===================== Product Identification =====================
MSDS NAME:SODIUM BISULFATE
NIIN:00-159-4453
MSDS Number: BLVZS
=== Responsible Party ===
Company:ECOLAB INC., INSTITUTIONAL PRODUCTS DIVISION
Address:370 WABASHA STREET
City:ST. PAUL
State:MN
ZIP:55102-1307
Country:US
Info Phone Num:612-293-2233
Emergency Phone Num:612-293-2233
Preparer's Name:DOD-HMIS (DGSC-SSH)
CAGE:DO852
=== Contractor Identification ===
Company:ECOLAB INC., INSTITUTIONAL PRODUCTS DIVISION
Address:370 WABASHA STREET
City:ST. PAUL
State:MN
ZIP:55102-1307
Country:US
Phone:612-293-2233
CAGE:DO852
Company:ECOLAB PROFESSIONAL PRODUCTS DIVISION OF ECOLAB INC.
Address:ECOLAB CENTER
Box:City:ST PAUL
State:MN
ZIP:55102
Country:US
Phone:800-352-5326
CAGE:85884
============= Composition/Information on Ingredients =============
Name:SODIUM BISULFATE ANHYDROUS GLOBULAR (SODIUM ACID SULFATE,
NITRE CAKE)
CAS:7681-38-1
RTECS #:VZ1860000
Fraction by Wt: 94.5%
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INCLUDING SIGNIFICANT ROUTES EFFECTS,
SYMPTOMS OF OVER EXPOSURE & MEDICAL CONDITIONS AGGRAVATED BY
EXPOSURE.
Effects of Overexposure:WATERING OF EYES, MILD SKIN BURNS, MILD BURNING
SENSATION MAY OCCUR TO MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT.
INHALATION: IRRITANT. SKIN: MILD TO SEVERE IRRITANT. INGESTION:
IRRITANT.
======================= First Aid Measures =======================
Eyes:FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES, GET PROMPT
MEDICAL ATTENTION. SKIN:FLUSH WITH WATER FOR 15 MINUTES. IF BURNS
OCCUR OBTAIN MEDICAL HELP. INHALE:MOVE TO FRESH AIR LOCATION.
SWALLOW:DRIN K LARGE QUANTITIES OF WATER/MILK, FOLLOW WITH MILK OF
MAGNESIA, BEATEN EGGS OR VEGETABLE OIL. DO NOT INDUCE VOMITING.
CONTACT PHYSICIAN IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Extinguishing Media:WATER OR DRY CHEMICAL AS APPROPRIATE FOR
COMBUSTIBLES IN AREA
Fire Fighting Procedures:WHEN WATER USED TO EXTING COMBUSTIBLES/
PRODUCT IS DISSOLVED IN WATER FORMING SULFURIC ACID.USE ACID
PROTECTIVE EQUIP. ELEVATED TEMPS(+570F)IS REACHED, USE SCBA
Unusual Fire/Explosion Hazard:PRODUCT READILY DISSOLVES IN WATER TO
FORM WEAK SULFURIC ACID SOLUTION. NO GASES, TOXIC FUMES ARE EMITTED
FROM REACTION, BUT PRECAUTIONS SHOULD BE FOLLOWED.
================== Accidental Release Measures ==================
Spill Release Procedures:SMALL:MATERIAL IS A GRANULAR PRODUCT & CAN BE
SWEPT UP FROM SURFACES. LARGE:PICK UP AS MUCH AS POSSIBLE W/SHOVEL
OR OTHER TOOL. NEUTRALIZE BALANCE OF SPILL W/WEAK ALKALINE SOLUTION
& WASH DOWN TO SEWE R IF FEDERAL, STATE & LOCAL REGULATIONSPERMITS.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID CONTACT WITH SKIN, EYES OR
CLOTHING. DO NOT STORE WHERE EXPOSED TO MOIST CONDITIONS OR NEAR
STRONG ALKALIES. KEEP CONTAINERS TIGHTLY CLOSED.
Other Precautions:WEAR ALL RECOMMENDED PROTECTIVE EQUIPMENT WHEN
HANDLING.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:NIOSH OR MSA CERTIFIED DUST MASK SHOULD BE WORN
WHILE HANDLING PRODUCT TO CONTROL EXPOSURE BELOW NUISANCE DUST
LIMITS OF 10 MG/M3
Ventilation:LOCAL EXHAUST:LOCAL VENTILATION TO A DUST COLLECTOR IS
RECOMMENDED.
Protective Gloves:ACID RESISTANT GLOVES:RUBBER OR NEOPRENE
Eye Protection:SAFETY GOGGLES OR FULL FACE SHEILD
Other Protective Equipment:CLOTHES SHOULD COMPLETELY COVER SKIN TO
AVOID SKIN CONTACT. COATS, COVERALLS OR APRONS ARE RECOMMENDED.
Work Hygienic Practices:USE COMMON SENSE & CARE AROUND CHEMICALS. NEVER
MIX CHEMICALS. CONSULT YOUR SUPERVISOR FOR OTHER PRACTICES.
Supplemental Safety and Health
MSDS COPIED FROM ANOTHER NSN OF SODIUM BISULFATE ANOTHER MANUFACTURER.
================== Physical/Chemical Properties ==================
HCC:C3
Melt/Freeze Pt:M.P/F.P Text:350F,177C
Solubility in Water:100%
Appearance and Odor:OFF-WHITE, BEAD LIKE, GRANULAR, DRY MATERIAL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG ALKALINE MATERIAL SUCH AS CAUSTIC. REACT WITH
WATER TO FORM WEAK SULFURIC ACID SOLUTION.
Stability Condition to Avoid:STORE IN DRY AREA TO AVOID MOISTURE
CONTACT
Hazardous Decomposition Products:NONE UNLESS HEATED OVER 570F AT WHICH
SULFUR DIOXIDE & SULFUR TRIOXIDE ARE FORMED.
==================== Disposal Considerations ====================
Waste Disposal Methods:COMPLY WITH ALL THE STATE, FEDERAL & LOCAL
REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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