===================== Product Identification =====================
MSDS NAME:POLYMERIC MDI INSTAPAK COMPONENT A FLAME RE
NIIN:00N028623
Kit Part:Y
MSDS Number: BPCXM
=== Responsible Party ===
Company:SEALED AIR CORP
Address:OLD SHERMAN TNPK
City:DANBURY
State:CT
ZIP:06810
Country:US
Info Phone Num:203-791-3500
Emergency Phone Num:203-791-3500;800-424-9300(CHEMTREC)
CAGE:51614
=== Contractor Identification ===
Company:SEALED AIR CORP INSTAPAK DIVISION
Address:OLD SHERMAN TPKE
Box:City:DANBURY
State:CT
ZIP:06810
Country:US
Phone:203-791-3500/800-424-9300(CHEMTREC)
CAGE:51614
============= Composition/Information on Ingredients =============
Name:ING 8: HIGHEST EXPOSURE, 30X THE OSHA PEL, WAS THERE A
STATISTICALLY RECOGNIZABLE NUMBER OF BENIGN TUMORS & ONE (ING 10)
RTECS #:9999999ZZ
Name:ING 9:MALIGNANT TUMOR. LUNG IRRIT & AN ACCUM OF YELLOW MATL
IN LUNGS WAS SEEN IN HIGHEST EXPOS GRP(30X OSHA PEL)(ING 11)
RTECS #:9999999ZZ
Name:ING 10: & TO A LESSER DEGREE IN GROUP EXPOS AT 5X OSHA PEL.
BASED ON INFORMATION, IT IS HIGHLY UNLIKELY THAT (ING 12)
RTECS #:9999999ZZ
Name:ING 11: TUMOR FORMATION WILL RESULT FROM EXPOSURES AT/BELOW
CURRENT EXPOSURE GUIDELINES.
RTECS #:9999999ZZ
Name:EFTS OF OVEREXP: RATS WERE EXPOS TO POLYMERIC MDI AEROSOLS
FOR 6 HRS/DAY, 5 DAYS/WK FOR A LIFETIME. ONLY AT THE (ING 9)
RTECS #:9999999ZZ
Name:ISOCYANIC ACID, METHYLENEDI-P-PHENYLENE ESTER;
(4,4'DIPHENYLMETHANE DIISOCYANATE (MDI))
CAS:101-68-8
RTECS #:NQ9350000
Fraction by Wt: 50%
OSHA PEL:0.02 PPM, C
ACGIH TLV:0.005 PPM
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:POLYMETHYLENEPOLYPHENYL ISOCYANATE; (HIGHER MOLECULAR
WEIGHT OLIGOMERS OF MDI)
CAS:9016-87-9
RTECS #:TR0350000
Fraction by Wt: 45%
OSHA PEL:0.02 PPM, C (MFR)
Name:ARSENIC (SARA III)
CAS:7440-38-2
RTECS #:CG0525000
Fraction by Wt: 0.5% PPM
OSHA PEL:0.5 MG/M3 (AS)
ACGIH TLV:0.01,A1 MG/M3; 9394
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:CADMIUM (SARA III)
CAS:7440-43-9
RTECS #:EU9800000
Fraction by Wt: 0.5% PPM
Other REC Limits:NONE SPECIFIED
OSHA PEL:SEE 1910.1027
ACGIH TLV:0.01 MG/M3 DUST;9394
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS
Name:LEAD (SARA III)
CAS:7439-92-1
RTECS #:OF7525000
Fraction by Wt: 0.5% PPM
OSHA PEL:0.05 MG/M3
ACGIH TLV:.15 MG/M3;DUST
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SUPP DATA: CAN BE ASSURED. WHERE CONCENTRATIONS EXCEED PEL,
SUPPLIED AIR RESPS MUST BE USED.
RTECS #:9999999ZZ
Name:VAPOR PRESS: <0.00001 @ 25C.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50: (ORAL,RAT) 20 G/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: MAY LEAD TO MUC MEMB IRRIT,
TIGHTENING OF CHEST, RESP TRACT IRRIT, COUGHING, HDCH, SHORTNESS OF
BRTH. MAY LEAD TO ALLERGIC SENSIT IN SOME INDIVIDUALS RSLTG IN
ASTHMA-LIKE SYMPS UPON EXPOS
FROM FURTHER EXPOS. SKIN: MAY CAUSE IRRIT/RASH. CAN CAUSE SKIN
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DISCOLORATION. RPTD CONTACT MAY RSLT
IN SKIN SENSIT. EYE: LIQ CAN CAUSE IRRIT, TEARING, REDDENING &
SWELLING. PERM CORNEAL INJURY IS UNLIKELY. VAPS IN EXCESS OF 0.02
PPM MAY CAUSE IRRIT. INGE ST: UNLIKELY. CAN CAUSE IRRIT & CORR
ACTION IN MOUTH, STOMACH & DIGESTIVE TRACT. IN RECENT STUDY, GROUPS
OF (ING 8)
Medical Cond Aggravated by Exposure:PERSONS W/ASTHMA-TYPE
CONDITIONS/OTHER CHRONIC RESPIRATORY DISEASES OR PULMONARY
DISORDERS SHOULD BE EXCLUDED FROM WORKING WITH MDI.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO UNCONTAMD AREA, ADMIN O2 IF NEC.
ASTHMATIC-LIKE SYMPS, IF MANIFESTED, MAY DEVEL IMMED/MAY BE DELAYED
FOR UP TO SEVERAL HRS. OBTAIN MED ATTN .TREATMENT IS SYMPTOMATIC.
SKIN: WASH AREA T HORO W/SOAP & H2O. LAUNDER CLTHG BEFOREREUSE.
EYES: FLUSH W/ H2O FOR AT LEAST 15 MINS, HOLDING LIDS OPEN
W/FINGERS. CALL MD. INGEST: DO NOT INDUCE VOMIT. DRINK H2O TO
REDUCE CORR. SEE MD.
===================== Fire Fighting Measures =====================
Flash Point Method:PMCC
Flash Point:390F,199C
Extinguishing Media:CO2, CHEMICAL FOAM, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
AVOID WATER CONTAM IN CLSD CNTNRS, CO2 IS EVOLVED WHICH CAN CAUSE
PRESS BUILD-UP.
Unusual Fire/Explosion Hazard:CAUTION! REACTION BETWEEN WATER AND HOT
ISOCYANATE CAN BE VIGOROUS.
================== Accidental Release Measures ==================
Spill Release Procedures:SPILL SHLD BE COVERED W/LOOSE,ABSORB,NON-
BIODEGRADABLE MATL. POUR DEACTIVATING SOLN OVER SPILL AREA; ALLOW
TO REACT 10 MINS/LONGER. COLLECT MATL IN OPEN CNTNRS & TREAT
W/ADDTNL DEACTIVATING SOLN; ALL OW TO STAND UNCOVERED FOR 24-48
HRS.(SUPP DATA)
Neutralizing Agent:DEACTIVATING SOLN: 90% WATER, 8% CONC AMMONIA, 2%
DETERGENT.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE DRUMS UNCOVERED OUTDOORS.
DO NOT RESEAL CNTNRS UNLESS SURE THAT NO MOISTURE CONTAM HAS
OCCURED. DO NOT BREATH VAPS/ALLOW SKIN CONT.
Other Precautions:REACTS WITH MOISTURE TO PRODUCE CO2. STORAGE
TEMPERATURE: MIN 50F, MAX 100F.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:DUE TO LOW VAP PRESS OF MATL, PEL IS NOT LIKELY
TO BE EXCEEDED UNDER NORMAL CNDTNS. IF MATL IS HEATED/SPILLED IN
CONFINED AREA, NIOSH/MSHA APPRVD RESP PROT SHOULD BE WORN. BECAUSE
OF THEIR SHORT LIFE & LACK OF BREAKTHROUGH (SUPP DATA)
Ventilation:USE LOCAL EXHAUST IF NECESSARY TO MAINTAIN LEVELS
Protective Gloves:RUBBER/PLASTIC GLOVES.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SAFETY SHOWER, EYEWASH STATION &
DEACTIVATING SOLN SHLD BE AVAIL.
Work Hygienic Practices:SEE "RECOMMENDATIONS FOR THE SAFE USE AND
HANDLING OF INSTAPAK FOAM-IN-PLACE CHEMICALS" BULLETIN BEFORE
OPERATING EQUIP.
Supplemental Safety and Health
SPILL PROC: WASH AREA W/DEACTIVATING SOLN. RESP, EYE & SKIN PROT SHLD
BE WORN DURING SPILL CLEAN-UP & VENT MAINT. RESP PROT: INDICATORS,
CARTRIDGE TYPE RESPS EQUIPD FOR ORG VAPS ARE GENERALLY NOT RECO MMD
FOR USE W/ISOCYANTES. CAN BE USED FOR SHORT TERM EMERG SITUATIONS
AT CONC
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:B.P. Text:625F,329C
Vapor Pres:ING 7
Vapor Density:8.5
Spec Gravity:1.24 @ 25C
Solubility in Water:REACTS WITH WATER
Appearance and Odor:DARK BROWN LIQUID W/SLIGHT AROMATIC ODOR.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
WATER, AMINES, STRONG BASES, ALCOHOLS, SURFACE ACTIVE MATERIALS.
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE 110F OR BELOW
40F.
Hazardous Decomposition Products:BY FIRE OR EXTREME HEAT, COX, NOX,
TRACES OF HYDROGEN CYANIDE.
Conditions to Avoid Polymerization:MAY OCCUR, IS ACCELERATED AT
ELEVATED TEMPS. AVOID CONTACT W/MOISTURE & OTHER MATLS WHICH
CONTAIN ACTIVE HYDROGEN.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE OR DISP OF IN ACCORDANCE W/EXISTING
FEDERAL, STATE & LOCAL ENVIRON CONTROL REGULATIONS. ALSO SEE
"RECOMMENDATIONS FOR SAFE USE & HANDLING OF INSTAPAK FOAM-IN-PLACE
CHEMICALS" BULLETIN.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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