===================== Product Identification =====================
MSDS NAME:HARDENER HY 956
NIIN:00N028316
MSDS Number: BPCVY
=== Responsible Party ===
Company:CIBA-GEIGY CORP
Address:THREE SKYLINE DR
City:HAWTHORNE
State:NY
ZIP:10532
Country:US
Info Phone Num:914-347-4700;800-334-9481
Emergency Phone Num:914-347-4700;800-334-9481
Preparer's Name:JONAS WEISS
CAGE:07566
=== Contractor Identification ===
Company:CIBA-GEIGY CORP ADDITIVES DIV.
Address:SEVEN SKYLINE DRIVE
Box:City:HAWTHORNE
State:NY
ZIP:10532-2119
Country:US
Phone:800-888-8372
CAGE:07566
============= Composition/Information on Ingredients =============
Name:N,N'-BIS(2-AMINOETHYL)-1,2-ETHANEDIAMINE, POLYMER WITH
METHYLOXIRANE; (PROPOXLYLATED TRIETHYLENETETRAMINE)
CAS:26950-63-0
Name:TRIETHYLENETETRAMINE;
(N,N'-BIS(2-AMINOETHYL)-1,2-ETHANEDIAMINE)
CAS:112-24-3
RTECS #:YE6650000
===================== Hazards Identification =====================
LD50 LC50 Mixture:LD50:(ORAL,RAT) 4500 MG/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:HEATED PROD MAY PRODUCE INHALABLE
VAPORS. SKIN: MAY CAUSE SEVERE IRRIT. EYE: SEVERE IRRIT. MAY CAUSE
SENSIT. DURING A TERATOLOGY STUDY W/RATS, WHOLE BODY EDEMA &
HEMORRHAGE WAS FOUND IN OFFSPRING FROM DAMS RECEIVING 415 OR 830
MG/KG; HOWEVER, THESE EFTS WERE ASSOC W/MATERNAL TOX. THE
NO-OBSERVABLE(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: EFTS-LEVEL (NOEL) FOR THE MATERNAL
TOX & OFFSPRING EFTS WAS 85 MG/KG. THESE EFTS MAY BE ATTRIBUTED TO
A COPPER DEFICIENCY CAUSED BY RPTD ORAL ADMIN OF
TRIETHYLENETETRAMINE. ANOTHER RECENT TE RATOLOGY STUDY INDICATED
THAT TRIETHYLENETETRAMINE WAS NON-TERATOGENIC & CAUSED NO ADVERSE
EFTS ON MOTHERS (SUPP DATA)
Medical Cond Aggravated by Exposure:ALLERGY, ECZEMA OR SKIN CONDITIONS.
======================= First Aid Measures =======================
Eyes: IMMED FLUSH WITH WATER FOR AT LEAST 15 MINUTES. CALL
MD. SKIN: PROMPTLY WASH THORO WITH MILD SOAP AND WATER. PROMPTLY
REMOVE WET CONTAM NON-IMPERVIOUS CLTHG. WASH BEFORE REUSE. INGEST:
GET IMMED MEDICAL ATTN. DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE
PLENTY OF WATER TO DILUTE. INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN
IF BREATHING DFCLT.
===================== Fire Fighting Measures =====================
Flash Point Method:CC
Flash Point:>200F,>93C
Extinguishing Media:CO*2, FOAM, DRY CHEMICAL, WATER SPRAY.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:DECOMPOSITION AND COMBUSTION PRODUCTS MAY
BE TOXIC.
================== Accidental Release Measures ==================
Spill Release Procedures:AVOID ALL PERSONAL CONTACT. TAKE UP WITH
ABSORBENT MATERIAL. SHOVEL INTO CLOSABLE CNTNRS. FLUSH CONTAM AREA
WITH WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:PROD MAY BE CORR/CAUSE EYE BURNS.
HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRIT. AVOID EYE, SKIN & CLTHG
CONT. DO NOT TASTE OR INGEST.
Other Precautions:DO NOT INHALE MISTS. KEEP CONTAINER TIGHTLY CLOSED
WHEN NOT IN USE AND DURING TRANSPORT. USE WITH ADEQ VENT. FOR
INDUSTRIAL USE ONLY.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR, IF NEEDED.
Ventilation:GOOD GENERAL MECHANICAL VENTILATION AND LOCAL EXHAUST IF
NEEDED.
Protective Gloves:WEAR IMPERVIOUS GLOVES.
Eye Protection:CHEM WORK GOGG & FULL LGTH FSHLD .
Other Protective Equipment:WEAR APPROPRIATE EQUIP TO PREVENT
PROBABILITY OF EXPOSURE AND PERSONAL CONTACT. EMERGENCY EYEWASH,
DELUGE SHOWER .
Work Hygienic Practices:WASH AFTER HANDLING, AND BEFORE EATING,
DRINKING OR SMOKING.
Supplemental Safety and Health
EFTS OF OVEREXP:OR OFFSPRING AT A DOSE OF 750 MG/KG. MAY BE CORROSIVE
OR CAUSE EYE BURNS. INHAL MAY CAUSE UPPER RESP TRACT IRRITATION,
MUCOUS MEMBRANE IRRITATION. EXTENSIVE OVEREXPOSURE MAY CAUSE SPAS
MS AND INFLAMMATION OF THE LARYNX OR BRONCHI.
================== Physical/Chemical Properties ==================
Boiling Pt:B.P. Text:>392F,>200C
Vapor Pres:<0.01@ 20C
Spec Gravity:1.02 (H*2O=1)
pH:12
Solubility in Water:MISCIBLE
Appearance and Odor:YELLOW LIQUID, AMINE ODOR.
Percent Volatiles by Volume:NIL
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS AND ACIDS.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:CO, CO*2, ALDEHYDES, NITROGEN OXIDES.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE IN ACCORDANCE WITH FEDERAL, STATE AND
LOCAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
*** END OF RECORD *** |
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