| MSDS | : | BUTANOL, A-399 | | CAS | : | 71-36-3 | | NAME | : | 1-butanol; (n-butyl alcohol)
supp data:flow can be stopped. use water in flooding amts
ing 2:w/flooding amts of water. apply from as far a
explo haz:mixtures are explosive above flash point.
efts of overexp:auditory nerve & vestibular injury in
ing 5:hemorrhage, reduced erythrocyte count, lymphocytosis,
ing 6:cortical & tubular degeneration in kidneys were
ing 7:skin:irritant. acute:liq cntct may cause irrit
ing 8:skin. single applications to skin of rabbits resulted
ing 9:been reported to cause drying,cracking & eczematoid
ing 10:liq. application of 42-55 ml/kg/day for 1-4
ing 11:eye:irritant. acute:vap concs of 25ppm may cause
ing 12:eyes caused mod temporary injury which was rated 7
ing 13:result in conjunct.vacuolar keratitis, charact by
ing 14:of gas in epithelial layers of cornea has been
ing 15:expos to >200ppm for 10 yrs caused conjunctival &
ing 16: vision, corneal inflamm, photophobia & burning
ing 17:residual dmg. ingest:narcotic. acute:may cause abdom
ing 18:of butyl alcohol caused complete
ing 19:ciliary reflexes,nystagmus,salivation, reduction of
ing 20:hyperemia, degeneration of liver & kidneys & death
ing 21:in drinking water resulted in liver damage in rats.
first aid proc:ingest:remove ingested matl by gastric
ing 23:get md immed. no specific antidote. treat
spill proc:area! keep unnecessary people away; isolate
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===================== Product Identification =====================
MSDS NAME:BUTANOL, A-399
NIIN:00-939-5390
MSDS Number: BLWCJ
=== Responsible Party ===
Company:FISHER SCIENTIFIC
Address:1 REAGENT LANE
City:FAIR LAWN
State:NJ
ZIP:07410
Country:US
Info Phone Num:201-796-7100
Emergency Phone Num:201-796-7523;800-424-9300(CHEMTREC)
CAGE:1B464
=== Contractor Identification ===
Company:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV
Address:1 REAGENT LANE
Box:City:FAIRLAWN
State:NJ
ZIP:07410-2802
Country:US
Phone:201-796-7100
CAGE:1B464
============= Composition/Information on Ingredients =============
Name:1-BUTANOL; (N-BUTYL ALCOHOL)
CAS:71-36-3
RTECS #:EO1400000
Fraction by Wt: 100%
OSHA PEL:100 PPM
ACGIH TLV:S, C 50 PPM; 9293
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:SUPP DATA:FLOW CAN BE STOPPED. USE WATER IN FLOODING AMTS
AS FOG. SOLID STREAMS MAY NOT BE EFTIVE. COOL CNTNRS (ING 3)
RTECS #:9999999ZZ
Name:ING 2:W/FLOODING AMTS OF WATER. APPLY FROM AS FAR A
DISTANCE AS POSSIBLE. AVOID BREATHING TOXIC VAPORS. KEEP UPWIND.
RTECS #:9999999ZZ
Name:EXPLO HAZ:MIXTURES ARE EXPLOSIVE ABOVE FLASH POINT.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP:AUDITORY NERVE & VESTIBULAR INJURY IN
WORKERS RESULTING IN SEVERE VERTIGO & HEARING LOSS. LUNG (ING 6)
RTECS #:9999999ZZ
Name:ING 5:HEMORRHAGE, REDUCED ERYTHROCYTE COUNT, LYMPHOCYTOSIS,
ALBUMINURIA, EARLY DEGENERATIVE CHANGES OF LIVER, & (ING 7)
RTECS #:9999999ZZ
Name:ING 6:CORTICAL & TUBULAR DEGENERATION IN KIDNEYS WERE
REPORTED IN ANIMALS FOLLOWING PRLNGD EXPOS TO 100PPM. (ING 8)
RTECS #:9999999ZZ
Name:ING 7:SKIN:IRRITANT. ACUTE:LIQ CNTCT MAY CAUSE IRRIT
W/REDNESS & DRYNESS. SUBSTANCE MAY BE ABSORBED THRU INTACT (ING 9)
RTECS #:9999999ZZ
Name:ING 8:SKIN. SINGLE APPLICATIONS TO SKIN OF RABBITS RESULTED
IN SLIGHT-MOD IRRIT. CHRONIC:RPTD/PRLNGD CNTCT HAS (ING 10)
RTECS #:9999999ZZ
Name:ING 9:BEEN REPORTED TO CAUSE DRYING,CRACKING & ECZEMATOID
DERM OF FINGERS & HANDS DUE TO DEFATTING ACTION OF (ING 11)
RTECS #:9999999ZZ
Name:ING 10:LIQ. APPLICATION OF 42-55 ML/KG/DAY FOR 1-4
CONSECUTIVE DAYS TO RABBITS RESULTED IN 100% MORTALITY. (ING 12)
RTECS #:9999999ZZ
Name:ING 11:EYE:IRRITANT. ACUTE:VAP CONCS OF 25PPM MAY CAUSE
SLIGHT IRRIT. APPLICATION OF 1 DROP OF LIQ TO RABBIT (ING 13)
RTECS #:9999999ZZ
Name:ING 12:EYES CAUSED MOD TEMPORARY INJURY WHICH WAS RATED 7
ON SCALE OF 10. CHRONIC:RPTD/PRLNGD EXPOS TO VAPS MAY (ING 14)
RTECS #:9999999ZZ
Name:ING 13:RESULT IN CONJUNCT.VACUOLAR KERATITIS, CHARACT BY
VERY FINE TRANSPARENT VACUOLES RESEMBLING TINY BUBBLES (ING 15)
RTECS #:9999999ZZ
Name:ING 14:OF GAS IN EPITHELIAL LAYERS OF CORNEA HAS BEEN
REPORTED IN WORKERS EXPSD TO BUTYL ALCOHOL & OTHER SOLVS. (ING 16)
RTECS #:9999999ZZ
Name:ING 15:EXPOS TO >200PPM FOR 10 YRS CAUSED CONJUNCTIVAL &
CORNEAL EDEMA RESULTING IN LACRIMATION, BLURRING OF (ING 17)
RTECS #:9999999ZZ
Name:ING 16: VISION, CORNEAL INFLAMM, PHOTOPHOBIA & BURNING
SENSATION W/INFLAMMATION CLEARING W/I A FEW DAYS W/NO (ING 18)
RTECS #:9999999ZZ
Name:ING 17:RESIDUAL DMG. INGEST:NARCOTIC. ACUTE:MAY CAUSE ABDOM
PAIN,NAUSEA,VOMIT & DIARRHEA. INGEST OF HIGH DOSES (ING 19)
RTECS #:9999999ZZ
Name:ING 18:OF BUTYL ALCOHOL CAUSED COMPLETE
PARALYSIS,CONSTRICTION OF PUPILS,REDUCTION IN CORNEAL,PUPILLARY &
(ING 20)
RTECS #:9999999ZZ
Name:ING 19:CILIARY REFLEXES,NYSTAGMUS,SALIVATION, REDUCTION OF
BODY TEMP & RESP, DEEP NARCOSIS, MARKED HEPATIC (ING 21)
RTECS #:9999999ZZ
Name:ING 20:HYPEREMIA, DEGENERATION OF LIVER & KIDNEYS & DEATH
IN ANIMALS. CHRONIC:PRLNGD INGEST OF N-BUTYL ALCOHOL (ING 22)
RTECS #:9999999ZZ
Name:ING 21:IN DRINKING WATER RESULTED IN LIVER DAMAGE IN RATS.
RTECS #:9999999ZZ
Name:FIRST AID PROC:INGEST:REMOVE INGESTED MATL BY GASTRIC
LAVAGE OR EMESIS. GIVE ARTF RESP W/O*2 IF RESP DEPRESSED. (ING 24)
RTECS #:9999999ZZ
Name:ING 23:GET MD IMMED. NO SPECIFIC ANTIDOTE. TREAT
SYMPTOMATICALLY AND SUPPORTIVELY.
RTECS #:9999999ZZ
Name:SPILL PROC:AREA! KEEP UNNECESSARY PEOPLE AWAY; ISOLATE
HAZARD AREA AND DENY ENTRY.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT)790 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL:IRRITANT/NARCOTIC. 8000PPM IDLH.
ACUTE:VAP CONCS OF 25PPM MAY CAUSE MILD IRRIT TO RESP TRACT & NOSE.
SUBSTANCE QUITE ODOROUS WHICH USUALLY PROVIDES ADEQ WARNING BUT
OLFACTORY SENSES READILY BECO ME FATIGUED. EXPOS TO 50PPM MAY CAUSE
HDCH & VERTIGO; HIGHER CONCS MAY CAUSE MARKED IRRIT, SORE
THROAT,(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:NERVOUS SYS DEPRESS W/HDCH, DIZZ, DULL
& DROWS. EXPOS TO 6600PPM PRODUCED GIDDINESS,
PROSTRATION,NARCOSIS,ATAXIA & DEATH IN SOME ANIMALS.
CHRONIC:LONG-TERM STUDY ON HUMANS EXPSD TO BUTYL ALCO HOL REVEALED
LITTLE/NO IRRIT/COMPLICATIONS OCCURRED AT 100PPM/BELOW. HOWEVER,
PRLNGD INHAL AT THIS LEVEL CAUSED (ING 5)
Medical Cond Aggravated by Exposure:PERSONS W/A HISTORY OF CHRONIC
RESPIRATORY, SKIN, OR EYE DISEASE MAY BE AT AN INCREASED RISK FROM
EXPOSURE.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR IMMED.IF BRTHG STOPPED, GIVE ARTF
RESP.KEEP WARM/AT REST.GET MD IMMED. SKIN:REMOVE CONTAMD
CLTHG/SHOES IMMED. WASH AFFECTED AREA W/SOAP/MILD DETERGENT & LG
AMTS OF WATER UNTI L NO EVID OF CHEM REMAINS (APPROX 15-20MIN). GET
MD IMMED. EYE:WASH IMMED W/LG AMTS OF WATER/NORMAL SALINE,OCCASNLY
LIFTING LIDS UNTIL NO EVID OF CHEM REMAINS(APPROX 15-20 MIN).GET MD
IMMED. (ING 23)
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:84.0F,28.9C
Lower Limits:1.4%
Upper Limits:11.2%
Extinguishing Media:DRY CHEMICAL, CARBON DIOXIDE, HALON, WATER
SPRAY/ALCOHOL FOAM. LG FIRE:WATER SPRAY, FOG/ALCOHOL FOAM.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. WATER MAY BE INEFTIVE. MOVE CNTNR FROM FIRE AREA IF POSS. COOL
FIRE-EXPSD CNTNRS W/WATER FROM (SUPP DATA)
Unusual Fire/Explosion Hazard:DANGEROUS FIRE HAZARD WHEN EXPOSED TO
HEAT/FLAME. VAPORS HEAVIER THAN AIR & MAY TRAVEL CONSIDERABLE
DISTANCE TO SOURCE OF IGNIT & FLASH BACK. VAPOR-AIR (ING 4)
================== Accidental Release Measures ==================
Spill Release Procedures:SHUT OFF IGNIT SOURCES. STOP LEAK IF CAN BE
DONE W/O RISK. USE WATER SPRAY TO REDUCE VAPS. SML:TAKE UP
W/SAND/OTHER ABSORB MATL & PLACE INTO CNTNRS FOR LATER DISP.
LG:DIKE FAR AHEAD OF SPILL FOR LATER DISP. NO SMOKING,
FLAMES/FLARES IN HAZ(ING 25)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE I/A/W 29 CFR 1910.106.
Other Precautions:SUBSTANCES W/LOW ELECTROCONDUCTIVITY WHICH MAY BE
IGNITED BY ELECTROSTATIC SPARKS SHOULD BE STORED IN CNTNRS WHICH
MEET BONDING & GROUNDING GUIDELINES SPECIFIED IN NFPA 77-1983,
RECOMMENDED PRACTICE O N STATIC ELECTRICITY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:REFER TO ORIGINAL MSDS .
Ventilation:PROVIDE LOCAL EXHAUST/GEN DILUTION VENT TO MEET PUBLISHED
EXPOS LIMITS. VENT EQUIP MUST BE EXPLOSION-PROOF.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:IMPERVIOUS CLOTHING AND EQUIPMENT.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN.
Supplemental Safety and Health
FIRE FIGHT PROC:SIDE UNTIL WELL AFTER FIRE IS OUT. STAY AWAY FROM STOR
TANK ENDS.FOR MASSIVE FIRE IN STOR AREA,USE UNMANNED HOSE
HOLDER/MONITOR NOZZ, ELSE WITHDRAW FROM AREA & LET FIRE BURN.
WITHDRAW IMMED IN CASE OF RISING SOUND FROM VENTING SFTY
DEVICE/ANY DISCOLORATION OF STOR TANK DUE TO FIRE. EXTING ONLY
IF(ING 2)
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:243F,117C
Melt/Freeze Pt:M.P/F.P Text:-128F,-89C
Vapor Pres:6.5 @ 25C
Vapor Density:2.55
Spec Gravity:0.8098
Evaporation Rate & Reference:0.5 (BUTYL ACETATE = 1)
Solubility in Water:7.7%
Appearance and Odor:CLEAR,MOBILE,COLORLESS LIQ, W/STRONG, PUNGENT
CHARACT ODOR SIMILAR TO FUEL OIL.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
ALKALI METALS, ALUMINUM, T-BUTANOL, CHROMIC ANHYDRIDE, STRONG
OXIDIZERS. SEE ORIGINAL MSDS FOR ADDL INFO .
Stability Condition to Avoid:MAY BE IGNITED BY HEAT, SPARKS OR FLAMES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC CO*X.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE I/A/W STANDARDS APPLICABLE TO
GENERATORS OF HAZ WASTE, 40 CFR 262. EPA HAZ WASTE NO U031. OBSERVE
ALL FEDERAL, STATE & LOCAL REGS WHEN STORING/DISPOSING SUBSTANCE.
FOR ASSISTANCE, CNT CT DISTRICT DIRECTOR OF EPA.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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