===================== Product Identification =====================
MSDS NAME:DIMETHYLFORMAMIDE
NIIN:00F008075
MSDS Number: BBZGD
=== Responsible Party ===
Company:BASF WYANDOTTE CORPORATION
Address:100 CHERRY HILL ROAD
City:PARSIPPANY
State:NJ
ZIP:07054
Info Phone Num:(201) 263-3400
Emergency Phone Num:(201) 263-3400
CAGE:1T774
=== Contractor Identification ===
Company:BASF CORPORATION
Box:13528
City:RESEARCH TRIANGLE PARK
State:NC
ZIP:27709
Country:US
Phone:919-547-2000
CAGE:1T774
============= Composition/Information on Ingredients =============
Name:MONOMETHYLFORMAMIDE
CAS:123-39-7
RTECS #:LQ3000000
ACGIH TLV:200 PPM
Name:FORMIC ACID (SARA III)
CAS:64-18-6
RTECS #:LQ4900000
Other REC Limits:5 PPM=IC
OSHA PEL:5 PPM
ACGIH TLV:5 PPM/10 STEL; 9192
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:DIMETHYLAMINE (SARA III)
CAS:124-40-3
RTECS #:IP8750000
Other REC Limits:10 PPM
OSHA PEL:5 PPM/STEL15PPM;9293
ACGIH TLV:10 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:DIMETHYLFORMAMIDE
CAS:68-12-2
RTECS #:LQ2100000
Fraction by Wt: 99.9%
Other REC Limits:10 PPM (SKIN)
OSHA PEL:S, 10 PPM
ACGIH TLV:S, 10 PPM; 9192
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:METHYL ALCOHOL (METHANOL) (SARA III)
CAS:67-56-1
RTECS #:PC1400000
Other REC Limits:200 PPM
OSHA PEL:S,200PPM/250STEL
ACGIH TLV:S,200PPM/250STEL; 93
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
===================== Hazards Identification =====================
LD50 LC50 Mixture:RAT ORAL LD50 = 1.5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: OVEREXPOSURE SKIN
ABSORPTION MAY CAUSE ABDOMINAL PAIN, LOSS OF APPETITE, NAUSEA,
VOMITING, DIARRHEA, & INCREASED BLOOD PRESSURE. LIVER INJURY MAY
RESULT. MAY CAUSE FACIAL FLUSHING, ESPECIA LLY IN CONJUNCTION
W/ALCOHOL INGESTION.SKIN: REPEATED W/THE LIQUID MAY RESULT IN A
DEFATTING DERMATITIS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION OF THE EYES/SKIN. SKIN: REPEATED
CONTACT WITH THE LIQUID MAY RESULT IN A DEFATTING DERMATITIS.
CHRONIC OVEREXPOSURE TO DIMETHYLFORMAMIDE MAY RESULT IN LIVER &
KIDNEY DAMAGE. OVEREXPOSURE SK IN ABSORPTION MAY CAUSE ABDOMINAL
PAIN,LOSS OF APPETITE, NAUSEA, VOMITING, DIARRHEA, & INCREASED
BLOOD PRESSURE.
Medical Cond Aggravated by Exposure:LIVER & KIDNEY DAMAGE.
======================= First Aid Measures =======================
Eyes: FLUSH W/FLOWING WATER AT LEAST 15 MINS. SKIN: WASH
AFFECTED AREAS THOROUGHLY W/SOAP & WATER. INGESTION: IF SWALLOWED,
DILUTE WITH WATER & INDUCE VOMITING. GET MED ATT. INHALATION: MOVE
TO FRESH AIR. AID IN BREATHING, IF NECESSARY, & GET MED ATT. NEVER
GIVE FLUIDS OR INDUCE VOMITING IF PATIENT IS UNCONSCIOUS OR HAVING
CONVULSIONS.
===================== Fire Fighting Measures =====================
Flash Point:58C
Lower Limits:2.2%
Extinguishing Media:WATER FOG, FOAM, CO2, DRY CHEMICAL
Fire Fighting Procedures:FIREFIGHTERS SHOULD BE EQUIPPED WITH SCBA &
TURN-OUT GEAR. USE WATER TO KEEP CONTAINERS COOL.
Unusual Fire/Explosion Hazard:MODERATE, WHEN EXPOSED TO HEAT OR FLAMES.
CAN REACT WITH OXIDIZING MATERIALS. EXPLOSION HAZARD WHEN EXPOSED
TO FLAME.
================== Accidental Release Measures ==================
Spill Release Procedures:SPILLS SHOULD BE CONTAINED, SOLIDIFIED, &
PLACED IN SUITABLE CONTAINERS FOR DISPOSAL IN A RCRA LICENSED
FACILITY. THIS MATERIAL IS RCRA HAZARDOUS DUE TO ITS PROPERTIES.
====================== Handling and Storage ======================
Handling and Storage Precautions:EMPTY CONTAINERS WITH <1 INCH OF
RESIDUE MAY BE LANDFILLED AT A LICENSED FACILITY. RECOMMEND
CRUSHING OR OTHER MEANS TO PREVENT UNAUTHORIZED REUSE.
Other Precautions:DON'T REUSE THIS CONTAINER UNLESS IT IS
PROFESSIONALLY CLEANED AND RECONDITIONED.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:APPROVED ORGANIC VAPOR RESPIRATOR.
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION TO KEEP
Eye Protection:GOGGLES, FACE SHIELD
Other Protective Equipment:COVERALLS, APRON, BOOTS AS NECESSARY TO
PREVENT SKIN CONTACT.
Supplemental Safety and Health
MOLECULAR WEIGHT: 73.09
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:153C
Melt/Freeze Pt:M.P/F.P Text:-61C
Vapor Pres:2.65
Vapor Density:2.51
Spec Gravity:0.9445
Solubility in Water:INFINITE
Appearance and Odor:COLORLESS LIQUID, AMINE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
BROMINE/INORGANIC ACIDS/HALOGENATED
HYDROCARBONS/OXIDIZERS/MAGNESIUM/ORGANIC NITRATES/METHYLENE
DIISOCYANATE/ALUMINUM.
Stability Condition to Avoid:HEAT, SPARKS, FLAME, HUMIDITY.
Hazardous Decomposition Products:FORMIC ACID & DIMETHYLAMINE
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR BURY AS A SOLID IN A RCRA LICENSED
FACILITY. DON'T DISCHARGE INTO WATERWAYS OR SEWERS SYSTEMS.
HAZARDOUS WASTE NUMBER D001.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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