===================== Product Identification =====================
MSDS NAME:WOLMANAC CONCENTRATE 5096, 38000057
NIIN:00N022068
MSDS Number: BLVSH
=== Responsible Party ===
Company:KOPPERS CO INC
Address:436 SEVENTH AVENUE
City:PITTSBURGH
State:PA
ZIP:15219-1818
Country:US
Info Phone Num:800-323-6571
Emergency Phone Num:800-424-9300 (CHEMTREC)
Preparer's Name:OCCUP HLTH/PROD SFTY DEPT
CAGE:80592
=== Contractor Identification ===
Company:KOPPERS CO INC
Address:3000 KOPPERS BLDG
Box:City:PITTSBURGH
State:PA
ZIP:15219-1818
Country:US
CAGE:80592
============= Composition/Information on Ingredients =============
Name:ARSENIC PENTOXIDE
CAS:1303-28-2
RTECS #:CG2275000
Fraction by Wt: 20%
OSHA PEL:0.01 MG/M3
ACGIH TLV:0.2 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CHROMIUM (VI) OXIDE (1:3); (CHROMIC ACID)
CAS:1333-82-0
RTECS #:GB6650000
Fraction by Wt: 25%
OSHA PEL:0.1 MG/M3, C
ACGIH TLV:0.05 MG/M3
Name:COPPER OXIDE
CAS:1317-38-0
RTECS #:GL7900000
Fraction by Wt: 25%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 50%
Name:FIRST AID PROC: SEV ARSENIC POISONING FROM OCCUP EXP IS
UNLIKELY; IF IT SHLD OCCUR, ADMIN BAL 10% IN OIL, IM, (ING #6)
RTECS #:9999999ZZ
Name:ING #5: 3 MG/KG FOR EACH INJECTION-DAY 1 & 2, EVERY 4HRS;
DAY 3, EVERY 6HRS; DAY 4-14, EVERY 12HRS.
RTECS #:9999999ZZ
Name:SPILL PROC:CLEANER TO RECOVER. USE AN INERT ABOSRB TO
COMPLETE A CLEAN-UP.
RTECS #:9999999ZZ
Name:NEUT AGENTS: CEMENT/50 GAL PRODUCT.
RTECS #:9999999ZZ
Name:OTHER PREC: DISCARDING/REUSE. DO NOT TAKE INTERNALLY. LIQ
PENETRATES SHOES/LEATHER CAUSING DELAYED BURNS. (ING #10)
RTECS #:9999999ZZ
Name:ING #9: SHOWERING/CLOTHING CHANGE RECOMMENDED AT END OF
EACH SHIFT.
RTECS #:9999999ZZ
Name:HYGIENE PRAC: CONTACT FROM WORKING W/PROD & BEFORE
EATING/DRINKING/USING TOBACCO PRODUCTS OR REST ROOMS. (ING #12)
RTECS #:9999999ZZ
Name:ING #11: DO NOT WEAR CONTACT LENS WITHOUT PROPER EYE
PROTECTION.
RTECS #:9999999ZZ
Name:OTHER PROT EQUIP: EYE WASH AND DELUGE SHOWER .
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:(ORAL, RAT) 90 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:DANGER! CAUSES SEVERE EYE BURNS/SEVERE
BURNS. MAY BE FATAL IF INHAL. MAY BE FATAL IF ABSORB THRU SKIN. MAY
BE FATAL IF SWALLOWED. WARNING: THIS PROD CONTS A CHEM KNOWN TO
CALIFORNIA TO CAUSE CANCER. E YE: CORR TO EYES. SKIN: CORR TO SKIN.
MATL MAY PENETRATE SKIN, CAUSE DEATH/DMG TO INTERNAL ORGANS (EFTS
OF OVEREXP)
Explanation of Carcinogenicity:ARSENIC PENTOXIDE: GROUP 1 (NTP);
CHROMIC ACID: GROUP 1 (NTP), GROUP 1 (IARC)
Effects of Overexposure:HLTH HAZ: INCLUDING LIVER/KIDNEYS. INHAL: CORR
TO UPPER AIRWAY WHEN INHAL IN CONC EXCEEDING RECOMM EXPOS LMTS.
SHORT- TERM OVEREXP MAY CAUSE MUSCLE SPASMS, DIZZ, COLLAPSE. PRLNGD
OVEREXP MAY CAUSE PER FORATION OF NASAL SEPTUM, HOARSENESS OFVOICE,
LIVER INJURY & SKIN CHANGES. CHRONIC ARSENIC INTOX IS CHARACT (SUPP
DATA)
Medical Cond Aggravated by Exposure:INDIVIDUALS W/PRE-EXISTING DISEASE
IN/A HISTORY OF AILMENTS INVOLVING SKIN, KIDNEY, LIVER, LUNGS, OR
CNS MAY BE AT GREATER RISK OF DEVELOPING ADVERSE HEALTH EFFECTS.
======================= First Aid Measures =======================
Eyes:IMMED FLUSH W/POTABLE WATER FOR AT LEAST 15 MIN, SEEK
ASSIST FROM MD. SKIN:FLUSH W/COPIOUS AMTS OF WATER (DELUGE SHOWER)
FOR AT LEAST 15 MIN. REMOVE CONTAM CLOTHG UNDER SHOWER. CALL
MD.(FPN ) INHAL: REMOVE TO FRESH AIR. SUPPORT BRTHG (GIVE O2/ARTF
RESP).INGEST: DO NOT INDUCE VOMIT. GIVE 1 GLASS OF MILK/1-2 OZ OF
ACTIVATED CHARCOAL IN WATER TO VICTIM AS TOLERATED.NOTE TO MD.(ING
5)
===================== Fire Fighting Measures =====================
Flash Point:NON FLAMMABLE
Extinguishing Media:USE MEDIA SUITABLE FOR SURROUNDING FIRE .
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
USE H2O TO COOL FIRE-EXPOS CNTNR/STURCTURE/PROTECT PERS. PROD DOES
NOT BURN. FIRE FROM SEPARATE (SUPP DATA)
Unusual Fire/Explosion Hazard:CONC WILL NOT BURN. CHROMIC ACID CONTENT
MAKES PROD STRONG OXID AGENT; CONT W/STRONG RED AGENT MAY CAUSE
EXPLOS. MAY CAUSE FIRE ON CON W/COMBUST MATLS.(SUPPDAT)
================== Accidental Release Measures ==================
Spill Release Procedures:STOP LEAK IF NO RISK INVOLVED. STAY UPWIND.
SMALL SPILLS: TAKE UP W/SAND/OTHER NONCOMBUST ABSORB MATL. FLUSH
AREA W/ WATER. LGE SPILLS: DIKE FOR LATER DISP. CONTAIN RUNOFF FROM
FIRE CONTROL & DILUTION WATER. PREF USE A LIQ RECOVERY TYPE VACUUM
(ING 7
Neutralizing Agent:NEUT W/LIME/CEMENT BEFORE CLEANUP BEGINS.
RATIO-200LBS LIME/800LBS (ING 8)
====================== Handling and Storage ======================
Handling and Storage Precautions:KEEP IN CLSD, PROP LBL CNTNR W/IN
COOL(SHADED) DRY, WELL-VENT AREA.SEPARATE MATL FROM COMBUST
SUBSTANCES/ FUELS/ORG CHEM,DEHYDRATING/REDUCING AGENTS.
Other Precautions:FOLLOW OSHA/NIOSH CONFINED SPACE ENTRY PROC. RELIEVE
INTERNAL PRESS WHEN RECEIVED IN DRUMS/AT LEAST WEEKLY THEREAFTER BY
SLOWLY LOOSENING CLOSR. RETIGHTEN IMMED. DO NOT USE PRESS TO EMPTY
DRUMS. CLEAN CNTNRS PROP/THORO BEFORE (ING 9)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF VENT IS INADEQ TO MAINT PERS INHAL EXP < TLV
(PEL), USE APPROP NIOSH/MSHA APPRVD RESP PROT TO COMPLY W/CURRENT
29 CFR 1910.134 & MFR'S "INSTRUCTIONS" & "WARNINGS".
Ventilation:PROVIDE SUFF GENL/LOCAL EXHAUST VENT IN PATTERN/VOL TO
CONTROL INHAL EXP BELOW CURRENT EXP LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOG W/FULL LNGTH FCSHLD
Other Protective Equipment:ACID RESIST INDUST CLOTHG/SAFETY FOOTWEAR.
DEPENDING CNDTNS, APRONS, JACKETS, PANTS, COVERALLS, BOOTS. (ING
13)
Work Hygienic Practices:AVOID ALL PERSONAL CONTACT-CORR MATL. DO NOT
WEAR CONTAM CLOTHG, WASH EXPOS AREAS PROMPTLY & THORO AFTER SKIN
(ING 11)
Supplemental Safety and Health
FIRE FIGHT PROC:FUEL SOURCE MAY BE INTENSE ENOUGH TO CAUSE THERM
DECOMP, REL TOX GASES. EXPLO HAZ: CLSD CNTNRS MAY EXPLO WHEN EXPOS
TO EXT HEAT(FIRE). EFTS OF OVEREXP:BY FATIGUE & GI DISTURB. CNS DMG
MAY ALSO OCCUR. INGEST: CORR. CAN CAUSEINTERNAL HEMORRHAGE &
DEATH. MAY LEAD TO EFTS LISTED UNDER INHAL.
================== Physical/Chemical Properties ==================
HCC:T1
Melt/Freeze Pt:M.P/F.P Text:-22F,-30C
Spec Gravity:1.64
Solubility in Water:SOLUBLE
Appearance and Odor:DARK BROWN HEAVY LIQUID.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALINE MATLS, REDUCING AGENTS, ZINC, GALVANIZED STEEL, NASCENT
HYDROGEN, ALUMINUM.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:ARSENICAL COMPOUNDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:PROD EXHIBITS CHARACTERISTICS OF EP TOXICITY-US
EPA DEFINED. DISPOSE OF AS AN EP TOXIC WASTE IN ACCORDANCE WITH
LOCAL, STATE AND FEDERAL REGULATIONS. PLACE IN TIGHTLY SEALED
LABELED CNTNRS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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84-74-2
7732-18-5
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64742-54-7
61790-49-6 |
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DARK CUTTING OIL, 7424
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61790-49-6
64742-65-0 |
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DARK CUTTING OIL, 7423
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61790-49-6
64742-65-0 |
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ALUMINUM/BRONZE-CDA ALLOY 613, 614
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GENAMID 2000
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L-33 CARBURETOR CLEANER
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123-86-4
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BONDERITE 723A
| 7732-94-5
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TURF BUILDER PLUS 2, 27-3-3, 24828
| 94-75-7
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TURF BUILDER PLUS 2, 27-3-3, 3035
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| 78-93-3
108-94-1
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9002-86-2
112945-52-5 |
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| 112945-52-5
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109-99-9
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108-94-1
109-99-9
9002-86-2
112945-52-5 |
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841 WHITE EPOXY RESIN INK
| 111-76-2
64742-95-6 |
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MOBILGEAR 636
| 72623-83-7
64742-62-7
64741-88-4
64742-54-7
8052-42-4
68511-50-2 |
|
POLY-K 3-325
| 68441-17-8 |
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RESIN CLEANER 990, 26032
| 123-86-4
71-36-3
108-88-3 |
|
FIBERGLASS FABRIC
| 65997-17-3 |
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WOLMANAC CONCENTRATE 5096, 38000057
| 1303-28-2
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| 4098-71-9 |
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PRORECO MARINE RUBBER CALK ONE-PART SEALANT
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| 7399-00-0 |
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SODIUM BISULFITE
| 7631-90-5 |
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LAPPING COMPOUND, LC-26
| 1344-28-1
8012-95-1
64742-52-5
68953-18-4
102-71-6
7732-18-5 |
BOILER WATER TREATMENT REAGENT A R5238,Z238
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RUB LUB 2776050
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METEC 4050 NICKEL CHROMIUM 80% NICKEL/20% C
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