| MSDS | : | SULFURIC ACID 77 TO 100%, 66 TECH | | CAS | : | 7664-93-9
7732-18-5 | | NAME | : | ing 16: the treatment. inhal: remove to fresh air immed &
ing 17: resp if brthg stops. give oxygen if brthg is dfclt.
ing 18: qtys of water. call md. do not give carbonates.
spill proc: ash & transfer to waste water treatment system.
ing 20:areas. comply w/fed, st & loc regs on reporting
eye prot: length faceshield to gogg .
ing 3: tearing/blurring of vision; or skin irrit
ing 4: incl irrit of upper resp passages/erosion of dental
ing 5: lung irrit efts w/cough, discomfort, difficulty
ing 6: symp, followed in hrs by severe shortness of breath,
ing 7: epidemiology studies did suggest a possible assocn
ing 8: conclusions from these studies are very limited
ing 9: example, only a sm number of workers was sampled,
ing 10:sulfate, a iarc & ntp carcinogen. in the other study
ing 11:histories of workers were ignored in the development
ing 12: of evidence from all human & chronic animal
ing 13:sulfuric acid expos & resp tract tumors has been
ing 14: note to md: continued washing of the affected area
ing 15: last traces of sulfuric acid. creams/ointments
sulfuric acid (sara iii)
water
efts of overexp: to muc memb of mouth & esophagus.
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===================== Product Identification =====================
MSDS NAME:SULFURIC ACID 77 TO 100%, 66 TECH
NIIN:00N015747
MSDS Number: BKRMR
=== Responsible Party ===
Company:DU PONT E I DE NEMOURS & CO INC
Address:1007 MARKET STREET
Box:1635
City:WILMINGTON
State:DE
ZIP:19898
Country:US
Info Phone Num:800-441-7515/MSDS 302-992-3511
Emergency Phone Num:800-441-3637/800-424-9300(CHEMTREC)
Preparer's Name:J.C. WATTS
CAGE:18873
=== Contractor Identification ===
Company:E.I. DUPONT DE NEMOURS & CO
Address:1007 MARKET STREET
Box:City:WILMINGTON
State:DE
ZIP:19898
Country:US
Phone:800-441-7515;800-441-9442
CAGE:18873
============= Composition/Information on Ingredients =============
Name:ING 16: THE TREATMENT. INHAL: REMOVE TO FRESH AIR IMMED &
HAVE PATIENT LIE DOWN & REMAIN QUIET. APPLY ARTF (SEE ING 18)
RTECS #:9999999ZZ
Name:ING 17: RESP IF BRTHG STOPS. GIVE OXYGEN IF BRTHG IS DFCLT.
CALL MD. INGEST: DO NOT INDUCE VOMIT. GIVE LRG (SEE ING 19)
RTECS #:9999999ZZ
Name:ING 18: QTYS OF WATER. CALL MD. DO NOT GIVE CARBONATES.
NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
RTECS #:9999999ZZ
Name:SPILL PROC: ASH & TRANSFER TO WASTE WATER TREATMENT SYSTEM.
PVNT LIQ FROM ENTERING SEWERS, WATERWAYS OR LOW (SEE ING 21)
RTECS #:9999999ZZ
Name:ING 20:AREAS. COMPLY W/FED, ST & LOC REGS ON REPORTING
RELEASES. SUPERFUND REPORTABLE DISCHARGE IS 1000 LBS.
RTECS #:9999999ZZ
Name:EYE PROT: LENGTH FACESHIELD TO GOGG .
RTECS #:9999999ZZ
Name:ING 3: TEARING/BLURRING OF VISION; OR SKIN IRRIT
W/DISCOMFORT/RASH. HUMAN HLTH EFTS OF OVEREXP BY INHAL MAY (SEE ING
5)
RTECS #:9999999ZZ
Name:ING 4: INCL IRRIT OF UPPER RESP PASSAGES/EROSION OF DENTAL
SURF. HIGHER EXPOS BY INHAL MAY LEAD TO TEMPORARY (SEE ING 6)
RTECS #:9999999ZZ
Name:ING 5: LUNG IRRIT EFTS W/COUGH, DISCOMFORT, DIFFICULTY
BRTHG/SHORTNESS OF BREATH/POSSIBLY MODEST INITIAL (SEE ING 7)
RTECS #:9999999ZZ
Name:ING 6: SYMP, FOLLOWED IN HRS BY SEVERE SHORTNESS OF BREATH,
REQUIRING PROMPT MED ATTN. ALTHOUGH TWO (SEE ING 8)
RTECS #:9999999ZZ
Name:ING 7: EPIDEMIOLOGY STUDIES DID SUGGEST A POSSIBLE ASSOCN
BETWEEN SULFURIC ACID EXPOS & RESP TRACT TUMORS, (SEE ING 9)
RTECS #:9999999ZZ
Name:ING 8: CONCLUSIONS FROM THESE STUDIES ARE VERY LIMITED
BECAUSE OF SIGNIFICANT DEFICIENCIES. IN ONE STUDY FOR(SEE ING 10)
RTECS #:9999999ZZ
Name:ING 9: EXAMPLE, ONLY A SM NUMBER OF WORKERS WAS SAMPLED,
AND THERE WAS EXPOS TO OTHER MATLS INCL DIETHYL (SEE ING 11)
RTECS #:9999999ZZ
Name:ING 10:SULFATE, A IARC & NTP CARCINOGEN. IN THE OTHER STUDY
THERE WAS EXPOS TO OTHER ACIDS, PLUS THE SMOKING(SEE ING 12)
RTECS #:9999999ZZ
Name:ING 11:HISTORIES OF WORKERS WERE IGNORED IN THE DEVELOPMENT
OF THE STUDY CONCLUSION. BASED ON THE OVERALL WT(SEE ING 13)
RTECS #:9999999ZZ
Name:ING 12: OF EVIDENCE FROM ALL HUMAN & CHRONIC ANIMAL
STUDIES, WE CONCLUDE THAT NO CASUAL RELATIONSHIP BETWEEN(SEE ING
14)
RTECS #:9999999ZZ
Name:ING 13:SULFURIC ACID EXPOS & RESP TRACT TUMORS HAS BEEN
SHOWN. FIRST AID PROC: APPLIED. AVOID FREEZING TISS.(SEE ING 15)
RTECS #:9999999ZZ
Name:ING 14: NOTE TO MD: CONTINUED WASHING OF THE AFFECTED AREA
W/COLD/ICED WATER WILL BE HELPFUL IN REMOVING THE(SEE ING 16)
RTECS #:9999999ZZ
Name:ING 15: LAST TRACES OF SULFURIC ACID. CREAMS/OINTMENTS
SHOULD NOT BE APPLIED BEFORE/DURING WASHING PHASE OF (SEE ING 17)
RTECS #:9999999ZZ
Name:SULFURIC ACID (SARA III)
CAS:7664-93-9
RTECS #:WS5600000
Fraction by Wt: 93.2%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 0-22%
Name:EFTS OF OVEREXP: TO MUC MEMB OF MOUTH & ESOPHAGUS.
RPTD/PRLNGD CONT W/MISTS MAY CAUSE EYE IRRIT W/DISCOMFORT,(SEE ING
4)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 2140 MG/KG.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:CAUSES SEVERE BURNS TO EYES, SKIN &
ALL BODY TISS. INHAL OF MIST MAY CAUSE LUNG DMG. THE CONC CMPD IS
CORR TO SKIN & EYE OF ANIMALS. BY INGEST IT IS MODERATELY TOXIC IN
ANIMALS CAUSING CORR OF MUCOSAL SURF. TOXIC EFTS DESCRIBED IN
ANIMALS FROM SINGLE EXPOS BY INHAL INCLUDE RESP IRRIT. ANIMAL (SEE
EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: TESTING INDICATES THAT THIS CMPD DOES
NOT HAVE THE POTENTIAL TO PRODUCE CARCINOGENIC, MUTAGENIC,
EMBRYOTOXIC, OR REPRO EFTS. HUMAN HLTH EFTS OF OVEREXP TO LIQ BY
SKIN/EYE CONT MAY CAUSE EYE CORR W/CORNEAL/CONJUNCTIVAL
ULCERATION;OR SKIN BURNS/ULCERATION. INGEST OF LIQ MAY CAUSE SEVERE
BURNS (SEE ING 3)
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PREEXISTING
DISEASES OF THE LUNGS MAY HAVE INCREASED SUSCEPTIBILITY TO THE
TOXICITY OF EXCESSIVE EXPOSURES.
======================= First Aid Measures =======================
First Aid:SKIN/EYES: IMMED (WITHIN SECONDS) FLUSH W/PLENTY OF WATER
(PREF COLD) FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG &
SHOES. CALL MD. WASH CLTHG BEFORE REUSE. WHILE PATIENT IS BEING
TRANSPORTED TO M EDICAL FACILITY, APPLY COMPRESSES OF ICED WATER.
IF MED TREATMENT MUST BE DELAYED, IMMERSE THE AFFECTED AREA IN ICED
WATER. IF IMMERSION IS NOT PRACTICAL, COMPRESSES OF ICED WATER CAN
BE (SEE ING 14)
===================== Fire Fighting Measures =====================
Flash Point:WILL NOT BURN
Extinguishing Media:USE MEDIA AS APPROP FOR COMBUST IN AREA. USE WATER
SPRAY TO COOL CNTNRS EXPOSED TO FIRE; DO NOT GET WATER INSIDE
CNTNRS.
Fire Fighting Procedures:NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP IF
FUMES OR MISTS ARE PRESENT. EVAC PERS TO SAFE AREA. KEEP PERS
REMOVED & UPWIND OF FIRE. GENERATES (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:REACTS WITH MOST METALS, ESPECIALLY WHEN
DILUTE, TO GIVE FLAMMABLE, POTENTIALLY EXPLOSIVE HYDROGEN GAS.
================== Accidental Release Measures ==================
Spill Release Procedures:STOP FLOW IF POSS. REVIEW "FIRE & EXPLO HAZ" &
"SAFETY PREC" BEFORE PROCEEDING W/CLEAN UP. USE APPROP PROT EQUIP
DURING CLEAN UP. SOAK UP SM SPILLS W/DRY SAND, CLAY/DIATOMACEOUS
EARTH. DIKE LRG SPILLS & CAUTIOUSLY DILUTE, NEUT W/LIME/SODA(SEE
ING 20)
Neutralizing Agent:SEE SPILL/RELEASE PROCEDURES.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP OUT OF SUN & AWAY FROM
HEAT/SPARKS/FLAME. KEEP CNTNR TIGHTLY CLOSED. LOOSEN CLOSURE TO
RELIEVE INTERNAL PRESS WHEN RECEIVED & WEEKLY THEREAFTER.
Other Precautions:DO NOT USE PRESS TO EMPTY. BE SURE CLOSURE IS
SECURELY FASTENED BEFORE MOVING CNTNR. DO NOT WASH OUT CNTNR/USE IT
FOR OTHER PURPOSES; REPLACE CLOSURE AFTER EACH WITHDRAWAL & RETURN
IT W/EMPTY CNTNR.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF ACID VAPOR OR MIST ARE PRESENT AND EXPOSURE
LIMITS MAY BE EXCEEDED, WEAR NIOSH/MSHA APPROVED RESPIRATORY
PROTECTION.
Ventilation:GOOD GENERAL VENTILATION SHOULD BE PROVIDED TO KEEP VAPOR
AND MIST CONCENTRATIONS BELOW THE EXPOSURE LIMITS.
Protective Gloves:ACID-PROOF GAUNTLET GLOVES.
Eye Protection:CHEM WORK GOGG. MAY ADD FULL(SEE ING 22)
Other Protective Equipment:APRON/BOOTS/LONG SLEEVE WOOL/ACRYLIC OR
POLYESTER CLTHG. IN CASE OF EMER WEAR COMPLETE ACID-PROOF
SUIT/HOOD/ (SUPP DATA)
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: HEAT UPON ADDTN OF WATER, W/POSS SPATTERING. RUNOFF
FROM FIRE CONTROL MAY CAUSE POLLUTION. NEUT RUNOFF W/LIME, SODA
ASH, ETC, TO PVNT CORR OF METALS & FORMATION OF HYDROGEN GAS. MATLS
TO AVOID: OXIDIZING, REDUCING/COMBUST ORG MATLS. OTHER PROT EQUIP:
BOTTS/GLOVES, EMERGENCY EYE WASH & DELUGE SHOWER.
================== Physical/Chemical Properties ==================
HCC:C1
Boiling Pt:B.P. Text:535F,279C
Melt/Freeze Pt:M.P/F.P Text:-31F,-35C
Vapor Pres:<0.3 @ 25C
Vapor Density:3.4
Spec Gravity:1.835
pH:<1
Evaporation Rate & Reference:<1 (BUTYL ACETATE = 1)
Solubility in Water:100%
Appearance and Odor:OILY; CLEAR TO TURBID, COLORLESS TO LIGHT GRAY WITH
NO ODOR-LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, ALKALINE SOLN, METALS, METAL POWDERS, CARBIDES, CHLORATES,
FULMINATES, NITRATES, PICRATES, STRONG (SEE SUPP DATA)
Stability Condition to Avoid:HAZARDOUS GASES ARE EVOLVED ON CONTACT
WITH CHEMICALS SUCH AS CYANIDES, SULFIDES AND CARBIDES.
Hazardous Decomposition Products:RELEASES SULFUR DIOXIDE AT EXTREMELY
HIGH TEMPERATURES.
==================== Disposal Considerations ====================
Waste Disposal Methods:CLEANED-UP MATL IS A RCRA HAZ WASTE. DO NOT
FLUSH TO SURF WATER/SANITARY SEWER SYSTEM. COMPLY WITH FEDERAL,
STATE, AND LOCAL REGULATIONS. IF APPROVED, NEUTRALIZE & TRANSFER TO
WASTE TREATMENT SYSTEM.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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