LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:SUSPECTED CANCER HAZARD:CONTAINS
4,4'-METHYLENEDIANILINE WHICH MAY CAUSE CANCER. RISK DEPENDS ON
LENGTH & LEV OF EXPOS. CHRONIC CONTACT/INHAL MAY ALSO CAUSE LIVER
DAMAGE AND BREATHING PROBLEMS. DANGER :MAY BE FATAL IF INGEST. VAPS
ARE EXCEEDINGLY IRRIT TO MUC MEM & EYES. RPTD EXPOS MAY CAUSE SKIN
(EFTS OF OVEREXPOS)
Explanation of Carcinogenicity:METHYLENE DIANILINE (4,4): ANTIC TO BE A
CARCIN (NTP), GROUP 2B (IARC).
Effects of Overexposure:HLTH HAZ:IRRIT, LEADING TO SENSIT & DERM. EYE
CONTACT MAY CAUSE EXTREME IRRIT AND/OR BURNING. POSSIBLY SEV IRRIT
AND/OR SENSIT CAN RESULT FROM OVEREXPOS TO THIS PRODUCT.
Medical Cond Aggravated by Exposure:PRE-EXISTING EYE, SKIN AND
RESPIRATORY DISORDERS MAY BE AGGRAVATED BY EXPOSURE.
======================= First Aid Measures =======================
Eyes:IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MINUTES.
GET MD ATTN. SKIN:IMMED WASH W/SOAP & PLENTY OF WATER. WASH CONTAM
CLOTHING BEFORE RE-USE & DESTROY CONTAM SHOES. INHAL:REMOVE TO
FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION,
PREFERABLY MOUTH-TO-MOUTH. IF BREATHING IS DIFFICULT GIVE O*2. GET
MD ATTN. INGEST:GET MD ATTN IMMED. INDUCE VOMITING ONLY UPON ADVICE
OF A MD.
===================== Fire Fighting Measures =====================
Flash Point Method:COC
Flash Point:>300F,>149C
Extinguishing Media:USE CARBON DIOXIDE OR DRY CHEMICAL FOR SMALL FIRES.
USE WATER AND FOAM FOR LARGE FIRES.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA AND FULL
PROTECTIVE EQUIPMENT . VAPORS ARE EXCEEDINGLY IRRITATING WHEN
INHALED.
Unusual Fire/Explosion Hazard:NONE SPECIFIED BY MANUFACTURER.
Spill Release Procedures:CONTAIN W/SUITABLE DIKING MATL. VENT AREA
THORO. KEEP ALL UNNEC PEOPLE AWAY. SPILLED MATL SHOULD BE ABSORBED
IN SAWDUST, SAND/OTHER ABSORB. PLACE IN AN OPEN-TOP CONTR. KEEP
CONTR OPEN FOR AT LEAST 12 HOURS BEFORE SEALING CONTAINER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.
====================== Handling and Storage ======================
Handling and Storage Precautions:AVOID BREATHING VAPORS. KEEP AWAY FROM
HEAT, SPARKS AND OPEN FLAME. USE ADEQUATE VENTILATION.
Other Precautions:STORE IN A COOL DRY AREA IN TIGHTLY CLOSED
CONTAINERS. AVOID MOISTURE COMTAMINATION.
Respiratory Protection:USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE
FOR EXPOSURE OF CONCERN .
Ventilation:USE ADEQUATE VENTILATION.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:SYNTHETIC APRON.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
KEY1:T6.
HCC:T6
Spec Gravity:1.06
Appearance and Odor:AMBER LIQUID WITH A FAINT ODOR
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH STRONG OXIDIZERS.
Stability Condition to Avoid:AVOID CONTACT WITH WATER, ALCOHOL, STRONG
BASES, METAL COMPOUNDS OR SURFACE ACTIVE MATERIALS.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE AND
NITROGEN OXIDES.
Waste Disposal Methods:CONTROLLED INCINERATION OR BURIED LANDFILL
DISPOSAL SHOULD BE IN ACCORDANCE WITH ALL LOCAL, STATE AND FEDERAL
ENVIRONMENTAL REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.