===================== Product Identification =====================
MSDS NAME:VELVALITE ZA-3B
NIIN:00N012692
MSDS Number: BQPLC
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:2219
City:DUBLIN
State:OH
ZIP:43017
Country:US
Info Phone Num:614-889-4505
Emergency Phone Num:614-889-4505
CAGE:5A188
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO
Address:5200 PAUL BLAZEL MEMORIAL PARKWAY
Box:City:DUBLIN
State:OH
ZIP:43017
Country:US
Phone:614-889-4505
CAGE:5A188
============= Composition/Information on Ingredients =============
Name:ROSIN ACIDS DIMERIZED
Fraction by Wt: 1-5%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:QUARTERNARY AMMONIUM COMPOUNDS WITH BENTONITE.ACGIH TLV &
OSHA PEL FOR NUISANCE PARTICULATES.
CAS:68953-58-2
Fraction by Wt: 1-5%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ALIPHATIC PETROLEUM DISTILATES (NAPHTHA,LIGHT
ALIPHATIC).BP:285.00F,140.00C.VP:15.00 MMHG AT 100.00F,37.77C.
CAS:64742-89-8
Fraction by Wt: 10-30%
Other REC Limits:400 PPM
OSHA PEL:N/K
ACGIH TLV:N/K
Name:SUP DATA: TRUCKS WHEN MATERIAL IS TRANSFERRED. ROUTE OF
ENTRY: INGEST .
RTECS #:9999999ZZ
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
Name:ZIRCONIUM SILICATE
CAS:10101-52-7
Fraction by Wt: >60%
Other REC Limits:N/K
OSHA PEL:N/K
ACGIH TLV:N/K
===================== Hazards Identification =====================
LD50 LC50 Mixture:N/K
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ASPIRATION INTO LUNGS FROM VOMITING
CAN CAUSE CHEMICAL PNEUMONITIS WHICH MAY BE FATAL. PROLONGED OR
REPEATED CONTACT CAN CAUSE DERMATITIS. OVEREXPOSURE HAS BEEN
SUGGESTED AS A CAUSE OF LUNG DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYES:POSSIBLE SEVERE
IRRITATION,REDNESS,TEARING,BLURRED VISION.SKIN:PRLNGD/RPTD CONTACT
CAN CAUSE MODERATE IRRIT,DEFAT,.INGEST:POSS GI IRRIT,NAUSEA,VOMIT,&
DIARRHEA.INHAL:EXCESS INHAL OF VAPORS MAY CA USE NASAL &
RESPIRATORY IRRIT,CNS EFFECTS INCLUDE
DIZZINESS,WEAK,FATIGUE,NAUSEA,HEADACHE,POSS UNCONSCIOSNESS,EVEN
DEATH.
Medical Cond Aggravated by Exposure:N/K
======================= First Aid Measures =======================
Eyes:FLUSH W/ LARGE AMTS OF H*2O FOR AT LEAST 15 MIN,LIFTING
UPPER & LOWER LIDS OCCASNLY.GET MED ATTN.SKIN:THORO WASH EXPOS AREA
W/ SOAP & H*2O.REMOVE CONTAM CLTHG.INGEST:DO NOT INDUCE VOMIT.KEEP
WARM ,QUIET,& GET MED ATTN.ASPIR OF MATL TO LUNGS BY VOMIT CAN
CAUSE POSS FATAL CHEM PNEUMIT.INHAL:REMOVE TO FRESH AIR.IF BRTHG
DFCLT,GIVE OXYG.IF BRTHG STOPPED,GIVE ARTF RESP.KEEP WARM,QUIET.GET
MED ATTN.
===================== Fire Fighting Measures =====================
Flash Point:56.0F,13.3C
Lower Limits:SEE SUPP
Extinguishing Media:USE WATER FOG,CARBON DIOXIDE,REGULAR FOAM,OR DRY
CHEMICAL.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPS HEAVIER THAN AIR,MAY MOVE ALONG THE
GROUND OR BY VENT.POSS IGNIT BY PILOT
LIGHTS,FLAMES,SPARKS,HEATERS,SMOKING,ELECTRIC MOTORS,STATIC
DISCHARGE (SEE SUPP)
================== Accidental Release Measures ==================
Spill Release Procedures:ELIM ALL POSS IGNIT SOURCES INCL
FLARES,FLAMES,PILOT LIGHTS,ELEC SPARKS.ABSORB SMALL SPILL ON
PAPER,VERMICULITE/OTHER ABSORB MATL & TRANSFER TO HOOD.STOP LARGE
SPILL AT SOURCE.EXCLUDE UNPROT PERS UNTI L CLEAN UP COMPLETE.DIKE
AREA TO PVNT (SEE SUPP)
Neutralizing Agent:N/K
====================== Handling and Storage ======================
Handling and Storage Precautions:NEVER USE WELDING/CUTTING TORCH
ON/NEAR DRUM,EVEN EMPTY SINCE PROD/RESIDUE CAN IGNITE
EXPLOSIVELY.GROUND/BOND ALL FIVE GAL PAILS & LARGER (SEE SUPP)
Other Precautions:CONTAINERS MAY BE HAZARDOUS EVEN WHEN EMPTY,SINCE
EMPTY CONTAINERS MAY RETAIN RESIDUES INCLUDING VAPORS,LIQIUD,AND/OR
SOLID.ALL HAZARD PRECAUTIONS IN DATASHEET MUST BE OBSERVED.THE FREE
SILICA CONTENT FOR THIS PRODUCT MAY RANGE FROM 0-4.0%.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:IF EXPOS LIM EXCEEDED,NIOSH/MSHA APPRVD AIR SUPP
RESP ADVISED IN ABSENCE OF ENVIRON CONTROL.OTHER NIOSH/MSHA RESP
(NEG PRESS TYPE) PERMISSIBLE UNDER SPECIFIED CNDTNS.SEE SFTY EQUIP
SUPPLIER.USE ENGINE ERING OR ADMIN CONTROLS TO REDUCE EXPOS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV(S).
Protective Gloves:RESISTANT:POLYETHYLENE
Eye Protection:CHEM SPLASH GOGG & FULL LENGTH FACESHLD.
Other Protective Equipment:IMPERVIOUS CLOTHING AND BOOTS.
Work Hygienic Practices:LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
LEL:1.0% LOWEST VALUE OF COMPONENT.EXPLO HAZ:/OTHER IGNIT SOURCES AT
LOCATIONS DISTANT FROM MATL HNDLG PT.HAZ DECOMP
PROD:CO,CO*2,VARIOUS HYDROCARBONS.SPILL PROC:SPREADING.PUMP LIQ TO
SALV TANK.ABSORB REMAINING LIQ W/ SAND,CLAY OR EARTH & SHOVEL INTO
CNTNRS.HNDLG/STOR PREC:METAL CNTNRS INCL TANK CARS & TANK (SEE ING
5)
================== Physical/Chemical Properties ==================
HCC:F3
Boiling Pt:B.P. Text:N/K
Melt/Freeze Pt:M.P/F.P Text:N/K
Decomp Temp:Decomp Text:N/K
Vapor Pres:N/K
Vapor Density:>1,AIR=1
Spec Gravity:2.160,WATER=1
Evaporation Rate & Reference:SLOWER THAN ETHER
Solubility in Water:N/K
Appearance and Odor:LIQUID
Percent Volatiles by Volume:20-25
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:N/K
Hazardous Decomposition Products:MAY FORM TOXIC MATERIALS,CARBON
DIOXIDE AND CARBON MONOXIDE,VARIOUS HYDROCARBONS,ETC.
Conditions to Avoid Polymerization:CANNOT OCCUR
==================== Disposal Considerations ====================
Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH
FEDERAL,STATE AND LOCAL REGULATIONS .FOR SMALL SPILL LET EVAP IN
HOOD.ALLOW TIME FOR VAPS TO CLEAR DUCTS.DISPOSE OF REMAINING
MATERIAL.FOR LARGE SPILLS INCINE RATE MATERIAL.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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