===================== Product Identification =====================
MSDS NAME:TF SOLVENT R-113
NIIN:00-935-1082
MSDS Number: BLWCH
=== Responsible Party ===
Company:TECHNICAL CHEMICAL CO.
Address:10737 SPANGLER ROAD
Box:20098
City:DALLAS
State:TX
ZIP:75220-7101
Country:US
Info Phone Num:214-556-1421
Emergency Phone Num:214-556-1421
Preparer's Name:KELLY BERRIOCHOA
CAGE:8X792
=== Contractor Identification ===
Company:TECHNICAL CHEMICAL COMPANY
Address:10737 SPANGLER ROAD
Box:20098
City:DALLAS
State:TX
ZIP:75220-7101
Country:US
Phone:972-556-1421
CAGE:8X792
============= Composition/Information on Ingredients =============
Name:1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA
III)
CAS:76-13-1
RTECS #:KJ4000000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:1000PPM/1250STEL
ACGIH TLV:1000PPM/1250STEL9192
Ozone Depleting Chemical:1
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD 50 ORAL RAT 43000 MG/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS HEAVIER THAN AIR
AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE
LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF B REATH, AND MAY LEAD TO
NARCOSIS, CARDIAC IRREGULARITIES, ULNCONSCIOUSNESS OF DEATH.
SKIN/EYE: LIQUID CAN DEFAT TISSUE.
Explanation of Carcinogenicity:FREON 113 IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP OR OSHA.
Effects of Overexposure:BREATHING HIGH CONCENTRATIONS OF VAPOR MAY
CAUSE LIGHT-HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH, AND MAY
LEAD TO NARCOSIS, CARDIAC IRREGULARITIES, UNCONSCIOUSNESS OR DEATH.
LIQUID IS NOT CORROSIVE O R AN IRRITANT, BUT CAN CAUSE DEFATTING OF
TISSUE.
Medical Cond Aggravated by Exposure:SKIN DISEASE - FREON 113 IS A
DEFATTING AGENT AND CAN CAUSE DERMATITIS ON PROLONGED EXPOSURE.
PERSONS WITH PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO
THE EFFECTS OF THIS AGENT.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR, CALL A PHYSICIAN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. EYE/SKIN: FLUSH WITH WATER FOR 15 MINUTES. IF
IRRITATION PRESI STS, GET MEDICAL ATTENTION. ORAL: GET MEDICAL
ATTENTION. DO NOT INDUCE VOMITING AS THE HAZARD OF ASPIRATING INTO
THE LUNGS IS TOO GREAT.
===================== Fire Fighting Measures =====================
Flash Point Method:TOC
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:NON-FLAMMABLE. USE EXTINGUISHING MEDIA APPROPIATE
FOR SURROUNDING FIRE.
Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A
FULL FACED SELF CONTAINED BREATHING APPARATUS. COOL FIRE EXPOSED
CONTAINERS WITH WATER SPRAY.
Unusual Fire/Explosion Hazard:CONTAINERS MAY RUPTURE UNDER FIRE
CONDITIONS. COMBUSTION OR HEAT OF FIRE MAY PRODUCE HAZARDOUS
DECOMPOSITION PRODUCTS AND VAPORS.
================== Accidental Release Measures ==================
Spill Release Procedures:VENTILATE AREA. DO NOT FLUSH INTO SEWERS.
COLLECT ON ABSORBENT MATERIAL AND TRANSFER TO STEEL DRUMS FOR
RECOVERY OR DISPOSAL. COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS ON REPORTING RELEASES.
Neutralizing Agent:NONE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN A CLEAN, COOL, DRY AND
WELL-VENTILATED AREA OF LOW FIRE RISK. PROTECT CONTAINERS FROM
PHYSICAL DAMAGE AND KEEP CLOSED.
Other Precautions:AVOID BREATHING VAPOR, LIQUID CONTACT WITH EYES, SKIN
OR CLOTHING. EMPTY CONTAINERS MAY CONTAIN PRODUCT RESIDUES/VAPORS,
FOLLOW THE SAME PROCEDURE AS IF THEY WERE FULL.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NONE REQUIRED FOR ADEQUATELY VENTED WORK
SITUATIONS. FOR ACCIDENTAL OR NON-VENTILATED SITUATIONS, USE A
SELF-CONTAINED BREATHING APPARATUS OR SUPPLIED-AIR RESPIRATOR,
APPROVED BY NIOSH.
Ventilation:PROVIDE LOCAL EXHAUST AT FILLING ZONES AND OTHER OPERATING
SPACES WHERE LEAKAGE IS PROBABLE. MECHANICAL FOR OTHER.
Protective Gloves:BUTYL RUBBER, PVA OR NEOPRENE
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:USE IMPERVIOUS CLOTHING IF THERE IS REPEATED
OR PROLONGED CONTACT WITH LIQUID.
Work Hygienic Practices:REMOVE AND WASH CLOTHING PROMPTLY UPON
CONTAMINATION.
Supplemental Safety and Health
NONE
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:118F,48C
Melt/Freeze Pt:M.P/F.P Text:31F FZ PT
Vapor Pres:334 @ 77F
Vapor Density:6.46
Spec Gravity:1.574
Evaporation Rate & Reference:0.1 (CCL4 = 1)
Solubility in Water:0.02% @ 77F
Appearance and Odor:CLEAR LIQUID. SLIGHT ETHEREAL ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
CHEMICALLY ACTIVE METALS SUCH AS ALUMINUM, ZINC, BERRYLIUM, STRONG
CAUSTICS AND OXIDIZERS.
Stability Condition to Avoid:HIGH HEAT, OPEN FLAMES AND OTHER SOURCES
OF IGNITION
Hazardous Decomposition Products:DECOMPOSED BY HIGH TEMPERATURES (OPEN
FLAMES, GLOWING METAL SURFACES, ETC.) FORMING HYDROCHLORIC AND
HYDROFLUORIC ACIDS.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH FEDERAL, STATE AND LOCAL
REGULATIONS. REMOVE TO A PERMITTED WASTE DISPOSAL FACILITY. EPA
HAZARDOUS WATES NOS. F001 AND F002 MAY APPLY TO WASTE MATERIALS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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