
FLOOR ABSORBENT OR OTHER ABSORBENT MATL. LG SPILL: ELIMINATE ALL
IGNIT SOURCES (FLARES, FLAMES INCLUDING PILOT LIGHTS, ELEC SPARKS).
PERSONS NOT WEARING PRO T EQUIP SHOULD BE EXCLUDED FROM (SEE INGRED
04)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:CNTNRS OF THIS MATL MAY BE HAZ WHEN
EMPTIED. SINCE EMPTIED CNTNRS RETAIN PROD RESIDUES (VAP, LIQ,
AND/OR SOLID), ALL HAZ PREC GIVEN MUST BE OBSERVED.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF WORKPLACE EXPOSURE LIMIT OF PROD/ANY
COMPONENT IS EXCEEDED, A NIOSH/MSHA APPRVD AIR SUPPLIED RESP IS
ADVISED IN ABSENCE OF PROPER ENVIRON CTL. OSHA REGS ALSO PERMIT
OTHER NIOSH/MSHA RESPS (NEGATIVE PRESSURE TYPE) UNDER SPECIFIED
CNDTNS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLVS.
Protective Gloves:RESISTANT GLOVES: NEOPRENE.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS TO
PREVENT REPEATED OR PROLONGED SKIN CONTACT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: CNTNRS INCLUDING TANK CARS/TANK TRUCKS SHOULD BE GROUNDED
AND/OR BONDED WHEN TRANSFERRED. VAPS ARE > AIR & MAY TRAVEL ALONG
GROUND/MAY BE MOVED BY VENT & IGNITED BY PILOT LIGHTS, OTHER FLAM
ES, SPARKS, HEATERS, SMOKING, ELEC MOTORS, STATIC DISCH, OTHER
IGNIT SOURCES @ LOCATIONS DISTANT FROM MATL HNDLG POINT.
================== Physical/Chemical Properties ==================
HCC:F2
Boiling Pt:B.P. Text:147F,64C
Vapor Pres:97.68 @20C
Vapor Density:> AIR
Spec Gravity:LESS THAN WATER
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:100%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS: CO*2 AND CO,
VARIOUS HYDROCARBONS, ETC.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL LOCAL, STATE
AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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