===================== Product Identification =====================
MSDS NAME:106 FLASH RIGHT
NIIN:00N018436
MSDS Number: BLFQM
=== Responsible Party ===
Company:HURST GRAPHICS INC
Address:2500 SAN FERNANDO
City:LOS ANGELES
State:CA
ZIP:90065
Country:US
Info Phone Num:213-223-4121
Emergency Phone Num:213-223-4121
Preparer's Name:A KORKIN, PHD
CAGE:54627
=== Contractor Identification ===
Company:HURST GRAPHICS INC
Address:2500 SAN FERNANDO RD
Box:City:LOS ANGELES
State:CA
ZIP:90065-1324
Country:US
Phone:213-223-4121
CAGE:54627
============= Composition/Information on Ingredients =============
Name:ING 14: AFTER EXPOSURE TO METHYLENE CHLORIDE.
RTECS #:9999999ZZ
Name:SPILL PROC: INERT MATLS TO DAM & CONTAIN SPILL. DO NOT
FLUSH AREA W/WATER. FOR SMALL SPILLS, DO NOT FLUSH WITH (ING 17)
RTECS #:9999999ZZ
Name:ING 16: WATER; USE ABSORBENT PADS. CALL SPILL RESPONSE TEAM
IF LARGE SPILL. NOTIFY APPROPRIATE STATE/LOCAL AGENCIES.
RTECS #:9999999ZZ
Name:OTHER PREC: MAY EXPLODE & CAUSE INJURY/DEATH. "EMPTY" DRUMS
SHOULD BE COMPLETELY DRAINED, PROPERLY BUNGED & (ING 19)
RTECS #:9999999ZZ
Name:ING 18: PROMPTLY SHIPPED TO THE SUPPLIER OR A DRUM
RECONDITIONER. ALL OTHER CNTNRS SHOULD BE DISPOSED OF IN AN (ING
20)
RTECS #:9999999ZZ
Name:ING 19: ENVIRON SAFE MANNER & I/A/W GOVERNMENTAL REGS. NO
SMOKING IN AREA OF USE. DO NOT USE IN THE GENL VICIN (ING 21)
RTECS #:9999999ZZ
Name:ING 20: OF ARC WELDING, OPEN FLAMES OR HOT SURF. HEAT
AND/OR UV RADIA MAY CAUSE THE FORM OF HCL AND/OR PHOSGENE .
RTECS #:9999999ZZ
Name:ING 13: IN PATIENTS SYMPTOMATIC (HEADACHE, NAUSEA,
VOMITING, MALAISE, SHORTNESS OF BREATH, CHEST PAIN, SWEATING)(ING
15)
RTECS #:9999999ZZ
Name:METHYLENE CHLORIDE (SARA III)
CAS:75-09-2
RTECS #:PA8050000
Fraction by Wt: 18-22%
OSHA PEL:500 PPM/C,1000; Z2
ACGIH TLV:50 PPM, A2; 9192
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:BENZIN; (VM&P NAPHTHA)
CAS:8030-30-6
RTECS #:DE3030000
OSHA PEL:100 PPM
ACGIH TLV:300 PPM (MFR)
Name:EFTS OF OVEREXP: NORM BLOOD FUNC OF EXPOS TO HIGH CONC
OCCURS. RPTS HAVE ASSOC RPTD/PRLNG OCCUP OVEREXP TO SOLV (ING 04)
RTECS #:9999999ZZ
Name:ING 03: W/PERM BRAIN & NERVS SYS DMG (SOMETIMES REFERRED TO
AS SOLV OR PAINTERS' SYNDROME). INTENTIONAL MISUSE (ING 05)
RTECS #:9999999ZZ
Name:ING 04: BY DELIBERATELY CONCENTRATING & INHALING CONTENTS
MAY BE HARMFUL/FATAL. CHLOROCARBON MATLS HAVE PRDCD (ING 06)
RTECS #:9999999ZZ
Name:ING 05: SENSITIZATION OF THE MYOCARDIUM TO EPINEPHRINE IN
LAB ANIMALS & COULD HAVE A SIMILAR EFFECT IN HUMANS. (ING 07)
RTECS #:9999999ZZ
Name:ING 06: ADRENOMIMETICS (E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS (ING 08)
RTECS #:9999999ZZ
Name:ING 07: ACUTELY OR CHRONICALLY EXPOSED TO CHLOROCARBONS .
RTECS #:9999999ZZ
Name:FIRST AID PROC: SEEK MED ATTN. INGEST: ASPIR HAZ: DO NOT
INDUCE VOMIT OR GIVE ANYTHING BY MOUTH, BECAUSE MATL (ING 10)
RTECS #:9999999ZZ
Name:ING 09: CAN ENTER LUNGS & CAUSE SEV DMG. IF VICTIM IS
DROWSY/UNCON, PLACE ON LEFT SIDE W/HEAD DOWN. IF POSS, DO (ING 11)
RTECS #:9999999ZZ
Name:ING 10: NOT LEAVE VICTIM UNATTENDED. SEEK MED ATTN. REC TO
MD: THE LIVER METABOLIZES PART OF THE DOSE OF (ING 12)
RTECS #:9999999ZZ
Name:ING 11: METHYLENE CHLORIDE TO CO, WHICH MAY INTERFERE W/O*2
TRANSPORT/UTILIZATION. PREEXISTING CARDIOVASCULAR (ING 13)
RTECS #:9999999ZZ
Name:ING 12: DISORDERS MAY BE AGGRAVATED BY EXPOS TO METHYLENE
CHLORIDE. CARBOXYHEMOGLOBIN LEVELS SHOULD BE MEASURED (ING 14)
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL: BRTHG HIGH CONC OF VAPS/MISTS
MAY CAUSE IRRIT OF NOSE & THROAT/SIGNS OF NERVS SYS
DEPRESS/NAUS/VOMIT. EYES: DIRECT CNTCT W/LIQ MAY CAUSE
STINGING/TEARING/REDNESS/SWELLING. SKIN: REDNESS/BURNING
/DRYING/CRACKING. INGEST: EXCESS QTYS MAY CAUSE SIGNS OF NERVS SYS
DEPRESS/IRRIT OF THE DIGESTIVE (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE: IARC GROUP 2B, NTP
KNOWN ANIMAL CARCINOGEN/SUSPECTED HUMAN CARCINOGEN, ACGIH GROUP A2.
Effects of Overexposure:HLTH HAZ: TRACT/VOMITING. ASPIR HAZ--ONE OR
MORE COMPS OF MATL CAN ENTER INTO THE LUNG DURING
SWALLOWING/VOMITING & CAUSE LUNG INFLAMM/DMG. ACUTE: SKIN/EYE/RESP
TRACT IRRIT/MILD CNS DEPRESS. CHRONIC: BLOOD/LIVER DISORDERS.
METHYLENE CHLORIDE, A COMP OF THIS PROD, FORMS CO IN THE BODY & MAY
INTERFERE W/ (SEE INGRED 03)
Medical Cond Aggravated by Exposure:RESPIRATORY SYMPTOMS ASSOCIATED
WITH PREEXISTING LUNG DISORDERS, PREEXISTING BLOOD/LIVER DISORDERS,
PREEXISTING CARDIOVASCULAR DISORDERS, PREEXISTING SKIN DISORDERS.
======================= First Aid Measures =======================
First Aid:EYE: MOVE VICTIM AWAY FROM EXPOS & INTO FRESH AIR. FLUSH
W/CLEAN WATER FOR AT LEAST 15 MIN & SEEK MED ATTN. SKIN: REMOVE
CONTAM SHOES/CLTHG & FLUSH AFFECTED AREAS W/LG AMTS WATER. IF SKIN
SURF IS DMGD , APPLY CLEAN DRESSING & SEEK MED ATTN,OTHERWISE WASH
W/MILD SOAP & WATER. INHAL: IF SYMPS OF EXPOS DEVELOP, MOVE VICTIM
AWAY FROM SOURCE OF EXPOS & INTO FRESH AIR. IF SYMPS PERSIST (SEE
INGRED 09)
===================== Fire Fighting Measures =====================
Flash Point:103F,39C
Lower Limits:0.9%
Upper Limits:6%
Extinguishing Media:CO2, FOAM, DRY CHEMICAL
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DMD SCBA & FULL
PROT EQUIP . WATER SPRAY MAY BE USEFUL IN MINIMIZING VAPS/COOLING
CNTNRS EXPOSED TO HEAT AND (SEE SUPP DATA)
Unusual Fire/Explosion Hazard:MATL IS COMBUST & MAY BE IGNITED BY HEAT/
FLAME. BLENDS CONTAINING CHLORINATED PRODS MAY EXHIBIT REDUCED FL
PT AS THE MORE VOLAT CHLORINE EVAPS. (SEE SUPP DATA)
================== Accidental Release Measures ==================
Spill Release Procedures:STAY UPWIND & AWAY FROM SPILL. KEEP ALL IGNIT
SOURCES/HOT METAL SURF AWAY FROM SPILL. IF SPILL IS INDOORS, VENT
AREA. A UNIVERSAL TYPE FOAM CAN BE USED TO SUPPRESS VAPS. KEEP
SPILL OUT OF DRAINS/SEWER S/WATERWAYS. USE SAND OR OTHER (SEE
INGRED 16)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP CONTAINERS TIGHTLY CLOSED. KEEP
CONTAINERS COOL, DRY AND AWAY FROM SOURCES OF IGNITION. USE AND
STORE WITH ADEQUATE VENTILATION.
Other Precautions:AVOID INHAL OF VAPS/PERS CNTCT W/PROD. "EMPTY" CNTNRS
RETAIN RESIDUE (LIQ AND/OR VAP) & CAN BE DANGEROUS. DO NOT
PRESSURIZE/CUT/ WELD/BRAZE/ SOLDER/DRILL/GRIND/EXPOSE SUCH CNTNRS
TO HEAT/FLAME/SPARKS/ OTHER IGNIT SOURCES; THEY (SEE INGRED 1
============= Exposure Controls/Personal Protection =============
Respiratory Protection:THE USE IS ADVISED WHEN CONCENTRATIONS EXCEED
THE ESTABLISHED EXPOSURE LIMITS. DEPENDING ON THE AIRBORNE
CONCENTRATION, USE A NIOSH/MSHA APPROVED RESPIRATOR OR GAS MASK
WITH APPROPRIATE CARTRIDGES AND CANISTERS.
Ventilation:IF CURRENT PRACT ARE NOT ADEQ, ADDNL VENT/EXHST SYS MAY BE
REQD. WHERE EXPLO MIX MAY BE PRESENT, ELEC SYS MAY BE USED.
Protective Gloves:IMPERMEABLE GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH & QUICK DRENCH SHOWER FAC SHOULD BE
AVAIL IN WORK AREA. THORO CLEAN SHOES & WASH CONTAM CLTHG BEFORE
REUSE.
Work Hygienic Practices:PRACT PERS CLEANLINESS BY PROMPT REMOVAL OF
SOLV IN CNTCT W/SKIN. TRAIN ALL EMPLOYEES ON SPEC HNDLG PROC PRIOR
TO USE.
Supplemental Safety and Health
FIRE FIGHT PROC: FLAME. AVOID SPREADING BURNING LIQ W/WATER USED FOR
COOLING PURPOSES. FIRE/EXPLO HAZ: CNTCT W/ ALUMINUM PARTS IN
PRESSURIZABLE FLUID SYS MAY CAUSE VIOLENT RXNS. THERM DECOMP PRODS
MAY INCL HCL & PHOSGENE . MATLS TO AVOID: OXIDIZERS, REACTIVE
METALS (ALUMINUM POTASSIUM, SODIUM, ETC).
================== Physical/Chemical Properties ==================
HCC:F4
Boiling Pt:B.P. Text:104F,40C
Vapor Pres:152.7 @20C
Vapor Density:3.86
Spec Gravity:0.864
Evaporation Rate & Reference:3.7 (BUTYL ACETATE=1)
Solubility in Water:0.3
Appearance and Odor:BLUE CLEAR LIQUID; PETROLEUM ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
INCOMPAT W/STRONG ACIDS OR BASES, OXIDIZING AGENTS, SELECTED AMINES,
ALKALIES, OXYGEN, NITROGEN PEROXIDE (SEE SUPP DATA)
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO2, CO, HCL AND PHOSGENE.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF PRODUCT IN ACCORDANCE WITH LOCAL,
COUNTY, STATE AND FEDERAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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