===================== Product Identification =====================
MSDS NAME:LEAD AZIDE, PART C.
NIIN:01-205-7859
Kit Part:Y
MSDS Number: BLZHR
=== Responsible Party ===
Company:OLIN CORPORATION
Address:120-LONG RIDGE ROAD
Box:1355
City:STAMFORD
State:CT
ZIP:06904-1355
Country:US
Info Phone Num:203-356-2000
Emergency Phone Num:800-OLIN-911(1-800-654-6911)
CAGE:99530
=== Contractor Identification ===
Company:OLIN CORPORATION
Address:501 MERRITT 7
Box:4500
City:NORWALK
State:CT
ZIP:06856-4500
Country:US
Phone:203-750-3000/800-511-MSDS
CAGE:99530
============= Composition/Information on Ingredients =============
Name:LEAD AZIDE
CAS:13424-46-9
RTECS #:OF8650000
Fraction by Wt: 100%
Other REC Limits:NONE SPECIFIED
OSHA PEL:0.05 MG/M3 AS PB
ACGIH TLV:0.15 MG/M3 AS PB
Name:DEXTRINE
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
LD50 LC50 Mixture:TLV: 0.15MG/M3 LEAD
Routes of Entry: Inhalation:NO Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SPECIALTY ELECTRIC DETONATORS DO NOT
PRESENT HEALTH HAZARDS IN NORMAL HANDLING AND USE. HOWEVER, THE
PRODUCTS ARE SQUIBS AND DECOMPOSITION MAY CAUSE SEVERE INJURY,
INCLUDING DEATH. OVEREXPOSURE TO LEA D MAY CAUSE ADVERSE EFFECTS TO
THE BLOOD FORMING, NERVOUS, URINARY, REPRODUCTIVE SYSTEMS,
INCLUDING EMBRYOTOXIC EFFECTS.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:LEAD POISONING MAY CAUSE LOSS OF APPETITE,
ANEMIA, DISTURBANCE OF SLEEP & FATIGUE. NITROGEN OXIDES GENERATED
DURING USE ARE SKIN, EYE & RESPIRATORY SYSTEM IRRITANTS. SYSTEMIC
TOXICITY RESULTING FROM O XIDATION OF LUNG TISSUE INCLUDES
EMPHYSEMA, BRONCHITIS, & BRONCHOPNEUMONIA. ACUTE EXPOSURE MAY CAUSE
ASPHYXIATION.
Medical Cond Aggravated by Exposure:INDIVIDUALS WITH PRE-EXISTING
DISEASE IN OR A HISTORY OF AILMENTS INVOLVING THE LUNGS, KIDNEY,
SKIN, CNS, OR REPRODUCTIVE SYSTEM ARE AT A GREATER THAN NORMAL RISK
WHEN EXPOSED TO THIS MATERIAL.
======================= First Aid Measures =======================
First Aid:INHALATION: TREAT FOR LEAD INHALATION IF EXPOSED TO A CLOUD
OF GAS RESULTING FROM A DETONATION. REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE CPR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET
MEDICAL ATT ENTION.
===================== Fire Fighting Measures =====================
Autoignition Temp:Autoignition Temp Text:653F
Extinguishing Media:NONE
Fire Fighting Procedures:DO NOT FIGHT FIRE. EVACUATE AREA, REMOVE ALL
PERSONNEL.
Unusual Fire/Explosion Hazard:MATERIAL DETONATES FROM SHOCK, FRICTION,
STATIC, AND FIRE. IT DOES NOT BURN - IT DETONATES.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTROL ACCESS TO AREA. TREAT SPILL WITH AT
LEAST FIVE (5) TIMES ITS WEIGHT OF A 20% SOLUTION OF SODIUM
HYR0XIDE. ALLOW THE MIXTURE TO STAND FOR 16 HOURS WITH OCCASIONAL
STIRRING.
Neutralizing Agent:SODIUM HYDROXIDE, 20% SOLUTION.
====================== Handling and Storage ======================
Handling and Storage Precautions:BE EXTREMELY CAUTIOUS WHEN HANDLING -
MATERIAL IS SENSITIVE TO SHOCK, FRICTION, STATIC, AND FIRE. GROUND
ALL EQUIPMENT, PERSONNEL, AND SURFACES.
Other Precautions:ADDITIONAL INFORMATION IS AVAILABLE IN THE BLASTERS'
HANDBOOK, PUBLISHED BY E.I.DUPONT DE NEMOURS AND COMPANY; ORDNANCE
SAFETY MANUAL, PUBLISHED BY THE US ARMY ORDNANCE DEPARTMENT; AND IN
THE INSTITUT E OF MAKERS OF EXPLOSIVES SAFETY PUBS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:WEAR A NIOSH/MSHA APPROVED RESPIRATOR WITH DUST
CARTRIDGE APPROPRIATE FOR EXPOSURE OF CONCERN.
Ventilation:NORMAL LOCAL EXHAUST.
Protective Gloves:CONDUCTIVE RUBBER.
Eye Protection:SAFETY GLASSES
Other Protective Equipment:LEG STATS, CONDUCTIVE CLOTHES, CONDUCTIVE
SHOES, AND FACE SHIELD.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
KEY1:E1, THIS ENTRY DESCRIBES PART C OF A 3 PART KIT. SEE PN IND A FOR
PART A DATA AND PN IND B FOR PART B DATA. OCCUPATIONAL EXPOSURE TO
LEAD IS REGULATED BY 29CFR1910.1025(F).
================== Physical/Chemical Properties ==================
HCC:E1
Decomp Temp:Decomp Text:653F,345C
Spec Gravity:4.71
Evaporation Rate & Reference:0
Solubility in Water:0.02%
Appearance and Odor:BUFF POWDER, NO ODOR.
Percent Volatiles by Volume:0
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:NO
COPPER OR ZINC, BRASS, CARBON DISULFIDE, CALCIUM STEARATE.
Stability Condition to Avoid:BE EXTREMLY CAUTIOUS WHEN HANDLING -
MATERIAL IS SENSITIVE TO SHOCK, FRICTION, STATIC, AND FIRE.
Hazardous Decomposition Products:HAZARDOUS GASES PRODUCED MAY CONTAIN
LEAD FUMES, CARBON MONOXIDE, AND NITROGEN OXIDES .
==================== Disposal Considerations ====================
Waste Disposal Methods:BURN NEUTRALIZED RESIDUE REMOTELY. COMPLY WITH
APPLICABLE FEDERAL REGULATIONS UNDER THE AUTHORITY OF THE RESOURCE
CONSERVATION & RECOVERY ACT (40 CFR, PARTS 260-271)
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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