===================== Product Identification =====================
MSDS NAME:MAP-9046 LITHIUM CARBONMONOFLUORIDE BATTERY
NIIN:01-137-3157
MSDS Number: BLZGZ
=== Responsible Party ===
Company:EAGLE-PICHER INDUSTRIES INC ELECTRONICS DIV
Address:C AND PORTER STS
Box:47
City:JOPLIN
State:MO
ZIP:64801
Country:US
Info Phone Num:417-623-8000
Emergency Phone Num:417-623-8000
CAGE:0B3X4
=== Contractor Identification ===
Company:EAGLE-PICHER INDUSTRIES INC
Address:14212 BETHEL ROAD
Box:130
City:SENECA
State:MO
ZIP:64865
Country:US
Phone:417-776-2256
CAGE:0B3X4
Company:EAGLE-PICHER INDUSTRIES, INC.
Address:C AND PORTER STS
Box:47
City:JOPLIN
State:MO
ZIP:64801
Country:US
Phone:417-623-8000
CAGE:81855
============= Composition/Information on Ingredients =============
Name:LITHIUM METAL
CAS:7439-93-2
RTECS #:OJ5540000
Other REC Limits:NONE SPECIFIED
Name:CARBON MONOFLUORIDE
Other REC Limits:NONE SPECIFIED
Name:DIMETHYL SULFITE (DIMETHOXY SULFOXIDE)
CAS:616-42-2
Other REC Limits:NONE RECOMMENDED
Name:LITHIUM HEXAFLUOROARSENATE
CAS:29935-35-1
Other REC Limits:NONE SPECIFIED
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:ACUTE: INHALATION- IRRITATION, BURNS
OF MUCOUS MEMBRANES. EYES/SKIN- BURNS, IRRITATION. INGESTION: BURNS
OF MOUTH, ESOPHAGUS, AND GI TRACT. CHRONIC: CONTAINS ARSENIC, A
KNOWN CARCINOGEN, SKIN IRRITATI ON. KIDNEY DAMAGE, ANOREXIA,
APATHY, CNS DEPRESSION.
Explanation of Carcinogenicity:ARSENIC, AN INGREDIENT, IS LISTED AS A
KNOWN CARCINOGEN BY IARC, NTP, OSHA, AND EPA.
Effects of Overexposure:INHALATION: BURNING, COUGHING, DIFFICULTY
BREATHING, DIZZINESS, NAUSEA, COMA. EYES: BURNING, TEARING. SKIN:
BURNING, REDDENING OF SKIN, BURNS. INGESTION: BURNING SENSATION IN
MOUTH, ESOPHAGUS, AND STO MACH. BURNS IN SAME. NAUSEA, ABDOMINAL
PAIN, DIZZINESS, PROSTATION. OTHER SYMPTOMS OF CNS DEPRESSION.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.
PRE-EXISTING SKIN OR RESPIRATORY CONDITIONS MAY BE AGGRAVATED BY
OVEREXPOSURE.
======================= First Aid Measures =======================
First Aid:INHALATION: REMOVE TO FRESH AIR. GIVE ARTIFICIAL
RESPIRATION/OXYGEN IF REQUIRED. GET MEDICAL ATTENTION. EYES: FLUSH
WITH WATER FOR 15 MINUTES. GET IMMEDIATE MEDICAL HELP. SKIN: WASH
THOROUGHLY WITH SO AP AND WATER. IF IRRITATION PERSISTS, SEE
DOCTOR. INGESTION: DO NOT INDUCE VOMITING! SEE DOCTOR IMMEDIATELY.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:113F,45C (MSI)
Extinguishing Media:DRY CHEMICAL, SODA ASH, LIME, SAND, OR LITHIUM-X.
Fire Fighting Procedures:USE SELF-CONTAINED BREATHING APPARATUS AND
FULL PROTECTIVE GEAR. SEAL AREA FROM UNEEDED PERSONNEL.
Unusual Fire/Explosion Hazard:DO NOT USE WATER. MATERIAL IS WATER
REACTIVE. FIRE AND EXPLOSION HAZARD. FIRE AND HEAT MAY PRODUCE
HAZARDOUS DECOMPOSITION PRODUCTS AND/OR EXPLOSION.
================== Accidental Release Measures ==================
Spill Release Procedures:PICK UP ALL BATTERIES. FOR RUPTURED BATTERIES:
VENTILATE THE AREA, GET CHEMICAL PROTECTIVE EQUIPMENT, ABSORB FREE
ELECTROLYTE ON PAPER OR VERMICULITE AND PLACE IN CONTAINER FULL OF
OIL FOR DISPOSAL. C ONTACT LOCAL ENVIRONMENTAL MANAGER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.AFTER ABSORBTION, 1 %
IODINE/5% POTASSIUM IODIDE
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE IN COOL, DRY PLACE AWAY FROM
SOURCES OF IGNITION. AVOID TEMPERATURES OVER 110F.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR OR
SELF-CONTAINED BREATHING APPARATUS IF BATTERIES RUPTURE.
Ventilation:USE ADEQUATE MECHANICAL VENTILATION.
Protective Gloves:PVC, VITON
Eye Protection:SAFETY GLASSES/CHEMICAL SPLASH GOGGLES
Other Protective Equipment:APRON MADE OF MATERIAL IMPERVIUOS TO
MATERIAL. EYE WASH STATION & SAFETY SHOWER.
Work Hygienic Practices:WASH THOROUGHLY AFTER EACH CONTACT. LAUNDER
CLOTHING BEFORE REUSE. DISPOSE OF CONTAMINATED FOOTWEAR.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
HCC:F8
pH:UNKNON
Appearance and Odor:SEALED BATTERY,6.25IN.X6.79 IN.X3.25
IN..ELECTROLYTE COLORLESS, ACETONE ODOR.
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STEAM, WATER, ACID, HEAVY METALS, OXIDIZERS, SILVER COMPOUNDS.
Stability Condition to Avoid:HEAT, AND SOURCES OF IGNITION.
Hazardous Decomposition Products:HYDROGEN, SULFUR OXIDES AND SULFUR
HALIDES, OXIDES OF CARBON.
==================== Disposal Considerations ====================
Waste Disposal Methods:DO NOT INCINERATE. BURY IN A LANDFILL IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. CONTACT LOCAL
ENVIRONMENTAL MANAGER.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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