===================== Product Identification =====================
MSDS NAME:HASTELLOY ALLOY W
NIIN:01-339-4362
MSDS Number: BPKRH
=== Responsible Party ===
Company:HAYNES INTERNATIONAL
Address:1020 WEST PARK AVE
City:KOKOMO
State:IN
ZIP:46902-9013
Country:US
Info Phone Num:317-456-6625
Emergency Phone Num:317-456-6894;800-424-9300(CHEMTREC)
CAGE:80357
=== Contractor Identification ===
Company:HAYNES INTERNATIONAL INC SUB OF CABOT CORP
Address:1020 W PARK AVE
Box:9013
City:KOKOMO
State:IN
ZIP:46904-9013
Country:US
Phone:318-263-2002;765-456-6614
CAGE:80357
============= Composition/Information on Ingredients =============
Name:COBALT (SARA III)
CAS:7440-48-4
RTECS #:GF8750000
Fraction by Wt: 2.5% MAX
OSHA PEL:0.1 MG/M3;AS CO
ACGIH TLV:0.05 MG/M3;DUST 9293
Name:CHROMIUM (SARA III)
CAS:7440-47-3
RTECS #:GB4200000
Fraction by Wt: 5%
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:IRON (III) OXIDE
CAS:1309-37-1
RTECS #:NO7400000
Fraction by Wt: 6%
OSHA PEL:10 MG/M3 (FE)
ACGIH TLV:5 MG/M3(FE),B2; 9293
Name:MANGANESE (SARA III)
CAS:7439-96-5
RTECS #:OO9275000
Fraction by Wt: 1% MAX
OSHA PEL:(C) 5 MG/M3 DUST
ACGIH TLV:5 MG/M3 DUST 9293
Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
Fraction by Wt: 24%
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3; 9293
Name:NICKEL (SARA III)
CAS:7440-02-0
RTECS #:QR5950000
Fraction by Wt: 63%
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
Fraction by Wt: 1% MAX
OSHA PEL:15 MG/M3 TDUST
ACGIH TLV:10 MG/M3 TDUST; 9293
Name:VANADIUM (SARA III)
CAS:7440-62-2
RTECS #:YW1355000
Fraction by Wt: 0.6% MAX
OSHA PEL:C,0.5 MG V2O5/M3 RD
ACGIH TLV:0.05 MG V205/M3;9293
Name:SUPP DATA:LINKED TO NASAL, BRONCHIAL & LUNG CANCERS.
ALUMINUM & IRON HAVE BEEN INDICATED TO CAUSE GI DISORDERS (ING 10)
RTECS #:9999999ZZ
Name:ING 9:& NON-SIGNIFICANT CHANGES IN THE LUNG. CHRONIC HLTH
EFTS SPECIFIC TO ELEMENT(S) MAY BE DFCLT TO DETECT (ING 11)
RTECS #:9999999ZZ
Name:ING 10:DUE TO NUMEROUS ELEMENTAL CONSTITUENTS IN THESE
ALLOYS.
RTECS #:9999999ZZ
Name:OTHER PREC:TESTS, CHEST X-RAYS & ROUTINE PHYSICAL EXAMS MAY
BE USEFUL TO DETERMINE EFFECTS OF DUST OR FUME EXPOSURE.
RTECS #:9999999ZZ
===================== Hazards Identification =====================
LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE:METAL DUST & FUMES OF ELEMENTS
IN INGREDS CAN CAUSE IRRIT TO SKIN, EYE & MUC MEMB. CNTCT
W/CHROMIUM, COBALT, COPPER & NICKEL MAY CAUSE ALLERGIC SKIN RXN. AS
DUST, PWDRS/FUME, EXPOS WHICH ABRADES SKIN CAN CAUSE IRRIT & DERM.
INJURY TOEYES IS GEN RESULT OF PARTICULATE IRRIT/MECH INJURY TO
CORNEA (EFTS OF OVEREXP)
Explanation of Carcinogenicity:CHROMIUM:GROUP 1 (NTP,IARC).
NICKEL:GROUP 2 (NTP), GROUP 2B (IARC)
Effects of Overexposure:HLTH HAZ:OR CONJUNCTIVA BY DUST/PARTICULATE.
EXCESSIVE INHAL OF ALUMINUM, COBALT, COPPER, MANGANESE & NICKEL CAN
CAUSE RESP IRRIT, COUGH, BRONCH, CHILLS, FUME FEVER & ASTHMA-LIKE
SYMPS. CHRONIC:RESP D ISEASE W/SYMPS RANGING FROM SHORT OF BREATH &
COUGH TO PERM DISABILITY DUE TO LOSS OF LUNG FUNCTION,
FIBROSIS(SUPP DATA)
Medical Cond Aggravated by Exposure:PERS WHO HAD ALLERGIC
RXN/SENSITIVITY TO METALS MAY GET SKIN RASH/DERM. PERS W/IMPAIRED
PULM FUNCTION, AIRWAY DISEASES & CONDS (ASTHMA, EMPHYSEMA, CHRONIC
BRONCH, ETC.) MAY INCUR FURTHER DISABILITY.
======================= First Aid Measures =======================
First Aid:INHAL:REMOVE TO FRESH AIR. IF BRTHG STOPPED, GIVE ARTF RESP &
GET MD IMMED. INGEST:IF AFFECTED, SWALLOW LG QTYS OF WATER & TRY TO
INDUCE VOMIT IF CONSCIOUS. GET MD IMMED. SKIN:CUTS & ABRASIONS CAN
BE TREATED BY STD FIRST AID. CONTAM W/DUST/PWDR: WASH W/SOAP &
WATER. IF IRRIT PERSISTS GET MD. EYE:DUST/PWDR:FLUSH W/COPIOUS AMTS
OF CLEAN WATER. IF IRRIT PERSISTS GET MD.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:ALLOYS NONCOMBUSTIBLE. USE EXTING MEDIA APPROP TO
SURROUNDING FIRE. TO EXTING METAL PWDR FIRE USE DRY SAND, (SUPP
DATA)
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
PROTECTIVE EQUIPMENT . IF THESE MATERIALS ARE REDUCED TO POWDER
FORM, CAUTION MUST BE USED TO PREVENT FIRE/EXPLOSION.
Unusual Fire/Explosion Hazard:NO UNUSUAL FIRE OR EXPLOSION HAZARDS ARE
ASSOCIATED W/THESE MATERIALS.
================== Accidental Release Measures ==================
Spill Release Procedures:IN SOLID FORM,MATLS POSE NO SPECIAL CLEAN-UP
PROBLEMS. IF PWDR/DUST FORM,CLEAN-UP W/VACUUM SYS USING HEPA
FILTRATION SYS. CAUTION:MINIMIZE AIRBORNE GENERATION OF PWDR/DUST,
AVOID CONTAM OF AIR,WATER. PROPERLY LABEL ALL MATLS COLLECTED IN
WASTE CNTNR.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEXT TO MINERAL ACIDS.
FINE METAL PWDR:KEEP AWAY FROM FLAMES/IGNIT SOURCES. PRODS MUST BE
HANDLED BY SIZE/SHAPE/QTY OF MATLS INVOLVED.
Other Precautions:SOLID METAL MAY REQ USE OF HOISTS/CRANES.
PWDRS:MOVE/TRANSPORT TO MINIMIZE SPILL/RELEASE POTNTL. EXPOS TO
ELEMENTS IN INGREDS CAN BE BEST DETERMINED BY HAVING AIR SAMPLES
TAKEN IN EMPLOYEE BRTHG ZONE, WORK AREA/DEPT. LUNG FUNCTION (ING
12)
============= Exposure Controls/Personal Protection =============
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATORS. USE A
NIOSH/MSHA APPROVED FUME RESPIRATOR OR AN AIR SUPPLIED RESPIRATOR
WHERE LOCAL EXHAUST OR VENTILATION DOES NOT KEEP EXPOSURE BELOW
OSHA LIMITS FOR AIR CONTAMI NATION.
Ventilation:LOCAL EXHAUST VENTILATION SHOULD BE USED TO CONTROL
EXPOSURE TO AIRBORNE DUST & FUME WHENEVER POSSIBLE.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:PROTECTIVE CLOTHING SUCH AS UNIFORMS,
DISPOSABLE COVERALLS, SFETY SHOES, ETC. MAY BE REQUIRED.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN IF WORKING
W/METAL DUSTS & POWDERS.
Supplemental Safety and Health
EXTING MEDIA:DRY GRAPHITE/OTHER CLASS D FIRE EXTING PWDR. EFTS OF
OVEREXP:OR SUBSEQUENT EFTS ON HEART MAY BE CAUSED BY EXCESSIVE
EXPOS TO DUST/FUMES CONTAINING COBALT, NICKEL, TITANIUM & TUNGSTEN.
CNS DEPRESS HAS BEEN IDENTIFIED W/EXCESSIVE MANGANESE EXPOS.
NICKEL & CHROMIUM METAL & CERTAIN CMPDS HAVE BEEN (ING 9)
================== Physical/Chemical Properties ==================
Melt/Freeze Pt:M.P/F.P Text:2400F,1316C
Spec Gravity:0.325
Solubility in Water:NONE
Appearance and Odor:SOLID, SILVER GRAY COLOR, NO ODOR.
Percent Volatiles by Volume:NONE
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
MINERAL ACIDS & OXIDIZING AGENTS WHICH MAY GENERATE HYDROGEN GAS.
EVOLUTION OF HYDROGEN MAY BE AN EXPLOSION HAZARD.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:VARIOUS ELEMENTAL METALS & METAL
OXIDES MAY BE GENERATED FROM WELDING/CUTTING/GRINDING/MELTING,
DROSS HNDLG OPERATIONS.
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSE OF I/A/W LOCAL, STATE OR FEDERAL
REGULATIONS. FOR SPECIFIC LABELING, PACKING, STORAGE,
TRANSPORTATION & DISPOSAL PROCEDURES, CONTACT ENVIRONMENTAL
ENGINEER OR CONSULTANT FAMILIAR W/WASTE DISPO SAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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